Search results for "Infrared"

showing 10 items of 2110 documents

Vibrational Spectrum of HXeSH revisited : Combined computational and experimental study

2020

Vibrational spectrum of HXeSH embedded in low-temperature matrix is experimentally studied. To support the spectrum interpretation, anharmonic vibrational analysis is performed using different models and basis sets and the data is compared with previous experimental and theoretical analyses. Computations of overtones and combination modes allowed for new band assignments. The HXeSH molecule exhibits high anharmonicity similarly as other molecules from the noble-gas hydride family. Comparison of the employed computational methods shows once again that the modelling of the noble-gas compounds faces theoretical challenges to yield quantitatively reliable results. peerReviewed

noble gasXenonInfraredspektroskopiaGeneral Physics and AstronomyInfrared spectroscopyksenonhydride02 engineering and technology010402 general chemistry01 natural sciencesMolecular physicsMatrix (mathematics)värähtelytinfrapunasäteilyMoleculePhysical and Theoretical ChemistryPhysics::Chemical PhysicsPhysicsBasis (linear algebra)anharmonicityAnharmonicityMatrix isolationmatrix isolationjalokaasut021001 nanoscience & nanotechnologylaskennallinen kemiacomputational chemistryvibrational spectroscopy0104 chemical sciencesinfrared spectrumYield (chemistry)hydridit0210 nano-technology
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High-resolution spectrum of La and Ar

2013

A high-resolution spectrum of lanthanum has been recorded by a Fourier Transform spectrometer in the wavelength range from 833nm to 1666nm (6000/cm to 12000/cm) using as light source a hollow cathode lamp operated with argon as the discharge carrier gas. In total, 2386 spectral lines were detected in this region, of which 555 lines could be classified as La I transitions and 10 lines as La II transitions. All La II transitions and 534 of these La I transitions were classified for the first time, and 6 of the La II transitions and 433 of the classified La I transitions appear to be new lines, which could not be found in the literature. The corresponding energy level data of classified lines …

observational astronomyAstrophysics and AstronomyInfrared astronomyPhysicsNatural SciencesSpectroscopyInterdisciplinary AstronomyAtomic physics
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Gaia-ESO Survey: Li-rich stars in NGC2547

2015

The nearby (distance ~350-400pc), rich Vela OB2 association, includes gamma^2^ Velorum, one of the most massive binaries in the solar neighborhood, and is an excellent laboratory for investigating the formation and early evolution of young clusters. Recent Gaia-ESO survey observations led to the discovery of two kinematically distinct populations in the young (10-15Myr) cluster immediately surrounding gamma^2^ Velorum. Here we analyse the results of Gaia-ESO survey observations of NGC 2547, a 35Myr cluster located two degrees south of gamma^2^ Velorum. The radial velocity distribution of lithium-rich pre-main sequence stars shows a secondary population, kinematically distinct and younger th…

observational astronomyOpen star clustersPhotometryAstrophysics and AstronomyStellar AstronomyPhysicsS starsNatural SciencesInfrared photometrySpectroscopyOptical astronomy
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Photometry of candidate members of NGC6611

2009

We present the list of candidate members of the young open cluster NGC 6611, selected in a field of view of 33'x34' by the X-rays emission and excesses in infrared bands. X-ray sources without infrared excesses are classified as candidate Class III cluster members; stars with infrared excesses as disk bearing members. Cone search capability for table J/A+A/496/453/catalog (NGC 6611 cluster member positions and magnitudes)

observational astronomyOpen star clustersPhotometryAstrophysics and AstronomyStellar AstronomyPhysicsWide-band photometryNatural SciencesInfrared photometryWide band photometryOptical astronomy
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VRIJHK observations of PKS 2155-304

2008

Spectral variability is the main tool for constraining emission models of BL Lac objects. By means of systematic observations of the BL Lac prototype PKS 2155-304 in the infrared-optical band, we explore variability on the scales of months, days and hours. We made our observations with the robotic 60cm telescope REM located at La Silla, Chile. VRIJHK filters were used. PKS 2155-304 was observed from May to December 2005. The wavelength interval explored, the total number of photometric points and the short integration time render our photometry substantially superior to previous ones for this source. On the basis of the intensity and colour we distinguish three different states of the sourc…

observational astronomyPhotometrygalactic and extragalactic astronomyAstrophysics and AstronomyPhysicsBL Lacertae objectsWide-band photometryNatural SciencesInfrared photometryWide band photometryOptical astronomy
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Optical Absorption of Excimer Laser‐Induced Dichlorine Monoxide in Silica Glass and Excitation of Singlet Oxygen Luminescence by Energy Transfer from…

2021

An optical absorption (OA) band of interstitial dichlorine monoxide molecules with peak at 4.7 eV and halfwidth 0.94 eV is identified in F2 laser - irradiated (photon energy=7.9 eV) synthetic silica glass bearing both interstitial O2 and Cl2 molecules. Alongside with intrinsic defects, this OA band can contribute to solarization of silica glasses produced from SiCl4. While the formation of ClClO is confirmed by its Raman signature, its structural isomer ClOCl may also contribute to this induced OA band. Thermal destruction of this band between 300C and 400C almost completely restores the pre-irradiation concentration of interstitial Cl2. An additional weak OA band at 3.5 eV is tentatively a…

optical absorptionMaterials scienceInfraredinterstitial chlorinemedicine.medical_treatmentFOS: Physical sciencesPhoton energyPhotochemistrysinglet oxygenchemistry.chemical_compoundsymbols.namesakesilica glassMaterials ChemistrymedicineElectrical and Electronic Engineering[PHYS]Physics [physics]Condensed Matter - Materials ScienceExcimer laserSinglet oxygenMaterials Science (cond-mat.mtrl-sci)Surfaces and InterfacesCondensed Matter PhysicsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDichlorine monoxidechemistryglass nanovoidssymbolschlorine oxidesluminescenceactivationAbsorption (chemistry)Raman spectroscopyLuminescence
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Synthesis, Optical, and Morphological Studies of ZnO Powders and Thin Films Fabricated by Wet Chemical Methods

