Search results for "IRC"
showing 10 items of 5754 documents
Effect of AlR3 (R = Me, Et, iBu) addition on the composition and microstructure of ethylene/1-olefin copolymers made with post-metallocene complexes …
2018
The effect of trialkylaluminum compound (AlR3, where R = Me, Et, iBu) addition on the performance of the [LigZrCl]2(μ-O)/AliBu3/Ph3CB(C6F5)4 and LigTiCl2/AliBu3/Ph3CB(C6F5)4 (Lig = Me2N(CH2)2N(CH2-2-O-3,5-tBu2-C6H2)2) catalysts in ethylene/1-olefin copolymerization was investigated. The presence of AlMe3 in the feed during the copolymerization process catalyzed by the diamine-bis(phenolate) zirconium catalyst greatly increases the amount of incorporated comonomer and leads to microstructural changes, e.g., the formation of blocky and alternating sequences of 1-olefin units. Moreover, the use of AlMe3 limits the reaction yield and decreases the molecular weight of the produced copolymers. Th…
Non‐subduction origin for 3.2 Ga high‐pressure metamorphic rocks in the Barberton granitoid‐greenstone terrane, South Africa
2019
The occurrence of high-pressure (HP) garnet-bearing metamorphic rocks in the southern Barberton granitoid-greenstone terrane (BGGT), South Africa, has been proposed as a key indicator of the onset of modern plate tectonics at ca. 3.2 Ga. Here, we report new zircon/titanite U-Pb ages of garnet-bearing HP metamorphic rocks and associated granitoids in the BGGT that argue against such an interpretation. The results show that HP metamorphism occurred synchronously with granitoid magmatism in the Stolzburg domain, the supposed subducted plate, during two episodes at 3.4 and 3.2 Ga, and that these two episodes of magmatism occurred on both sides of the assumed suture zone, a feature that cannot e…
Inter-annual climate variability in Europe during the Oligocene icehouse
2017
Abstract New sclerochronological data suggest that a variability comparable to the North Atlantic Oscillation (NAO) was already present during the middle Oligocene, about 20 Myr earlier than formerly assumed. Annual increment width data of long-lived marine bivalves of Oligocene (30–25 Ma) strata from Central Europe revealed a distinct quasi-decadal climate variability modulated on 2–12 (mainly 3–7) year cycles. As in many other modern bivalves, these periodic changes in shell growth were most likely related to changes in primary productivity, which in turn, were coupled to atmospheric circulation patterns. Stable carbon isotope values of the shells (δ 13 C shell ) further corroborated the …
Coastal precipitation regimes in Kenya.
1997
Kenya is under the influence of the seasonal reversal of the Indian ocean monsoons. However, its coastal belt, up to about 50 km inland, exhibits original climatic features. Hierarchical clustering...
Simulated European stalagmite record and its relation to a quasi-decadal climate mode
2013
Abstract. A synthetic stalagmite record for the Bunker cave is constructed using a combined climate-stalagmite modeling approach. The power spectrum of the simulated speleothem calcite δ18O record has a pronounced peak at quasi-decadal time scale. Interestingly, mixing processes in the soil and karst above the cave represent a natural low-pass filter of the speleothem climate archive. We identify a quasi-decadal mode characterized by a "tripole pattern" of sea surface temperature affecting stalagmite δ18O values. This pattern, which is well-known in literature as the quasi-decadal mode in the North Atlantic, propagates eastwards and affects western European temperature surrounding the cave.…
Photometric variability of the Be star CoRoT-ID 102761769
2010
Classical Be stars are rapid rotators of spectral type late O to early A and luminosity class V-III, wich exhibit Balmer emission lines and often a near infrared excess originating in an equatorially concentrated circumstellar envelope, both produced by sporadic mass ejection episodes. The causes of the abnormal mass loss (the so-called Be phenomenon) are as yet unknown. For the first time, we can now study in detail Be stars outside the Earth's atmosphere with sufficient temporal resolution. We investigate the variability of the Be Star CoRoT-ID 102761769 observed with the CoRoT satellite in the exoplanet field during the initial run. One low-resolution spectrum of the star was obtained wi…
Hydrothermal pressure-temperature control on CO2 emissions and seismicity at Campi Flegrei (Italy)
2021
Fluids supplied by stored magma at depth are causal factors of volcanic unrest, as they can cause pressurization/heating of hydrothermal systems. However, evidence for links between hydrothermal pressurization, CO2 emission and volcano seismicity have remained elusive. Here, we use recent (2010−2020) observations at Campi Flegrei caldera (CFc) to show hydrothermal pressure, gas emission and seismicity at CFc share common source areas and well-matching temporal evolutions. We interpret the recent escalation in seismicity and surface gas emissions as caused by pressure-temperature increase at the top of a vertically elongated (0.3–2 km deep) gas front. Using mass (steam) balance consideration…
Spectral biases in tree-ring climate proxies
2013
Seamless quantification of past and present climate variability is needed to understand the Earth’s climate well enough to make accurate predictions for the future. This study addresses whether tree-ring-dominated proxy data properly represent the frequency spectrum of true climate variability. The results challenge the validity of detection and attribution investigations based on these data. External forcing and internal dynamics result in climate system variability ranging from sub-daily weather to multi-centennial trends and beyond1,2. State-of-the-art palaeoclimatic methods routinely use hydroclimatic proxies to reconstruct temperature (for example, refs 3, 4), possibly blurring differe…
Effects of natural radiation damage on back-scattered electron images of single crystals of minerals
2006
Generally, it has been assumed that signal intensity variations in back-scattered electron (BSE) images of minerals are mainly controlled by chemical heterogeneity. This is especially true for images of single crystals, where effects of different crystal orientations with respect to the incident beam on the observed BSE are excluded. In contrast, we show that local variations of the structural state within single-crystals (i.e., degree of lattice order or lattice imperfectness) may also have dramatic effects on the back-scattering of electrons. As an example, we present BSE images of single-crystals of natural zircon, ZrSiO 4 , whose intensity patterns are predominantly controlled by struct…
Multiple intrusive phases in the Leinster Batholith, Ireland: geochronology, isotope geochemistry and constraints on the deformation history
2017
The formation of granite batholiths, commonly by incremental assembly of small magma batches, and their correlation with tectonic events, on both local and regional scales, is crucial to understanding the evolution of the Earth9s continental crust. However, these correlations often rely on assumptions about the detailed relationship and timing of mapped units. Here we report how an integrated geochronological, structural and isotope geochemical study in only one key locality from the late Caledonian Leinster Batholith in SE Ireland provides the potential for unravelling essential questions on batholith petrogenesis. The Northern Unit of the Leinster Batholith intruded incrementally, as demo…