Search results for "ISOTOPES"
showing 10 items of 1216 documents
THE EVALUATION OF STABLE ISOTOPIC RATIOS 13C AND 15N IN HUMIC ACIDS ALONG A FEN PEAT PROFILE
2019
Mires are known as consistent environmental archives, but humic acids are the fraction of peat that is most recalcitrant and refractory to organic matter degradation, thus data on environmental changes during mire development can be recorded into them. This work was focused on the studies of stable isotopic ratios delta carbon-13 and delta nitrogen-15, and their distribution in humic acids within fen peat layers of different depths and peat composition. The variations in delta carbon-13 reflect isotopic variations in peat-forming plants over time and can be considered as a function of photosynthetic pathway that is being used to fix carbon dioxide. At the same time, variations in delta nitr…
Stable isotope profiles of nitrogen gas indicate denitrification in oxygen-stratified humic lakes
2011
Mid-summer N(2) profiles were analyzed from nine oxygen-stratified, humic-acid-rich lakes using a continuous flow isotope ratio mass spectrometer and a Gasbench II device. Sample preparation steps were performed under water to avoid air contamination. The instrument precision for the δ(15)N measurement was high (0.03‰), but for the whole sampling and analysis procedure the mean deviation between replicate samples was 0.13‰ for the δ(15)N measurements and 5.5% for the N(2) gas concentration analysis. The results show that the Gasbench peripheral was suitable for measurement of the (15)N natural abundance of dissolved nitrogen gas, with denitrification indicated by the oversaturation and slig…
Influence of15N enrichment on the net isotopic fractionation factor during the reduction of nitrate to nitrous oxide in soil
2007
5 pages; International audience; Nitrous oxide, a greenhouse gas, is mainly emitted from soils during the denitrification process. Nitrogen stable-isotope investigations can help to characterise the N(2)O source and N(2)O production mechanisms. The stable-isotope approach is increasingly used with (15)N natural abundance or relatively low (15)N enrichment levels and requires a good knowledge of the isotopic fractionation effect inherent to this biological mechanism. This paper reports the measurement of the net and instantaneous isotopic fractionation factor (alpha(s/p) (i)) during the denitrification of NO(3) (-) to N(2)O over a range of (15)N substrate enrichments (0.37 to 1.00 atom% (15)…
Insights into the effect of soil pH on N(2)O and N(2) emissions and denitrifier community size and activity.
2010
ABSTRACT The objective of this study was to investigate how changes in soil pH affect the N 2 O and N 2 emissions, denitrification activity, and size of a denitrifier community. We established a field experiment, situated in a grassland area, which consisted of three treatments which were repeatedly amended with a KOH solution (alkaline soil), an H 2 SO 4 solution (acidic soil), or water (natural pH soil) over 10 months. At the site, we determined field N 2 O and N 2 emissions using the 15 N gas flux method and collected soil samples for the measurement of potential denitrification activity and quantification of the size of the denitrifying community by quantitative PCR of the narG , napA ,…
Development of an ICP-IDMS method for accurate routine analyses of toxic heavy metals in polyolefins and comparison with results by TI-IDMS
2000
An inductively coupled plasma isotope dilution mass spectrometric (ICP-IDMS) method was developed as a suitable method - with respect to its sensitivity, precision, accuracy, and time-consumption - for the analysis of toxic heavy metal traces (Pb, Cd, Cr, and Hg) in polyolefins. Results for Pb, Cd, and Cr were compared with those obtained by thermal ionization isotope dilution mass spectrometry (TI-IDMS), which was used as a reference method. Because of its high first ionization potential and its high volatility mercury could not be determined by TI-IDMS. A multi-element spike solution, containing isotopically enriched 206Pb, 116Cd, 53Cr, and 201Hg, was used for the isotope dilution step. D…
Identification of ground water contaminations by landfills using precise boron isotope ratio measurements with negative thermal ionization mass spect…
1997
Precise boron isotope ratio measurements with negative thermal ionization mass spectrometry were used for the identification of ground water contaminations by leakages of landfills. BO 2 - thermal ions were produced to determine the 11 B/ 10 B isotope ratio, which was expressed as δ 11 B value in ‰ normalized to the standard reference material NIST SRM 951. For example, household waste influences the boron isotope ratio by specific components such as washing powder. In the case of one investigated landfill low δ 11 B values correlate well with high boron concentrations in contaminated seepage water samples and vice versa for uncontaminated ground water samples. Possible boron contributions …
Species-Specific GC/ICP-IDMS for Trimethyllead Determinations in Biological and Environmental Samples
2005
An accurate and sensitive species-specific isotope dilution GC/ICPMS method was developed for the determination of trimethyllead (Me3Pb+) in biological and environmental samples. A trimethyllead spike was synthesized from 206Pb-enriched metallic lead by reaction of lead halide with methyllithium and subsequent formation of trimethyllead iodide. The isotopic composition of the spike solution was determined by GC/ICPMS after derivatization with tetraethylborate, and its concentration was determined by reverse isotope dilution analysis. The species-specific GC/ICP-IDMS method was validated by reference material CRM 605 (urban dust) certified for Me3Pb+. The method was also applied to determine…
The fate of organic matter sources in coastal environments: a comparison of three Mediterranean lagoons
2008
Trophic processes in coastal lagoons are strongly influenced by freshwater inputs and water exchanges with the sea. In recent years, stable isotope analysis has become a widespread and reliable method for the examination of trophic structure over time and space, also in complex ecosystems such as coastal lagoons. Stable isotopes of carbon and nitrogen were studied in primary producers and consumers to identify organic matter source pools from terrestrial, benthic and pelagic environments and to characterise the trophic structure in three Mediterranean coastal lagoons (Lake Fusaro, the Lake of Sabaudia and Stagnone di Marsala). The results highlighted the negligible importance of terrestrial…
In vivo comparison of DOTA based 68Ga-labelled bisphosphonates for bone imaging in non-tumour models.
2013
Bone metastases are a class of cancerous metastases that result from the invasion of a tumor into bone. The solid mass which forms inside the bone is often associated with a constant dull ache and severe spikes in pain, which greatly reduce the quality of life of the patient. Numerous (99m)Tc-labeled bisphosphonate functionalised complexes are well established tracers for bone metastases imaging. The objective of this research was to evaluate the pharmacokinetics and behaviour of three DOTA based bisphosphonate functionalised ligands (BPAMD, BPAPD and BPPED), using both (68)Ga μ-PET in vivo imaging and ex vivo biodistribution studies in healthy Wistar rats. The compounds were labelled with …
Exploring the mass surface near the rare-earth abundance peak via precision mass measurements at JYFLTRAP
2019
The JYFLTRAP double Penning trap at the Ion Guide Isotope Separator On-Line (IGISOL) facility has been used to measure the atomic masses of 13 neutron-rich rare-earth isotopes. Eight of the nuclides, $^{161}$Pm, $^{163}$Sm, $^{164,165}$Eu, $^{167}$Gd, and $^{165,167,168}$Tb, were measured for the first time. The systematics of the mass surface has been studied via one- and two-neutron separation energies as well as neutron pairing-gap and shell-gap energies. The proton-neutron pairing strength has also been investigated. The impact of the new mass values on the astrophysical rapid neutron capture process has been studied. The calculated abundance distribution results in a better agreement w…