Search results for "JUNCTION"
showing 10 items of 862 documents
Far-infrared intersubband absorption inp-typeGaAs/AlxGa1−xAssingle heterojunctions under uniaxial compression
2001
Electronic structure, lattice dynamics, and optical properties of a novel van der Waals semiconductor heterostructure: InGaSe2
2017
There is a growing interest in the property dependence of transition metal dichalcogenides as a function of the number of layers and formation of heterostructures. Depending on the stacking, doping, edge effects, and interlayer distance, the properties can be modified, which opens the door to novel applications that require a detailed understanding of the atomic mechanisms responsible for those changes. In this work, we analyze the electronic properties and lattice dynamics of a heterostructure constructed by simultaneously stacking InSe layers and GaSe layers bounded by van der Waals forces. We have assumed the same space group of GaSe, $P\overline{6}m2$ as it becomes the lower energy conf…
ZnO/ZnS heterostructures for hydrogen production by photoelectrochemical water splitting
2016
This work studies the photoelectrochemical behavior of novel ZnO/ZnS heterostructures obtained by means of anodization in water and glycerol/water/NH4F electrolytes with different Na2S additions under controlled hydrodynamic conditions. For this purpose different techniques such as Field Emission Scanning Electronic Microscopy (FE-SEM) with EDX, Raman spectroscopy and photoelectrochemical water splitting tests under standard AM 1.5 conditions have been carried out. The obtained results showed that the hydrodynamic conditions promoted an ordered nanotubular morphology which facilitates electron-hole separation and consequently, the photoelectrochemical activity for water splitting is enhance…
Metal thin-film temperature sensor embedded in heat-sink for CPV cells characterization
2014
The efficiency of a photovoltaic cell is dependent on its temperature, for this reason an accurate measurement of this parameter is important to fully characterize the device and to optimize its performance. For CPV applications a significant heat flux is needed to remove excess heat from the cell towards a heat sink, making it difficult to derive the cell temperature. In fact, measurements performed directly between the cell and the heat-sink, by use of commercial bulk sensors, would produce a significant disturbance in the heat flow; on the other hand, a measurement performed out of the cell / heat sink axis would be subject to large uncertainties, due to the high radial temperature gradi…
Aqueous synthesis of Z-scheme photocatalyst powders and thin-film photoanodes from earth abundant elements
2018
Riga Technical University supported the preparation of this manuscript from the Scientific Research Project Competition for Young Researchers No. ZP 2017/8
Functionalisation of MoS2 2D layers with diarylethene molecules
2021
Functionalisation of two dimensional (2D) materials with stimuli-responsive molecules has been scarcely investigated. Here, MoS2 layers obtained by chemical exfoliation are covalently and non-covalently functionalised using two photoswitchable diarylethene derivatives under their open- and closed-ring isomers. The choice of these light-responsive molecules is based on their excellent thermal irreversibility and fatigue resistance. The characterisation of the resultant molecular/2D heterostructures proves the successful anchoring of the molecules by both approaches as well as the influence that the driving interaction has in the photoswitching behaviour of the diarylethene isomers after thei…
Modulation of the organic heterojunction behavior, from electrografting to enhanced sensing properties
2019
International audience; The energy barrier of an organic heterojunction built on ITO electrodes and made from a low conductive sublayer (Cu(F16Pc)) covered by a highly conductive semiconductor (LuPc2) is modulated by electrografting of organic layers before depositing the sublayer. Impedance spectroscopy clearly demonstrates the increase of the energy barrier at the ITO – sublayer interface. Additionally, the electrografting is a versatile and promising method for the tuning of heterojunctions. The I(V) characteristics of the heterojunctions are highly modified by the electrografting. The same electromodifications of electrodes carried out on LuPc2 resistors lead to a modification of their …
Modulating the Electrical Properties of Organic Heterojunction Devices Based On Phthalocyanines for Ambipolar Sensors.
2020
International audience; HAL is a multidisciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.
Organic Heterojunction Devices Based on Phthalocyanines: A New Approach to Gas Chemosensing.
2020
Organic heterostructures have emerged as highly promising transducers to realize high performance gas sensors. The key reason for such a huge interest in these devices is the associated organic heterojunction effect in which opposite free charges are accumulated at the interface making it highly conducting, which can be exploited in producing highly sensitive and faster response kinetics gas sensors. Metal phthalocyanines (MPc) have been extensively studied to fabricate organic heterostructures because of the large possibilities of structural engineering which are correlated with their bulk thin film properties. Accordingly, in this review, we have performed a comprehensive literature surve…
Molecular semiconductor-doped insulator (MSDI) heterojunctions: Oligothiophene/bisphtalocyanine (LuPc2) and perylene/bisphthalocyanine as new structu…
2010
Abstract The combination of a sexithiophene and a perylene diimide derivatives, as p-type and n-type materials, respectively, used as sub-layers, to an intrinsic semiconductor, namely the lutetium bisphthalocyanine, allows to obtain a new transducer for gas sensing. These transducers were called molecular semiconductor-doped insulator (MSDI) heterojunctions, were recently designed and reported, but with only phthalocyanines as active materials. p-Type material leads to MSDIs that exhibit a positive response to ozone and a negative response to ammonia, whereas MSDIs prepared from n-type material exhibit a positive response to ammonia and negative response to ozone. The remarkable point is th…