Search results for "ISOTOPE"
showing 10 items of 2232 documents
Contributions of autochthonous and allochthonous sources to dissolved organic matter in a large, shallow, eutrophic lake with a highly calcareous cat…
2013
We traced the origin of dissolved organic matter (DOM) in the large, shallow, eutrophic Lake Vortsjarv in Estonia. Allochthonous DOM (Al-DOM) had higher δ13C values than autochthonous DOM (Au-DOM). The δ13C of inflow DOM varied from −28.2‰ to −25.4‰ (mean −26.7‰) and in-lake DOM varied from −28.4‰ to −26.1‰ (mean −27.2‰). Low stable isotope (SI) signatures of Au-DOM were caused by relatively 13C-depleted values of its precursors (mainly phytoplankton) with mean δ13C of −28.9‰. SI signatures of dissolved inorganic carbon (DIC) in the inflows and in the lake were also relatively low (from −15.1‰ to −3.28‰). SI values of DOM were lower during the active growing season from May to September and…
Nitrogen sedimentation in a lake affected by massive nitrogen inputs: autochthonous versus allochthonous effects
2006
12 pages, and tables statics, and figures
A New Method to Reconstruct Quantitative Food Webs and Nutrient Flows from Isotope Tracer Addition Experiments
2020
Understanding how nutrients flow through food webs is central in ecosystem ecology. Tracer addition experiments are powerful tools to reconstruct nutrient flows by adding an isotopically enriched element into an ecosystem and tracking its fate through time. Historically, the design and analysis of tracer studies have varied widely, ranging from descriptive studies to modeling approaches of varying complexity. Increasingly, isotope tracer data are being used to compare ecosystems and analyze experimental manipulations. Currently, a formal statistical framework for analyzing such experiments is lacking, making it impossible to calculate the estimation errors associated with the model fit, the…
Oxygen isotope composition of natural waters in the Mt. Etna area
2004
Oxygen isotopes of both rainwater and groundwater samples from Mt Etna were used to obtain information on recharge areas, flow paths, and the origin of wet air masses. Oxygen isotope composition was determined in rainwater samples collected for a period of 3 years (October 1997– October 2000), in 11 rain-gauges distributed along the flanks of Mt Etna from sea level to 2900 m of altitude. Values ranged from 213.8 to þ 1.9‰, the lowest values being measured at higher altitudes and/or during cooler periods. For rain-gauges located from sea level up to 1000 m altitude, volume weighted values defined an isotopic gradient of 22.7‰/km, which is in the range observed in the Mediterranean area. High…
The impact of natural and anthropogenic factors on groundwater quality in an active volcanic/geothermal system under semi-arid climatic conditions: T…
2017
Abstract A comprehensive hydrogeochemical study of the cold and thermal groundwaters of the presently quiescent volcanic system at Methana was undertaken that involved collecting 71 natural water samples. Methana is a peninsula in Peloponnesus, Greece whose arid climate and hydrological situation is similar to that of the nearby small islands of the Aegean Sea. Similarly, the chemical and isotopic compositions of its water are dominated by the mixing of seawater with meteoric water both through direct intrusion and meteoric recharge. However, the simple mixing trends at Methana are modified by water–rock interaction processes, enhanced by the dissolution of endogenous CO2, which lead to str…
Apparent discrepancy in contamination history of a sub-tropical estuary evaluated through 210Pb profile and chronostratigraphical markers.
2005
Abstract Zn and Cd concentrations, stable lead isotopes and 210 Pb-derived chronology were determined in a sediment core sampled at Sepetiba Bay (South-eastern Brazil). During the last decades, the bay’s watershed has been modified by the increase of industrial activities and human interventions. In particular, Zn and Cd ore treatment plants were built near the coast in 1960 and 1970, respectively, and water has been diverted from the adjacent Paraiba do Sul River watershed since 1950. The core collected at shallow depth near the industrial area exhibits four successive events: (i) at 50 cm depth, a change in the 206 Pb/ 207 Pb ratio from about 1.162 to more than 1.18 might be the result of…
Stable isotopes of water as a tool to study groundwater–seawater interactions in coastal south-eastern Sicily
2009
Summary Stable isotopes of hydrogen (δD) and oxygen (δ 18 O) in groundwater, submarine springs and seawater collected in coastal south-eastern Sicily were investigated. While the spatial distribution of δ 18 O in groundwater showed that most of the heavy-isotope-depleted samples (from −5.7‰ to −6.9‰) were located in the higher portion of the Hyblean Mountains, more positive values (from −3.4‰ to −5.6‰) were found in the marginal areas. The isotope composition of submarine springs was characterized by significant variability (δ 18 O between −5.6‰ and +1.0‰ and δD between −30‰ and +5.0‰) reflecting seasonal variations and different seawater contributions. The isotopic and chemical composition…
Carbon isotope exchange between gaseous CO2 and thin solution films: Artificial cave experiments and a complete diffusion-reaction model
2017
Abstract Speleothem stable carbon isotope (δ 13 C) records provide important paleoclimate and paleo-environmental information. However, the interpretation of these records in terms of past climate or environmental change remains challenging because of various processes affecting the δ 13 C signals. A process that has only been sparsely discussed so far is carbon isotope exchange between the gaseous CO 2 of the cave atmosphere and the dissolved inorganic carbon (DIC) contained in the thin solution film on the speleothem, which may be particularly important for strongly ventilated caves. Here we present a novel, complete reaction diffusion model describing carbon isotope exchange between gase…
Geochemical and hydrogeological characterization of thermal springs in Western Sicily, Italy
1998
Abstract Thermal and cold waters from Castellammare–Alcamo (Western Sicily-Italy) were collected between May 1994 and May 1995 and studied for their chemical and isotopic composition. During the same period, mean monthly samples of meteoric water were also collected and measured for their isotopic composition. The main purpose of this study was the characterization of the acquifers and, if possible, of their recharge areas. According to the results obtained, the acquifers were divided into three main groups: (a) selenitic waters, (b) cold carbonatic waters, and (c) deep thermal waters resulting from the mixing of the other two types. Besides a mixing process between carbonatic and selenitic…
Characterisation of submarine groundwater discharge offshore south-eastern Sicily
2005
A complex approach in characterisation of submarine groundwater discharge (SGD) off south-eastern Sicily comprising applications of radioactive and non-radioactive tracers, direct seepage measurements, geophysical surveys and a numerical modelling is presented. SGD fluxes in the Donnalucata boat basin were estimated by direct seepage measurements to be from 4 to 12Ls(-1), which are comparable with the total SGD flux in the basin of 17Ls(-1) obtained from radon measurements. The integrated SGD flux over the Donnalucata coast estimated on the basis of Ra isotopes was around 60m(3)s(-1) per km of the coast. Spatial variations of SGD were observed in the Donnalucata boat basin, the average (222…