Search results for "IR M"
showing 10 items of 151 documents
Two end-members of carbonate slope evolution during the Late Cretaceous in the peri-Tethyan domain (Western Sicily and Southern Albania)
2019
Climatic and tectonic processes are major mechanisms influencing tropical carbonate platform development, sediment production and sediment export. Mass transport deposits (including slides, slumps and debrites) and calciturbidites are some of the sediment export products resulting from the interplay of aforementioned redeposition mechanisms. They reflect distinct variations in both production and export of sediments from the carbonate factories. The gravitary export deposits provide information on their sediment source and result in sedimentary sequences with specific porosity / permeability properties prone to host hydrocarbon resources. Climate-controlled sea-level variations are well-con…
Slope Failures and MTDs along a Cretaceous Escarpment in Western Sicily (Italy)
2018
In the last decades, many contributions have examined the Mass Transport Deposits (MTDs) in both modern and ancient examples for the comprehension of the sedimentary dynamics along the carbonate escarpments. Such sedimentary bodies have a great economic significance, since they are widely considered prone to the development of petroleum systems. In particular, MTDs from Cretaceous escarpments are well known from many regions of the world, since they are typically rich in rudists aragonite fragments determining high percentages of porosity. In these respect the deep knowledge on the facies architecture of these depositional systems is of broad interest as can offer examples for the predictio…
Ranking Series of Cancer-Related Gene Expression Data by Means of the Superposing Significant Interaction Rules Method
2020
The Superposing Significant Interaction Rules (SSIR) method is a combinatorial procedure that deals with symbolic descriptors of samples. It is able to rank the series of samples when those items are classified into two classes. The method selects preferential descriptors and, with them, generates rules that make up the rank by means of a simple voting procedure. Here, two application examples are provided. In both cases, binary or multilevel strings encoding gene expressions are considered as descriptors. It is shown how the SSIR procedure is useful for ranking the series of patient transcription data to diagnose two types of cancer (leukemia and prostate cancer) obtaining Area Under Recei…
Levels of trace elements in human hair samples of adolescents living near petrochemical plants
2020
The aim of the study is a comparative analysis to investigate human hair metal profiles of adolescents residing near petrochemical plants (Sicily, Italy). We selected the small town of Augusta, Gela, and Pace del Mela, and a control area made up of the towns characterized by low anthropogenic activity. Twenty trace elements were measured in samples of scalp hair from adolescents (11–14 years old) of both genders. Hair samples were cleaned using a rigorous cleaning method, mineralized, and processed for analyses by inductively coupled plasma–mass spectrometry (ICP-MS). In industrial sites, zinc was always the most abundant element, ranging from186 to 217 μg g−1. Following zinc, the elements …
Ultra-thin film sensors based on porphyrin-5-ylphosphonate diesters for selective and sensitive dual-channel optical detection of mercury(II) ions
2020
International audience; Reusable dual-channel optical sensors for Hg2+ ions were prepared by Langmuir-Schaefer (LS) method from amphiphilic (trans-A2)BC-type porphyrins functionalized at meso-positions of the tetrapyrrolic macrocycle by sterically demanding diethoxyphosphoryl and mesityl groups as well as electron donating RO, RS or RNH substituents (R = n-C8H17). These three novel amphiphilic porphyrin derivatives were synthesized in good yields and their floating films at the air⎯water interface were investigated. In these monolayers, porphyrin molecules display a slipped stack-of-card orientation, but their strong π stacking is prohibited by bulky diethoxyphosphoryl and mesityl groups. T…
A theoretical approach to pneumatic muscle mechanics
2013
The mechanical response of pneumatic artificial muscles is analyzed assuming the inextensibility of the sheathing braids and taking into account the stress field inside the rubber bladder, which is regarded as a Mooney-Rivlin hyperelastic material. The end effects are simulated by heuristically profiling the meridian section. After estimating the constitutive parameters by traction tests on rubber specimens, the theoretical results are compared with experiments and a satisfactory accordance may be detected.
Infrared microspectroscopy of biochemical response of living cells in microfabricated devices
2010
Abstract First experiments demonstrating the suitability of novel microfabricated fluidic devices for measuring living cells in physiological environment by synchrotron radiation (SR) Fourier Transform Infrared microspectroscopy (μ-FTIR) are presented. The devices were fabricated on CaF 2 windows, using the photoresist XARP 3100/10 to define the liquid cell lay-out. Therefore, the sample holder is transparent to both visible and infrared light, robust, completely recyclable and with a precise spacing. Using prototype devices of thicknesses 9, 5 and 3 μm, we studied the response of the U937 monocytic cell line to mechanical compression. The temporal evolution of the FTIR spectra, characteris…
Chemical characterization in coastal fog and rain at Mount Monduver fog-collection station, Mediterranean Iberian Peninsula
2021
Abstract An experimental site was selected for fog- and rain-water quality analyses. The selected location corresponds to Mount Monduver of 843 m elevation, being geographically centered in the Mediterranean Iberian Peninsula. Single fog- and rain-water samples were taken manually with a dedicated fog and rain collectors, to prevent any contamination with dry-deposition. Besides, a permanently exposed fog collector and a rain gauge were also used for the collection of water samples affected by dry deposition. Results indicated that all chemical analyses complied with Spanish drinking water regulations, except for the particular case of the dry-deposition contaminated water samples. A furthe…
Constraining the ship contribution to the aerosol of the central Mediterranean
2017
Particulate matter with aerodynamic diameters lower than 10 µm, (PM10) aerosol samples were collected during summer 2013 within the framework of the Chemistry and Aerosol Mediterranean Experiment (ChArMEx) at two sites located north (Capo Granitola) and south (Lampedusa Island), respectively, of the main Mediterranean shipping route in the Straight of Sicily. The PM10 samples were collected with 12 h time resolutions at both sites. Selected metals, main anions, cations and elemental and organic carbon were determined. The evolution of soluble V and Ni concentrations (typical markers of heavy fuel oil combustion) was related to meteorology and ship traffic intensity in the Straight of Sicily…
Sea surface temperature and torrential rains in the Valencia region: modelling the role of recharge areas
2015
Abstract. Heavy rain events are frequently recorded in the Western Mediterranean causing economic losses and even human casualties. The Western Mediterranean is a deep and almost closed sea surrounded by high mountain ranges and with little exchange of water with the Atlantic ocean. A main factor in the development of torrential rains is ocean-atmosphere exchanges of heat and moisture that can potentially destabilize air masses travelling over the sea. The study of air mass trajectories previous to the rain event permits the identification of sea areas that could probably contribute to the development or intensification of rainfall. From a previous Mediterranean sea surface temperature clim…