Search results for "Kimberlite"
showing 10 items of 21 documents
Differentiation of natural and synthetic gem-quality diamonds by luminescence properties
2003
Abstract Laser-excited time-resolved and UV-excited static photoluminescence (PL) as well as cathodoluminescence (CL) techniques were applied to identify the origin of diamonds. Samples represented natural faced and rough diamonds from diamond market and different kimberlites as well as the most common high pressure–high temperature (HPHT) and as-grown synthetic diamonds. The time-resolved PL spectra of natural and synthetic diamonds display clear mutual differences. The static PL and CL spectra of natural diamonds revealed emission bands caused by complex nitrogen–vacancy (N–V)-aggregates whereas the bands of synthetic diamonds reflect simple N–V-aggregates and nickel-containing defects. T…
Spectroscopic 2D-tomography: Residual pressure and strain around mineral inclusions in diamonds
2004
We have studied high-pressure inclusions (Ca-silicates, coesite, graphite) in three large diamonds, one from the Kankan district, Guinea, and the other two from the Panda kimberlite, Ekati diamond mines, Canada. Using the in situ point-by-point mapping technique with a confocal Raman system, the mineralogy of the inclusions, as well as their area distribution pattern ( e.g. , of different Ca-silicate phases) and their order-disorder distribution pattern (shown for graphite/disordered carbon), were determined. Raman mapping of the host diamonds yielded 2D-tomographic pressure and strain distribution patterns and provided information on the residual pressure of the inclusions (∼ 2.3 GPa for a…
Contrasting types of metasomatism in dunite, wehrlite and websterite xenoliths from Kimberley, South Africa
2008
Abstract Dunite, wehrlite and websterite are rare members of the mantle xenolith suite in the Kimberley kimberlites of the Kaapvaal Craton in southern Africa. All three types were originally residues of extensive melt extraction and experienced varying amounts and types of melt re-enrichment. The melt depletion event, dated by Re–Os isotope systematics at 2.9 Ga or older, is evidenced by the high Mg# (Mg/(Mg + Fe)) of silicate minerals (olivine (0.89–0.93); pyroxene (0.88–0.93); garnet (0.72–0.85)), high Cr# (Cr/(Cr + Al)) of spinel (0.53–0.84) and mostly low whole-rock SiO2, CaO and Al2O3 contents. Shortly after melt depletion, websterites were formed by reaction between depleted peridotit…
Eclogite xenoliths from the Kuruman kimberlites, South Africa: geochemical fingerprinting of deep subduction and cumulate processes☆
2004
The mineralogically diverse eclogite xenolith suite sampled by the >1.6 Ga Zero kimberlite in the Kuruman group, close to the western edge of the Kaapvaal craton consists of bimineralic eclogites, orthopyroxene-bearing eclogites with and without sanidine, and kyanite eclogites. Garnet exsolutions in clinopyroxene occur in all Zero eclogite types, and orthopyroxene and, where present, sanidine are also exsolved from clinopyroxene in orthopyroxene-bearing eclogites. Mineral thermobarometry indicates that the last P–T condition prior to the kimberlite eruption was 900–950 °C at 3.5–4.0 GPa. However, inclusions of quartz, rutile and rarely K-feldspar, plus former fluid inclusions in garnets, in…
Integrating Ultramafic Lamprophyres into the IUGS Classification of Igneous Rocks: Rationale and Implications
2005
RECEIVED JULY 16, 2004; ACCEPTED MARCH 16, 2005ADVANCE ACCESS PUBLICATION APRIL 29, 2005We introduce a modification to the current IUGS classificationsystem for igneous rocks to include ultramafic lamprophyres, whicharecurrentlyentirelyomitted.Thisisdonebyincludinganewstepinthe sequential system, after the assignment of pyroclastic rocks andcarbonatites, that considers ultramafic inequigranular textured rockswith olivine and phlogopite macrocrysts and/or phenocrysts. At thisstepultramaficlamprophyresareconsideredtogetherwithkimberlites,orangeites (former Group 2 kimberlites) and olivine lamproites.This proposal allows the correct identification and classificationof ultramafic lamprophyres w…
The composition of near-solidus melts of peridotite in the presence of CO2 and H2O between 40 and 60 kbar
2009
Abstract Partial melting experiments at 40, 50 and 60 kbar pressure on three peridotite compositions with 0.5–0.63 wt.% H2O and 2.0–3.2 wt.% CO2 added indicate melting temperatures only marginally above continental geotherms. Most experiments were performed on a composition with 1.5 wt.% K2O added, which causes a further decrease of about 40 °C in melting temperature. Melts progress gradually from carbonate-rich to carbonated silicate in composition: near-solidus melts have Ca/(Ca + Mg) of 0.46–0.53, which fall to 30 wt.%) and Al2O3 ( 9 wt.%) and concomitant decrease in CaO (> 20 to Partial melts of peridotite with CO2 and H2O are too low in MgO to resemble kimberlites, but will act as ef…
Nature and origin of eclogite xenoliths from kimberlites
2004
Abstract Eclogites from the Earth's mantle found in kimberlites provide important information on craton formation and ancient geodynamic processes because such eclogites are mostly Archean in age. They have equilibrated over a range of temperatures and pressures throughout the subcratonic mantle and some are diamond-bearing. Most mantle eclogites are bimineralic (omphacite and garnet) rarely with accessory rutiles. Contrary to their overall mineralogical simplicity, their broadly basaltic-picritic bulk compositions cover a large range and overlap with (but are not identical to) much younger lower grade eclogites from orogenic massifs. The majority of mantle eclogites have trace element geoc…
Between carbonatite and lamproite - Diamondiferous Torngat ultramafic lamprophyres formed by carbonate-fluxed melting of cratonic MARID-type metasomes
2008
Abstract New U–Pb perovskite ages reveal that diamondiferous ultramafic lamprophyre magmas erupted through the Archean crust of northern Labrador and Quebec (eastern Canada) between ca. 610 and 565 Ma, a period of strong rifting activity throughout contiguous Laurentia and Baltica. The observed Torngat carbonate-rich aillikite/carbonatite and carbonate-poor mela-aillikite dyke varieties show a large spread in Sr–Nd–Hf–Pb isotope ratios with pronounced correlations between isotope systems. An isotopically depleted component is identified solely within aillikites (87Sr/86Sri = 0.70323–0.70377; eNdi = +1.2–+1.8; eHfi = +1.4–+3.5; 206Pb/204Pbi = 18.2–18.5), whereas some aillikites and all mela-…
Trace-element partitioning between amphibole and silicate melt.
2007
Knowledge of the partitioning behavior of trace elements between solid and liquid is a prerequisite for modern igneous and mantle petrology. Most of the mathematical models simulating melt generation, migration and evolution within the mantle and/or the crust require the availability of reliable solid/liquid partition coefficients for the mineral phases involved in the process. Calcic amphiboles are extremely important for the understanding of lithospheric processes because of both their common occurrence in a variety of igneous and metamorphic rocks types and their capability of hosting a large number of geochemically important trace elements. A series of studies on the partitioning behavi…
Melting of sediments in the deep mantle produces saline fluid inclusions in diamonds.
2019
We demonstrate the formation of highly saline mantle fluids by the reaction of subducted sediment with peridotite.