Search results for "Kinetic"
showing 10 items of 3064 documents
EFFICIENT DEGRADATION OF CLOFIBRIC ACID BY HETEROGENEOUS PHOTOCATALYTIC OXIDATION PROCESS
2019
International audience; Emerging pollutants such as pharmaceutical active compounds were detected worldwide in different environmental compartments. Nowadays, multiple studies are focused on the investigation of their environmental fate, as well as to find new, efficient and sustainable removal technologies. Several studies demonstrated that heterogeneous photocatalysis is one of the most promising techniques used for water purification. Thus, the aim of our work was to evaluate the photodegradation efficiency of a refractory emergent compound, named clofibric acid, under UV light in aqueous solution. We report that photodegradation and mineralization efficiency are strongly dependent of th…
Solid acid-catalyzed depolymerization of barley straw driven by ball milling
2015
This study describes a time and energy saving, solvent-free procedure for the conversion of lignocellulosic barley straw into reducing sugars by mechanocatalytical pretreatment. The catalytic conversion efficiency of several solid acids was tested which revealed oxalic acid dihydrate as a potential catalyst with high conversion rate. Samples were mechanically treated by ball milling and subsequently hydrolyzed at different temperatures. The parameters of the mechanical treatment were optimized in order to obtain sufficient amount of total reducing sugar (TRS) which was determined following the DNS assay. Additionally, capillary electrophoresis (CE) and Fourier transform infrared spectrometr…
Insight into the role of the zeolitization process in enhancing the adsorption performance of kaolinite/diatomite geopolymer for effective retention …
2021
Abstract Diatomite/kaolinite-based geopolymer (GP) was synthesized and incorporated in zeolitization process (Z/GP) to investigate the role of the zeolite phases in inducing its retention capacity of the dissolved Sr (II) ions in water. The retention of Sr (II) ions using Z/GP in comparison with GP was evaluated based on both batch and fixed-bed column studies. In the batch study, the zeolitized geopolymer (Z/GP) shows enhancement in the Sr (II) retention capacity (193.7 mg/g) as compared to the normal geopolymer (102 mg/g). Moreover, the recyclability studies demonstrate higher stability for Z/GP than GP with a retention percentage higher than 90% for five reusing runs. The kinetic and the…
Strontium isotopes as tracers of water-rocks interactions, mixing processes and residence time indicator of groundwater within the granite-carbonate …
2016
This study aims at identifying the water-rock interactions and mixing rates within a complex granite-carbonate coastal aquifer under high touristic pressure. Investigations have been carried out within the coastal aquifer of Bonifacio (southern Corsica, France) mainly composed of continental granitic weathering products and marine calcarenite sediments filling a granitic depression. A multi-tracer approach combining physico-chemical parameters, major ions, selected trace elements, stable isotopes of the water molecule and 87Sr/86Sr ratios measurements is undertaken for 20 groundwater samples during the low water period in November 2014. 5 rock samples of the sedimentary deposits and surroun…
Bioconcentration, metabolism and toxicity of substituted anilines in the zebrafish (Brachydanio rerio).
1991
The LC50 (96 h) values and the bioconcentration factors (BCF) for nine anilines (aniline; 2-, 3-, 4-chloroaniline; 2-, 3-, 4-nitroaniline; 2,4- and 3,4-dichloroaniline) in the zebrafish (Brachydanio rerio) were determined. Biotransformation products of anilines in the zebrafish were analyzed by HPLC. The aim of the investigations was to find relationships between accumulation/elimination/metabolism and toxicity on the one hand and between chemical structure and biotransformation on the other. We found a good correlation of log BCF and of log Pow with log LC50. This concurs with the assumption that the internal dose determines the toxicological effect. All anilines investigated, with the exc…
Quantification of kinetic parameters for heterotrophic bacteria via respirometry in a hybrid reactor
2010
Over the last decade new technologies are emerging even more for wastewater treatment. Among the new technologies, a recent possible solution regards Moving Bed Biofilm Reactors (MBBRs) that represent an effective alternative to conventional processes. More specifically such systems consist in the introduction of plastic elements inside the aerobic reactor as carrier material for the growth of attached biomass. Recently, one of the mostly used alternatives is to couple the Moving Bed Biofilm Reactor (MBBR) process with the conventional activated sludge process, and the resulting process is usually called HMBBR (Hybrid MBBR). In the MBBR process the biofilm grows attached on small plastic el…
Impact of historical mining assessed in soils by kinetic extraction and lead isotopic ratios.
2014
12 pages; International audience; The aim of this study is to estimate the long-term behaviour of trace metals, in two soils differently impacted by past mining. Topsoils from two 1 km(2) zones in the forested Morvan massif (France) were sampled to assess the spatial distribution of Cd, Cu, Pb and Zn. The first zone had been contaminated by historical mining. As expected, it exhibits higher trace-metal levels and greater spatial heterogeneity than the second non-contaminated zone, supposed to represent the local background. One soil profile from each zone was investigated in detail to estimate metal behaviour, and hence, bioavailability. Kinetic extractions were performed using EDTA on thre…
BIOALGA reactor: preliminary studies for heavy metals removal
2002
Abstract Microalgae have a high affinity for polyvalent metals, for that reason they could be used to reduce the concentration of heavy metals present in water and wastewater. In the present work an evaluation of a rotary biofilm reactor for algae immobilization (BIOALGA) with the subject of heavy metal removal was investigated. The BIOALGA reactor consisted of a pilot scale model that was operated with synthetic wastewater with an initial concentration of 3000 μg/l of cobalt ion. Scenedesmus obliquus was immobilized in the reactor, which was operated in batch mode for a period of 20 days. The rotary velocity used, 2 rpm, was constant during the experiment. A maximum removal of cobalt ion o…
An extension of ASM2d including pH calculation
2003
This paper presents an extension of the Activated Sludge Model No. 2d (ASM2d) including a chemical model able to calculate the pH value in biological processes. The developed chemical model incorporates the complete set of chemical species affecting the pH value to ASM2d describing non-equilibrium biochemical processes. It considers the system formed by one aqueous phase, in which biochemical processes take place, and one gaseous phase, and is based on the assumptions of instantaneous chemical equilibrium under liquid phase and kinetically governed mass transport between the liquid and gas phase. The ASM2d enlargement comprises the addition of every component affecting the pH value and an i…
Biological nitrate removal from wastewater of a metal-finishing industry
2006
An upflow packed bed reactor at laboratory scale has been operated for a continuous period of 5 months to investigate the technical feasibility of biological nitrate removal applied to the effluent of the coagulation-sedimentation wastewater of a metal-finishing industry. The reactor was fed with industrial wastewater in a five-fold dilution to reproduce the global spill in the factory (20/80, industrial wastewater/domestic wastewater) with a concentration of nitrate between 141 and 210 gNO(3)-N/m(3). Methanol was added as a carbon source for denitrification. Inlet flow rate was progressively increased from 9 to 40 L/day (nitrogen input load from 45 to 250 gNO(3)-N/(m(3)h)). The highest obs…