Search results for "Inde"
showing 10 items of 7365 documents
Single-Component Polymerization Catalysts for Ethylene and Styrene: Synthesis, Characterization, and Reactivity of Alkyl and Hydrido Yttrium Complex…
1999
Yttrium alkyl complexes Y(η5:η1-C5Me4SiMe2NCMe2R)(CH2SiMe3)(THF) (R = Me, Et) and Y(η5:η1-C9H6SiMe2NCMe3)(CH2SiMe3)(THF) can be prepared in high yields by a σ-bond metathesis reaction between Y(CH2SiMe3)3(THF)2 and amino-functionalized cyclopentadienes or indene. The structure of Y(η5:η1-C5Me4SiMe2NCMe2Et)(CH2SiMe3)(THF) was shown by single-crystal X-ray diffraction to be that of a three-legged piano stool. Reaction of Y(CH2SiMe3)3(THF)2 with the tridentate linked amido−cyclopentadienyl ligands (C5Me4H)SiMe2NHR (R = CH2CH2OMe, CH2CH2NMe2, CH2CH2CH2OMe, CMe2CH2OMe), which contain an additional donor site, results in the cleavage of the silicon−cyclopentadienyl bond and the formation of the t…
Infrared spectroscopy on lead silicate glass
1993
The reflectance spectra of some lead silicate glasses of general formula (PbO)x(SiO2)y have been measured in the infrared frequency range from 50 to 4000 cm−1. The dispersion and absorption spectra in the range 50–2000 cm−1 have been calculated from the reflectance data using the Kramers-Kronig relations. The band at ∼ 135 cm−1 is assigned to the stretching vibration of lead-oxygen bonds. The shoulder band of the silicon-oxygen stretching mode at ∼900 cm−1 shows a weak coupling of those bonds to the Pb2+ modifier. The vibration strength of those bands shows that the number of the Pb2+ modifier increases first up approximately to 50 Mol% with the increase of PbO content and then decreases ra…
Hybrid silicon on insulator/polymer electro-optical intensity modulator operating at 780 nm
2014
Currently inorganic materials prevail as the nonlinear active medium for light modulation in electro-optical (EO) device technology. A recent promising trend is to consider organic nonlinear optical materials for application in EO modulators due to their multiple advantages including low costs and high EO coefficients. In this paper, we proposed a new type of polymer EO modulator whose fabrication is compatible with the currently used silicon on insulator technology. Our numerical optimization of the proposed structure demonstrates that it is theoretically possible to achieve a half-wave voltage as low as 1.56 V for a 1 cm long modulator structure operating at 780 nm. Based on the results o…
Pearl-necklace structures of molecular brushes with rigid backbone under poor solvent conditions: A simulation study
2010
Bottle-brush polymers, where flexible side chains containing N=20 to 50 effective monomers are grafted to a rigid backbone, are studied by molecular dynamics simulations, varying the grafting density σ and the solvent quality. Whereas for poor solvents and large enough σ the molecular brush is a cylindrical object, homogeneous in axial direction, for intermediate values of σ an axially inhomogeneous structure of "pearl-necklace" type is formed. The "pearls," however, have a strongly nonspherical ellipsoidal shape, due to the fact that several side chains cluster together in one pearl, qualitatively consistent with predictions of Sheiko et al. [Eur. Phys. J. E 13, 125 (2004)] We analyze the …
Effect of stress and temperature on the thermomechanical degradation of a PE-LD/OMMT nanocomposites
2014
Thermomechanical degradation of nanocomposites is a topical issue that has not been fully investigated as demonstrated by the low number of papers available in the literature regarding this spe- cific aspect. In particular, with regards to low density polyethylene/clay nanocomposites, the degrada- tion behavior is very complex since it involves the degradation paths of both the polymer matrix and the organomodified nanoclay. In the present work, the effects of mechanical stress and temperature on the thermomechanical behavior of PE-LD/organomodified clay nanocomposites and the degradation paths were investigated by rheological, FT-IR and mechanical methods. The results have shown that the t…
Accurately evaluating Young’s modulus of polymers through nanoindentations: a phenomenological correction factor to the Oliver and Pharr procedure
2006
The Oliver and Pharr [J. Mater. Res. 7, 1564 (1992)] procedure is a widely used tool to analyze nanoindentation force curves obtained on metals or ceramics. Its application to polymers is, however, difficult, as Young’s moduli are commonly overestimated mainly because of viscoelastic effects and pileup. However, polymers spanning a large range of morphologies have been used in this work to introduce a phenomenological correction factor. It depends on indenter geometry: sets of calibration indentations have to be performed on some polymers with known elastic moduli to characterize each indenter.
Photoreactive Langmuir–Blodgett–Kuhn multilayer assemblies from functionalized liquid-crystalline side chain polymers, I. Homopolymers containing azo…
1991
Stable monomolecular layers of a liquid-crystalline homopolymer bearing azobenzene chromophores in the mesogenic side groups could be prepared at the water–air interface by slow compression at room temperature. From the area per monomer unit of A0≈0.25 nm2 a structural model with tightly packed azobenzene groups oriented nearly parallel to the surface normal was deduced. After transfer to a solid support in a Y-type mode the obtained Langmuir–Blodgett–Kuhn (LBK) multilayer assemblies of varying thicknesses (from a double layer to a thick film of d = 238 nm, capable of guiding optical modes) were prepared and analyzed by X-ray reflection and optical evanescent wave techniques. A monolayer th…
Liquid crystal polymer-based blends: “Universal grade” polymers?
1992
Polymeric materials can be easily processed with different processing operations thanks to suitable rheological properties. Melt flow index, or grade, which is a measure of the fluidity of the polymers, is the most commonly parameter used to characterize the polymers from the point of view of their melt viscosity. Injection molding requires high grade materials, whereas low grade values are best suited for extrusion. Of course, it would be no doubt of interest if single “universal grade” materials could be used for all processing operations. In this paper it is demonstrated that the blends of low grade polymers with small amounts of liquid crystal polymers can be conveniently used for all p…
Indentation test as a tool for monitoring the solidification process during injection molding
2003
An inline method for monitoring the solidification process during the injection molding of semicrystalline polymers is demonstrated. The method has been applied to various poly(ethylene terephthalate) (PET) and poly(buthylene terephthalate) (PBT) samples. The technique is based on a simple device by which an additional ejector pin is pushed onto the injection-molded part with a fixed force at different times during the solidification phase while the mold remains closed. The residual deformation (the so-called indentation depth) due to the applied load is measured offline after ejection. By the performance of indentation at different times during the cooling phase, an indentation depth profi…
Composites of ethylene-vinyl acetate copolymers with modified magnesium hydroxide-thermo-oxidative ageing
2014
Flame retardant composites must perform their protective roles permanently, also under conditions of intermittent or long-term exposure to sunlight, moisture or increased temperature. The aim of our work was characterization of the thermo-oxidative ageing (90 °C) and the changes in flammability of ethylene-vinyl acetate copolymer composites with 40 and 60 wt.% of magnesium hydroxide. The neat polymer and its composites were investigated for their thermal (DSC) and structural (FTIR) characteristics as well as their density, melt flow index, tensile properties and combustibility during ageing test. As FTIR results identified the different carbonyl groups in copolymer were created, the highest…