Search results for "ISOTOPES"
showing 10 items of 1216 documents
Anthropogenic lead distribution in soils under arable land and permanent grassland estimated by Pb isotopic compositions
2008
International audience; The role of land use on fate of metals in soils is poorly understood. In this work, we studied the incorporation of lead in two neighboring soils with comparable pedogenesis but under long-term different agricultural management. Distributions of anthropogenic Pb were assessed from concentrations and isotopic compositions determined on bulk horizon samples, systematical 5–10 cm increment samples, and on 24-h EDTA extracts. Minor amounts of anthropogenic lead were detected until 1-m depth under permanent grassland, linked to high earthworm activity. In arable land, exogenous Pb predominantly accumulated at depths <60 cm. Although the proximity between the two sites ens…
Understanding volcanoes in the Vanuatu arc
2016
We report the first helium isotope survey of volcanic gases, hot springs and some olivine phenocrysts along the Vanuatu island arc, from Tanna in the south to Vanua Lava in the north. Low CO2 content and low He-3/He-4 ratios in thermal fluids of Epi (4.0 +/- 0.1 R-a), Efate (4.5 +/- 0.1 R-a) and Pentecost (5.3 +/- 0.5 R-a) islands coherently indicate reduced mantle gas leakage and crustal contamination by radiogenic helium on these extinct volcanic systems of the former (Pliocene) arc. Instead, presently active Vanuatu volcanoes display He-3/He-4 and C/He-3 ratios typical of subduction-related volcanic arcs: He-3/He-4 ratios range from 6.4 +/- 0.5 Ra in southernmost Tanna and 7.23 +/- 0.09 …
The imprint of subduction fluids on subducted MORB-derived melts (Sierra del Convento Mélange, Cuba)
2011
International audience; Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE…
Abiotic and biotic controls on methane formation down to 2.5 km depth within the Precambrian Fennoscandian Shield
2017
Abstract Despite a geological history characterised by high temperature and pressure processes and organic carbon deprived crystalline bedrock, large amounts of hydrocarbons are found in deep groundwaters within Precambrian continental shields. In many sites, methane comprises more that 80% of the dissolved gas phase reaching concentrations of tens of mmol l −1 . In this study, we used isotopic methods to study the carbon isotope systematics and sources of crustal methane within the Fennoscandian Shield. The main study sites were the Outokumpu Deep Drill Hole and the Pyhasalmi mine in Finland, both of which allow groundwater sampling down to 2.5 km depth and have been previously studied for…
Geodynamic control on carbonate diagenesis: Petrographic and isotopic investigation of the Upper Jurassic formations of the Paris Basin (France).
2007
23 pages; International audience; The Oxfordian and Kimmeridgian carbonates of the eastern edge of the Paris Basin display poor reservoir properties (Φb15% and Kb0.1 md). The petrographic investigation and the resultant paragenetic sequence show that this is due to extensive precipitation of 2 types of almost synchronous blocky LMC (Low Magnesian Calcite) cements during mesogenesis (burial). Stable isotope investigation of these non-recrystallized cements, through both microdrilling sampling and in-situ SIMS (Secondary IonMass Spectrometry) analysis, shows that they originated from slightly buffered meteoric fluids (−3‰SMOW to −8‰SMOW) flowing through the Malm carbonate aquifers of the east…
Black shale deposition during Toarcian super-greenhouse driven by sea level
2013
Abstract. One of the most elusive aspects of the Toarcian oceanic anoxic event (T-OAE) is the paradox between carbon isotopes that indicate intense global primary productivity and organic carbon burial at a global scale, and the delayed expression of anoxia in Europe. During the earliest Toarcian, no black shales were deposited in the European epicontinental seaways, and most organic carbon enrichment of the sediments postdated the end of the overarching positive trend in the carbon isotopes that characterises the T-OAE. In the present study, we have attempted to establish a sequence stratigraphic framework for Early Toarcian deposits recovered from a core drilled in the Paris Basin using a…
Evolution of the neodymium isotopic signature of neritic seawater on a northwestern Pacific margin: new constrains on possible end-members for the co…
2013
11 pages; International audience; The Neodymium(Nd) isotope composition of fish remains has beenwidely used to track past changes in oceanic circulation. Although the number of published Nd isotope data for the Cretaceous has markedly increased in the last years, no consensus has been reached on the structure of the oceanic circulation and its evolution during the Late Cretaceous. Yet this period is characterised bymajor geodynamical and climatic changes andmarked by the disappearance of global oceanic anoxic events inwhich changes in oceanic circulation modesmay have played a significant role. In this study we present the first record of Nd isotopic composition of fish remains from contine…
13C composition of dissolved organic carbon in upland forested catchments of the Morvan Mountains (France): Influence of coniferous and deciduous veg…
2007
10 pages; International audience; One of the main environmental changes caused by human activities is that of land use. These changes influence the quantity and quality of the dissolved organic matter (DOM) fluxes through the vegetation–soil–stream system. The aim of this work is to evaluate the influence of the substitution of native deciduous forests by well managed coniferous forests on dissolved organic carbon (DOC) fluxes and their associated carbon isotopic composition (d13CDOC). DOC fluxes and d13CDOC were monitored for 2 years in the streams of four similar upland forested catchments in the Morvan Mountains (France). Mean annual DOC concentrations and fluxes were 2–4 times lower in …
Rare earth element and neodymium isotope tracing of sedimentary rock weathering
2020
Chemical weathering plays an important role in sequestering atmospheric CO2, but its potential influence on global climate over geological timescales remains debated. To some extent, this uncertainty arises from the difficulty in separating the respective contribution of sedimentary and crystalline silicate rocks to past weathering rates in the geological record; two types of rocks having presumably different impact on the long-term carbon cycle. In this study, we investigate the use of rare earth element (REE) and neodymium isotopes (εNd) in leached iron oxide fractions of river sediments for tracing the origin of weathered rocks on continents. A new index, called ‘concavity index’ (CI), i…
In situ carbon and oxygen isotopes measurements in carbonates by fiber coupled laser diode-induced calcination: A step towards field isotopic charact…
2021
International audience; Natural stable isotopes ratios (δ13Ccarb and δ18Ocarb) of carbonates archived in the geological record are routinely used to reconstruct local and global paleo temperatures and the secular evolution of the biogeochemical carbon cycle. The state-of-the-art technique, employed since the mid 20th century, to measure these isotopic ratios starts with field sampling followed by several steps of physical and chemical laboratory preparation including: (i) microdrilling and/or sawing and crushing, (ii) CO2 release by wet acid digestion, (iii) gas equilibration, purification and transfer, before (iv) gas phase IRMS measurements. While these steps are time and resource consumi…