Search results for "Isola"
showing 10 items of 818 documents
Vibrational Spectrum of HXeSH revisited : Combined computational and experimental study
2020
Vibrational spectrum of HXeSH embedded in low-temperature matrix is experimentally studied. To support the spectrum interpretation, anharmonic vibrational analysis is performed using different models and basis sets and the data is compared with previous experimental and theoretical analyses. Computations of overtones and combination modes allowed for new band assignments. The HXeSH molecule exhibits high anharmonicity similarly as other molecules from the noble-gas hydride family. Comparison of the employed computational methods shows once again that the modelling of the noble-gas compounds faces theoretical challenges to yield quantitatively reliable results. peerReviewed
Ecologia e distribuzione di Chamaerops humilis L. (Arecaceae) nella Sicilia nord-orientale
2014
I settori costieri e collinari della Sicilia nord-orientale e delle Eolie sono stati esplorati ai fini della raccolta di informazioni aggiornate sulla distribuzione dei popolamenti di palma nana e sulle caratteristiche ecologiche delle stazioni che li ospitano. I risultati delle indagini di campo sono stati integrati dalla verifica dei toponimi locali legati ai nomi dialettali della specie. Si con- ferma la totale assenza della palma nana lungo l’intero settore costiero dei Nebrodi. Dei nove popolamenti accertati, quattro si trovano alle Eolie, due sul versante ionico e tre sul versante tir- renico dei Peloritani; uno di questi ultimi, localizzato su Capo Calavà, risulta inedito. La conco- …
Conformational-Dependent Photodissociation of Glycolic Acid in an Argon Matrix
2023
Ultraviolet-induced photodissociation and photo-isomerization of the three most stable conformers (SSC, GAC, and AAT) of glycolic acid are investigated in a low-temperature solid argon matrix using FTIR spectroscopy and employing laser radiation with wavelengths of 212 nm, 226 nm, and 230 nm. The present work broadens the wavelength range of photochemical studies of glycolic acid, thus extending the understanding of the overall photochemistry of the compound. The proposed kinetic model for the photodissociation of glycolic acid proceeds from the lowest energy conformer (SSC). The model suggests that ultraviolet light induces isomerization only between the SSC and GAC conformers and between …
Toward Sustainable PLA-Based Multilayer Complexes with Improved Barrier Properties
2019
Poly(lactic acid) or PLA is currently considered as one of the most promising substitutes of conventional plastics, with low environmental impact, especially for food packaging applications. Nevertheless, some drawbacks, such as high permeability to oxygen, are still limiting its industrial applications. The objective of this study was to highly increase the oxygen barrier performance of PLA without compromising its sustainable nature and following the principles of circular economy perspective. Coproducts coming from mill industries, such as wheat gluten proteins (WG), were used to produce PLA-WG-PLA multilayer complexes with improved barrier performance. Different technologies of industri…
UInDeSI4.0 : An efficient Unsupervised Intrusion Detection System for network traffic flow in Industry 4.0 ecosystem
2023
In an Industry 4.0 ecosystem, all the essential components are digitally interconnected, and automation is integrated for higher productivity. However, it invites the risk of increasing cyber-attacks amid the current cyber explosion. The identification and monitoring of these malicious cyber-attacks and intrusions need efficient threat intelligence techniques or intrusion detection systems (IDSs). Reducing the false positive rate in detecting cyber threats is an important step for a safer and reliable environment in any industrial ecosystem. Available approaches for intrusion detection often suffer from high computational costs due to large number of feature instances. Therefore, this paper…
Lenses on very curved zones of a singular line field of ${\mathbb C}^2$ or of a singular plane field of ${\mathbb C}^3$
2020
We renormalize, using suitable lenses, small domains of a singular holomorphic line field of ${\mathbb C}^2$ or plane field of ${\mathbb C}^3$ where the curvature of a plane-field is concentrated. At a proper scale the field is almost invariant by translations. When the field is integrable, the leaves are locally almost translates of a surface that we will call {\it profile}. When the singular rays of the tangent cone (a generalization to a plane-field of the tangent cone of a singular surface is defined) are isolated, we obtain more precise results. We also generalize a result of Merle (\cite{Me}) concerning the contact order of generic polar curves with the singular level $f=0$ when $\ome…
Study of xT scaling in proton-proton collisions measured by the ALICE experiment
2012
In this Master's Thesis an analysis of proton proton data measured by the ALICE (A Large Ion Collider Experiment) Collaboration at center-of-mass energies 7 TeV and 2.76 TeV is presented. The ALICE detector is located at the LHC (Large Hadron Collider) at CERN, Switzerland. The goal of this thesis was to study whether the isolation requirement can increase the sensitivity of the xT spectra (xT=2pT/sqrt(s)) to higher-twist (HT) processes. In HT processes the outgoing hadron is produced directly in the hard subprocess, rather than in the fragmentation process described by the leading-twist (LT) processes in the perturbative QCD picture. Higher-twist processes are mainly low pT phenomena, caus…
Analysis of MAC-level throughput in LTE systems with link rate adaptation and HARQ protocols
2015
LTE is rapidly gaining momentum for building future 4G cellular systems, and real operational networks are under deployment worldwide. To achieve high throughput performance, in addition to an advanced physical layer design LTE exploits a combination of sophisticated mechanisms at the radio resource management layer. Clearly, this makes difficult to develop analytical tools to accurately assess and optimise the user perceived throughput under realistic channel assumptions. Thus, most existing studies focus only on link-layer throughput or consider individual mechanisms in isolation. The main contribution of this paper is a unified modelling framework of the MAC-level downlink throughput of …
Do allopatric male Calopteryx virgo damselflies learn species recognition?
2012
There is a growing amount of empirical evidence that premating reproductive isolation of two closely related species can be reinforced by natural selection arising from avoidance of maladaptive hybridization. However, as an alternative for this popular reinforcement theory, it has been suggested that learning to prefer conspecifics or to discriminate heterospecifics could cause a similar pattern of reinforced premating isolation, but this possibility is much less studied. Here, we report results of a field experiment in which we examined (i) whether allopatric Calopteryx virgo damselfly males that have not encountered heterospecific females of the congener C. splendens initially show discri…