Search results for "IRRADIATION"

showing 10 items of 1012 documents

Influence of a Crosslinker Containing an Azo Group on the Actuation Properties of a Photoactuating LCE System

2016

Photoactuating liquid crystalline elastomers (LCE) are promising candidates for an application as artificial muscles in microdevices. In this work, we demonstrate that by optimizing (1) the illumination conditions and (2) the mixture of azo monomer and azo crosslinker, thick films of an all-azo LCE can be prepared, which show a strong length change without bending during photoactuation. This becomes possible by working with white light (about 440 nm), whose absorption is low, leading to a large penetration depth. By adding an azo crosslinker to a previously prepared system, several improvements of the actuation properties—like a stronger photoactuation at lower operational temperatures—coul…

Materials sciencePolymers and Plasticsvis photo polymerizationazo02 engineering and technology010402 general chemistryElastomer01 natural sciencesArticleIsothermal processlcsh:QD241-441chemistry.chemical_compoundlcsh:Organic chemistryPolymer chemistryphotoactuationliquid crystalline elastomersIrradiationPenetration depthAbsorption (electromagnetic radiation)crosslinkerlight-responsiveactuatorpolymer filmGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesliquid crystalline networkPhotopolymerMonomerChemical engineeringchemistryliquid crystalline elastomers; photoactuation; polymer film; light-responsive; azo; crosslinker; actuator; vis photo polymerization; liquid crystalline networkArtificial muscle0210 nano-technologyPolymers
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Low-temperature positron-lifetime studies of proton-irradiated silicon

1990

The positron-lifetime technique has been used to identify defects created in high-purity single-crystal silicon by irradiation with 12-MeV protons at 15 K, and the evolution of the defects has been studied by subsequent annealings between 20 and 650 K. Two clear annealing steps were seen in the samples, the first starting at 100 K and the other at 400 K. The first is suggested to be a result of the migration of free, negatively charged monovacancies, and the second is connected to the annealing of some vacancy-impurity complexes, probably negatively charged vacancy-oxygen pairs. The specific trapping rate of positrons to both of these negatively charged monovacancy-type defects has been fou…

Materials sciencePositronSiliconchemistryProtonAnnealing (metallurgy)chemistry.chemical_elementCrystal structureIrradiationAtomic physicsSingle crystalCrystallographic defectPhysical Review B
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Preparation of Catalysts and Photocatalysts Used for Similar Processes

2019

Abstract This chapter reports the main techniques used to synthesize powders and films of heterogeneous catalysts and photocatalysts, often used for similar processes. Traditional preparation processes of bulky (photo)catalysts including precipitation, sol–gel technique, hydrothermal or solvothermal method, solid-state reactions, and flame syntheses were briefly described. The sonochemical method and microwave irradiation technique were also considered. The syntheses of supported catalysts by different techniques, including deposition–precipitation, impregnation, and wet coating technologies were also described. Moreover, a survey is reported of methods to deposit thin films of catalysts on…

Materials sciencePrecipitation (chemistry)Bulk and supported catalystFlame syntheseengineering.materialChemical and physical vapor depositionHydrothermal circulationCatalysisPreparation of heterogeneous (photo)catalystChemical engineeringCoatingWet chemical techniquesPhysical vapor depositionMicrowave irradiationengineeringThin filmSolid-state reaction
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Recombination luminescence of X-ray induced paramagnetic defects in BaY2F8

2020

This research is funded by the Latvian Council of Science , project “Novel transparent nanocomposite oxyfluoride materials for optical applications”, project No. LZP-2018/1–0335 . The crystal growth research was funded by the CNPq (Brazil), project NO 421581/2016–6 .

Materials scienceRecombination luminescenceBiophysics02 engineering and technologyElectron010402 general chemistry01 natural sciencesBiochemistryMolecular physicsRadiation defectsSpectral linelaw.inventionParamagnetismlawElectron paramagnetic resonance (EPR):NATURAL SCIENCES:Physics [Research Subject Categories]IrradiationElectron paramagnetic resonanceBaY2F8General Chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsAtomic and Molecular Physics and Optics0104 chemical sciencesOptically detected magnetic resonance (ODMR)0210 nano-technologyLuminescenceSingle crystalRecombinationJournal of Luminescence
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UV and X-ray excited red persistent luminescence in Mn2+ doped MgGeO3 material synthesized in air and reducing atmosphere

2021

Abstract Materials with long persistent luminescence (PersL) have caused widespread interest among scientists and industry for decades. Currently, there is widely available information on the long persistent luminescence materials with emission in the blue and green spectral range, while the number of publications on the afterglow in the red and near-infrared spectral range is considerably lower. In the course of this work MgGeO3 material doped with 0.1 mol% Mn2+ was produced using solid-state reaction synthesis in ambient and reducing atmospheres. The material exhibits a broad luminescence band with a peak around 680 nm, excited by either X-rays or UV. After cessation of irradiation, the a…

Materials scienceReducing atmosphereDopingBiophysics02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCondensed Matter PhysicsPhotochemistry01 natural sciencesBiochemistryAtomic and Molecular Physics and Optics0104 chemical sciencesAfterglowlaw.inventionPersistent luminescencelawExcited stateIrradiation0210 nano-technologyElectron paramagnetic resonanceLuminescenceJournal of Luminescence
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An EPR method for discriminating radiation beams in ammonium tartrate and tooth enamel

2008

The radiation linear energy transfer (LET), which is the energy released by ionizing radiation per path unit, arouses great scientific interest because the biological damage produced by ionizing radiation in tissues is strictly related to LET. Radiation beams with different LETs will cause different spatial energy distribution and therefore different effects inside matter. In the last twenty years the EPR spectroscopy has become a valuable dosimetric tool. This technique allows absorbed dose measurements through the detection of free radicals produced by ionizing radiation in organic and/or inorganic compounds. In this work we have analyzed the possibility of using the acquisition of two co…

