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Biological tolerance of different materials in bulk and nanoparticulate form in a rat model: sarcoma development by nanoparticles

2006

In order to study the pathobiological impact of the nanometre-scale of materials, we evaluated the effects of five different materials as nanoparticulate biomaterials in comparison with bulk samples in contact with living tissues. Five groups out of 10 rats were implanted bilaterally for up to 12 months with materials of the same type, namely TiO 2 , SiO 2 , Ni, Co and polyvinyl chloride (PVC), subcutaneously with bulk material on one side of the vertebral column and intramuscularly with nanoparticulate material on the contralateral side. At the end of each implantation time, the site was macroscopically examined, followed by histological processing according to standard techniques. Malign…

Navigation accuracy after automatic- and hybrid-surface registration in sinus and skull base surgery.

2016

Objective Computer-aided-surgery in ENT surgery is mainly used for sinus surgery but navigation accuracy still reaches its limits for skull base procedures. Knowledge of navigation accuracy in distinct anatomical regions is therefore mandatory. This study examined whether navigation accuracy can be improved in specific anatomical localizations by using hybrid registration technique. Study design Experimental phantom study. Setting Operating room. Subjects and methods The gold standard of screw registration was compared with automatic LED-mask-registration alone, and in combination with additional surface matching. 3D-printer-based skull models with individual fabricated silicone skin were u…

Digital Hydraulic Technology for Linear Actuation:A State of the Art Review

2020

This paper analyses the current state of the art in linear actuation with digital hydraulics. Based on the differences in their aims the paper partitions the area into four actuation concepts – parallel valve solutions, single switching valve solutions, multi-chamber cylinders, and multi-pressure cylinders. The concepts are evaluated based on accuracy and smoothness of motion, switching load, reliability, efficiency and the number of components required.

Bi-Sobolev extensions

2022

We give a full characterization of circle homeomorphisms which admit a homeomorphic extension to the unit disk with finite bi-Sobolev norm. As a special case, a bi-conformal variant of the famous Beurling-Ahlfors extension theorem is obtained. Furthermore we show that the existing extension techniques such as applying either the harmonic or the Beurling-Ahlfors operator work poorly in the degenerated setting. This also gives an affirmative answer to a question of Karafyllia and Ntalampekos.

Analytic capacity and quasiconformal mappings with $W^{1,2}$ Beltrami coefficient

2008

We show that if $\phi$ is a quasiconformal mapping with compactly supported Beltrami coefficient in the Sobolev space $W^{1,2}$, then $\phi$ preserves sets with vanishing analytic capacity. It then follows that a compact set $E$ is removable for bounded analytic functions if and only if it is removable for bounded quasiregular mappings with compactly supported Beltrami coefficient in $W^{1,2}$.

Hölder continuity of Sobolev functions and quasiconformal mappings

1993

Luminescence properties of III-V multi-junctions solar cells

2012

The recent achievement of multi-junctions solar cells, based on III-V semiconductors, exceeding 43% efficiency, has stimulated a rapid growth of concentration photovoltaic (CPV) technology. The large efficiency of these cells is based on the matching between the semiconductors band gap and the solar spectrum and the capability of working under concentrated illumination, up to ~1000 suns. The research pays, therefore, attention to investigate in detail the mechanisms that affect the conversion efficiency, such as the non radiative losses that increase the cell temperature thus favoring the electron-hole (e-h) recombination. With the aim to clarify the performances of these III-V cells, here …

The origin of slow electron recombination processes in dye-sensitized solar cells with alumina barrier coatings

2004

We investigate the effect of a thin alumina coating of nanocrystalline TiO2 films on recombination dynamics of dye-sensitized solar cells. Both coated and uncoated cells were measured by a combination of techniques: transient absorption spectroscopy, electrochemical impedance spectroscopy, and open-circuit voltage decay. It is found that the alumina barrier reduces the recombination of photoinjected electrons to both dye cations and the oxidized redox couple. It is proposed that this observed retardation can be attributed primarily to two effects: almost complete passivation of surface trap states in TiO2 that are able to inject electrons to acceptor species, and slowing down by a factor of…

Halogen exchange and expulsion: ligand stabilized dihalogen silicon dications

2000

The first ligand stabilized SiCl22+ dications were synthesized using N-methylimidazole as co-ordinating ligand. The compounds SiCl4, SiBr2Cl2, and SiH2Cl2 form six-co-ordinated dicationic compounds of almost octahedral symmetry with similar structures which were investigated by single crystal X-ray analysis and density functional calculations. The structures exhibit particularly short dative Si–N bonds of about 1.90 A. Complexes crystallized from the same solvent are isostructural. A different solvent, though, leads to geometrical variations. It was also discovered that the halogen exchange process among mixed silicon tetrahalides occurs under much milder conditions than previously thought …

Sensitizer exchange dynamics in air and solvent filled semiconductor nanocavities

2010

Multiple dye binding sites and their exchange in equilibrium in air and solvent filled sensitized titanium oxide nanocavities were identified by 2DIR spectroscopy. Binding geometry and flexibility may influence electron injection efficiency of solar cells.