Search results for "ISOTOPE"
showing 10 items of 2232 documents
Trophic structure of zooplankton / suprabenthos communities from the Galician and Cantabrian Coasts (NW Spain) by stable carbon and nitrogen isotope …
2007
Réponses du d13C au forçage astronomique dans divers contextes de production carbonatée : le cas du Valanginien du Sud-Est de la France
2018
International audience; Le d13C est un outil fréquemment utilisé pour établir des échelles de temps astronomiques en milieu (hémi-) pélagique. Pourtant le lien entre d13C et forçage astronomique n’est pas toujours clair, tant les sources de carbone sont multiples. Nous avons comparé le d13C à la susceptibilité magnétique (SM) et aux cortèges argileux dans les séries marno-calcaires du Valanginien du Bassin Vocontien (SE France). Ces deux signaux sont fréquemment utilisés pour détecter un forçage astronomique dans les alternances marno-calcaires. Deux intervalles de 400 ka (correspondant à un cycle de grande excentricité) ont été ciblés, l’un avant la crise des producteurs carbonatés associé…
Delayed and In-beam Spectroscopy on Francium and Astatine Nuclei at the Proton Drip Line
2011
Delayed and in‐beam spectroscopy on francium and astatine nuclei at and beyond the proton drip line has been performed. In neutron deficient astatine nuclei a shift to deformed shapes as a function of decreasing neutron has been obtained. In neutron deficient francium isotope the same shift is evident.
Hydrogeochemical multi-component approach to assess fluids upwelling and mixing in shallow carbonate-evaporitic aquifers (Contursi area, southern Ape…
2023
With the aim of deepening our understanding of deep-seated fluids upwelling and mixing in large regional aquifers, we performed a hydrogeochemical study of twenty-two springs in the Contursi area (upper Sele river valley, southern Apennines) by means of the measurements of chemical-physical parameters, major ions, trace elements, and stable and radioactive isotopes. Besides, we realized two updated geo-structural cross-sections in order to reconstruct the groundwater flowpath in the study area. The hydrogeochemical composition, as well as the water temperature allow to identify-three main groups of groundwater: Cold and Low salinity Groundwater (CLGW), Intermediate Salinity Groundwater (ISG…
Carboxylate catalyzed isomerization of β,γ‐unsaturated N-acetylcysteamine thioesters
2022
We demonstrate herein the capacity of simple carboxylate salts – tetrametylammonium and tetramethylguanidinium pivalate – to act as catalysts in the isomerization of β,γ-unsaturated thioesters to α,β-unsaturated thioesters. The carboxylate catalysts gave reaction rates comparable to those obtained with DBU, but with fewer side reactions. The reaction exhibits a normal secondary kinetic isotope effect ( k 1H / k 1D = 1.065±0.026) with a β,γ−deuterated substrate. Computational analysis of the mechanism provides a similar value ( k 1H / k 1D = 1.05) with a mechanism where γ-reprotonation of the enolate intermediate is rate determining. peerReviewed
Hydrogen isotopes (δ2H) of polyunsaturated fatty acids track bioconversion by zooplankton
2022
1. Organisms at the base of aquatic food webs synthesize essential nutrients, such as omega-3 polyunsaturated fatty acids (n-3 PUFA), which are transferred to consumers at higher trophic levels. Many consumers, requiring n-3 long-chain (LC) PUFA, such as eicosapentaenoic acid (EPA) and docosahexaenoic acid (DHA), have limited ability to biosynthesize them from the essential dietary precursor α-linolenic acid (ALA) and thus rely on dietary provision of LC-PUFA. 2. We investigated LC-PUFA metabolism in freshwater zooplankton using stable hydrogen isotopes (δ2H) of fatty acids as tracers. We conducted feeding experiments with the freshwater keystone grazer Daphnia to quantify changes in the δ2…
Benthic foodweb structure in a large shallow lake studied by stable isotope analysis
2014
The benthic foodweb structure of Lake Võrtsjärv, a large (270 km2), shallow, and turbid Estonian lake, was evaluated based on C and N stable-isotope signatures (δ13C, δ15N). Variation in δ13C between sampling sites was not related to site proximity to the littoral zone or the more vegetated southern part of the lake, but rather appeared to be influenced by in-situ site peculiarities. δ13C was stable temporally and between functional feeding groups, a result implying that the whole benthic food web of the lake relies largely on the same C source admixture, essentially particulate organic matter (POM). Thus, the foodweb composition of Lake Võrtsjärv is remarkably homogeneous given the lake’s …
Dependence of Arctic char (Salvelinus alpinus L.) on littoral and pelagic energy sources in a subarctic lake, Saanajärvi
2007
Production of a 15C radioactive ion beam based on 18O(n, α)
2019
In the context of the SPIRAL2 radioactive beam facility the production rate of the neutron-rich 15C nucleus by 18O(n,α) has been investigated. In a water target of 20 cm3, enriched in 18O and placed behind the neutron converter, a rate of a few 1010 nuclei per second can be reached with 1mA of 40MeV deuterons. A 18O(n,α) cross-section based on the activation method is proposed. It is intermediate between the highest and lowest evaluations available to date. peerReviewed