Materials scienceRenewable Energy Sustainability and the EnvironmentHealth Toxicology and MutagenesisPublic Health Environmental and Occupational HealthLinear energy transferRadiationIonizing radiationlaw.inventionNuclear Energy and EngineeringlawAbsorbed doseDosimetryIrradiationAtomic physicsSafety Risk Reliability and QualityElectron paramagnetic resonanceAbsorption (electromagnetic radiation)Waste Management and DisposalRadioprotection
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Thermal effects of continuous laser treatment on Ti-6 Al(wt%)-4V(wt%) titanium alloy

2008

A titanium alloy Ti-6 Al(wt%)-4V(wt%) was treated in air by Nd:YAG laser radiation (wavelength of 1.064 %m) in continuous mode. Targets were irradiated globally with different levels of energy (accumulated fluence) at constant power. Different focal lengths and beam displacement velocities were used. Cross section microstructural observations were carried out by scanning electron microscopy. Backscattered electron imaging reveals microstructural modifications in samples. A structural phase transformation of beta (bcc) to alpha prime (hcp) phase was observed. The depth of the transformed zone observed by phase transformation is dependent on the treatment parameters. Conformity between micros…

Materials scienceScanning electron microscopeAlloyAnalytical chemistry02 engineering and technologyengineering.materialFluence[SPI.MECA.MEMA] Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of materials [physics.class-ph]law.invention[PHYS.MECA.MEMA]Physics [physics]/Mechanics [physics]/Mechanics of materials [physics.class-ph][PHYS.MECA.MEMA] Physics [physics]/Mechanics [physics]/Mechanics of materials [physics.class-ph]0203 mechanical engineeringlawPhase (matter)[SPI.MECA.MEMA]Engineering Sciences [physics]/Mechanics [physics.med-ph]/Mechanics of materials [physics.class-ph][CHIM.CRIS]Chemical Sciences/CristallographyGeneral Materials ScienceIrradiation[CHIM.CRIS] Chemical Sciences/CristallographyComputingMilieux_MISCELLANEOUSMechanical EngineeringMetallurgyTitanium alloy021001 nanoscience & nanotechnologyCondensed Matter PhysicsLaser[PHYS.COND.CM-MS] Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]Wavelength020303 mechanical engineering & transportsMechanics of Materialsengineering[PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci]0210 nano-technology
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Behaviour of advanced tritium breeder pebbles under simultaneous action of accelerated electrons and high temperature

2017

The authors greatly acknowledge the technical and experimen-tal support of O. Valtenbergs and L. Avotina (Institute of Chemical Physics, University of Latvia). The work is performed in the frames of the University of Latvia financed project No. Y9-B044-ZF-N-300, “Nano, Quantum Technologies, and Innovative Materials for Eco-nomics”.

Materials scienceScanning electron microscopeAnalytical chemistrychemistry.chemical_element01 natural sciences7. Clean energy010305 fluids & plasmaslaw.inventionchemistry.chemical_compoundBreeder (animal)law0103 physical sciencesRadiolysis:NATURAL SCIENCES:Physics [Research Subject Categories]Tritium breeding ceramicGeneral Materials ScienceIrradiationElectron paramagnetic resonanceCivil and Structural Engineering010302 applied physicsMechanical EngineeringLithium orthosilicateMicrostructureNuclear Energy and EngineeringchemistryTritiumLithiumOrthosilicateLithium metatitanateFusion Engineering and Design
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Preliminary study on the laser cleaning of stainless steels after high temperature oxidation

2000

Abstract The objective of the present work was to estimate the influence of pulsed laser irradiation on the removal of the oxide layer, which is developed on the surface of stainless steels during their exposure to high temperature oxidation. In general, this layer is a protective one, mainly against corrosion. However, in many manufacturing applications or maintenance work, the removal of the oxides is necessary; for example, the metallic surfaces should be cleaned before welding, otherwise the presence of oxides increases the tendency to brittle behaviour of the joint. In this study, a pulsed Nd:YAG laser (λ=1.064 μm, 10 ns) was used for the surface cleaning of three stainless steels with…

Materials scienceScanning electron microscopeMechanical EngineeringMetallurgyOxideWeldingCondensed Matter PhysicsLaserCorrosionlaw.inventionchemistry.chemical_compoundchemistryMechanics of MaterialslawGeneral Materials ScienceIrradiationSurface layerLayer (electronics)Materials Science and Engineering: A
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Tritium distribution and chemical forms in the irradiated beryllium pebbles before and after thermoannealing

2011

Abstract Beryllium pebbles are foreseen as a neutron multiplier in the tritium breeding blanket of the future fusion devices. Tritium inventory in the beryllium as a result of neutron-induced transmutations is a significant safety and technological issue for the operation of the breeding blanket. In this study, beryllium pebbles from 3 different irradiation experiments: BERYLLIUM, EXOTIC 8/3-13 and PBA, performed at High Flux Reactor HFR have been investigated. The distribution of tritium in the bulk of the pebbles and the abundance ratios of chemical forms of tritium T 0 , T + and T 2 have been analysed before and after the different thermo-annealing experiments. In order to determine the …

Materials scienceScanning electron microscopeMechanical EngineeringRadiochemistrychemistry.chemical_elementThermal treatmentBlanketNuclear physicsNuclear Energy and EngineeringchemistryGeneral Materials ScienceNeutronTritiumIrradiationBerylliumPebbleCivil and Structural EngineeringFusion Engineering and Design
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