2020

Zinc oxide nanoparticles were prepared from Zn5(CO3)2(OH)6 precursor, capped with poly(vinylpyrrolidone) (PVP), and annealed at 600 &deg

optical propertiesMaterials scienceScanning electron microscopeAnalytical chemistryNanoparticleInfrared spectroscopy02 engineering and technology010402 general chemistrylcsh:Technology01 natural sciencesArticlesymbols.namesakeMicroscopyGeneral Materials ScienceThin filmlcsh:MicroscopyThermal analysisComputingMilieux_MISCELLANEOUSlcsh:QC120-168.85[PHYS]Physics [physics][PHYS.PHYS.PHYS-OPTICS]Physics [physics]/Physics [physics]/Optics [physics.optics]lcsh:QH201-278.5lcsh:T021001 nanoscience & nanotechnology0104 chemical scienceswet chemical methodsthin filmspoly(vinylpyrrolidone)lcsh:TA1-2040Transmission electron microscopyZnOsymbolsnanoparticleslcsh:Descriptive and experimental mechanics[PHYS.PHYS.PHYS-CHEM-PH]Physics [physics]/Physics [physics]/Chemical Physics [physics.chem-ph]lcsh:Electrical engineering. Electronics. Nuclear engineeringlcsh:Engineering (General). Civil engineering (General)0210 nano-technologyRaman spectroscopylcsh:TK1-9971poly(vinylpyrrolidone) optical propertiesMaterials
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Influence of PDA Coating on the Structural, Optical and Surface Properties of ZnO Nanostructures

2020

Polydopamine (PDA) is a new biocompatible material, which has prospects in biomedical and sensor applications. Due to functional groups, it can host wide range of biomolecules. ZnO nanostructures are well known templates for optical sensors and biosensors. The combination of ZnO and PDA results in a change of optical properties of ZnO&ndash

optical sensorsMaterials sciencePhotoluminescenceNanostructureNanocompositeGeneral Chemical Engineeringengineering.materialArticlelcsh:Chemistryfundamental propertiessymbols.namesakeAdsorptionlcsh:QD1-999CoatingChemical engineeringengineeringsymbolsGeneral Materials ScienceDiffuse reflectionZnO–polydopamine nanocompositesFourier transform infrared spectroscopyRaman spectroscopyNanomaterials
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Optimal Spectral Wavelengths for Discriminating Orchard Species Using Multivariate Statistical Techniques

2019

Sustainable management of orchard fields requires detailed information about the tree types, which is a main component of precision agriculture programs. To this end, hyperspectral imagery can play a major role in orchard tree species mapping. Efficient use of hyperspectral data in combination with field measurements requires the development of optimized band selection strategies to separate tree species. In this study, field spectroscopy (350 to 2500 nm) was performed through scanning 165 spectral leaf samples of dominant orchard tree species (almond, walnut, and grape) in Chaharmahal va Bakhtiyari province, Iran. Two multivariable methods were employed to identify the optimum wavelengths:…

optimal spectral wavelengths010504 meteorology & atmospheric sciences0211 other engineering and technologiesRed edge02 engineering and technologyfield spectroscopy; orchards species; ANOVA–RFC–PCA; PLS; optimal spectral wavelengths; discriminant analysis01 natural sciencesPartial least squares regressionlcsh:Science021101 geological & geomatics engineering0105 earth and related environmental sciencesMathematicsRemote sensinganova–rfc–pcaorchards speciesNear-infrared spectroscopyHyperspectral imaging15. Life on landplsLinear discriminant analysisdiscriminant analysisfield spectroscopyRandom forestTree (data structure)Principal component analysisGeneral Earth and Planetary Scienceslcsh:QRemote Sensing
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Carbon Dioxide Activation and Reaction Induced by Electron Transfer at an Oxide-Metal Interface

2015

A model system has been created to shuttle electrons through a metal-insulator-metal (MIM) structure to induce the formation of a CO2 anion radical from adsorbed gas-phase carbon dioxide that subsequently reacts to form an oxalate species. The process is completely reversible, and thus allows the elementary steps involved to be studied at the atomic level. The oxalate species at the MIM interface have been identified locally by scanning tunneling microscopy, chemically by IR spectroscopy, and their formation verified by density functional calculations.

oxalateta114Inorganic chemistryOxidecarbon dioxideInfrared spectroscopychemistry.chemical_elementGeneral Chemistryelectron transferOxygenmetal-insulator-metal structureCatalysisOxalateIonlaw.inventionMetalElectron transferchemistry.chemical_compoundchemistrylawvisual_artvisual_art.visual_art_mediumScanning tunneling microscopeta116oxygenAngewandte Chemie International Edition
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