Search results for "LA-ICP-MS"

The first archaeometric characterization of obsidian artifacts from the archaeological site of Samshvilde (South Georgia, Caucasus)

2019

This paper presents the first results about the provenance of obsidian fragments recovered in the archaeological site of Samshvilde (South Georgia, Caucasus) with the aim to obtain knowledge related to the network distribution and procurement of obsidian in Georgia. The geochemical characterization of thirty archaeological finds was obtained by the LA-ICP-MS method, an almost non-destructive technique capable of chemically characterizing the volcanic glass. A comparison of geochemical results obtained on both archaeological artefacts and geological samples collected from Chikiani outcrop in Georgia, together with literature data of southern Caucasus and eastern Turkey, allowed us to define …

Neoproterozoic Rosetta Gabbro from northernmost Arabian–Nubian Shield, south Jordan : Geochemistry and petrogenesis

2017

An Ediacaran mafic intrusion of south Jordan is a distinctive appinitic igneous rock with a possibly unique texture, characterized by spherical clots up to 40 mm in diameter composed of amphibole cores from which plagioclase euhedra radiate; we call it the Rosetta Gabbro. It is exposed as a small (ca. 750 m(2)) outcrop in the Neoproterozoic basement of south Jordan. A second outcrop of otherwise similar gabbro is located about 400 m to the north of the Rosetta Gabbro, but it lacks the distinctive texture. The Rosetta Gabbro could represent a magma pipe. It intrudes the Aqaba Complex (similar to 600 Ma) granitoids and metasediments of the Janub Metamorphic Complex (633-617 Ma). The gabbro is…

New data on the exploitation of obsidian in the mediterranean basin: The harbour of pyrgi and the trade in neolithic age

2020

The contribution shows the first results of ongoing research on the origins and prehistoric assumptions of the well-known Etruscan and Roman harbour of Pyrgi, an ancient Ceretan harbour in southern Etruria. In the light of recent land and submarine investigations, traces of ancient frequentations and contacts dating back to the Neolithic era are emerging when the coastal morphology and environmental characteristics of the site were very different from the current ones. The Etruscan port of Pyrgi, which continues its historical history in Roman and Medieval times, appears as the heir of one or more landing points frequented perhaps already in the Middle Neolithic. As part of this contributio…

Characterization and differentiation of rock varnish types from different environments by microanalytical techniques

2017

© 2017 Elsevier B.V. We investigated rock varnishes collected from several locations and environments worldwide by a broad range of microanalytical techniques. These techniques were selected to address the challenges posed by the chemical and structural complexity within the micrometer- to nanometer-sized structures in these geological materials. Femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs LA-ICP-MS), scanning transmission X-ray microscopy-near edge X-ray adsorption fine structure spectroscopy (STXM-NEXAFS) in combination with scanning electron microscopy (SEM) of focused ion beam (FIB) ultra-thin (100–200 nm) sections, conventional and polarization microscop…

A LA-ICP-MS STUDY OF CARBONATITES FROM FUERTEVENTURA, CANARY ISLAND

Carbonatites complexes are very rare in oceanic environments and in the Atlantic Ocean they can be only found at Cape Verde islands and Fuerteventura. Fuerteventura is the second largest island in the Canary Archipelago and is located on a transitional, continental to oceanic, crust. It consists essentially of Mesozoic sediments, submarine volcanic rocks, subaerial basaltic and trachytic series, ultramafic, mafic to felsic intrusives (clinopyroxenites, melteijites-ijolites, nepheline-monzogabbros, nepheline-sienites) and carbonatitic dike swarms (age 25 Ma). Carbonatite dike (Ca-carbonatites) mineralogy consists of calcite, aegirine-augite, albite, K-feldspar, biotite, apatite, Fe-Ti oxides…

Assessment of Five Monazite Reference Materials for U-Th/Pb Dating Using Laser-Ablation ICP-MS

2019

Monazite is a common accessory phosphate mineral that occurs under a wide range of pressure and temperature conditions in sedimentary, metamorphic and igneous rocks. Monazite contains high amounts of Th and U, rendering single monazite grains suitable for in-situ U-Th/Pb dating using laser ablation inductively-coupled mass spectrometry (LA-ICP-MS). Two key aspects of monazite dating that are critical for accurate age data with maximum precision are (i) optimized instrumental conditions to minimize analytical scatter and (ii) a well characterized reference material to ensure the accuracy of the obtained aged. Here, we analyzed five monazite reference materials (USGS 44069, 94-222, MAdel, Moa…

Origin of Blue Sapphire in Newly Discovered Spinel–Chlorite–Muscovite Rocks within Meta-Ultramafites of Ilmen Mountains, South Urals of Russia: Evide…

2019

Blue sapphire of gem quality was recently discovered in spinel&ndash

Biotic methylation of mercury by intestinal and sulfate-reducing bacteria and their potential role in mercury accumulation in the tissue of the soil-…

2014

Abstract Monomethylmercury as one of the most toxic mercury species influences the health and development of higher organisms and tends to accumulate in the tissue of animals and humans. The aim of this study was to explore the mercury methylating capability of (1) intestinal microbiota of the soil-living earthworm Eisenia foetida (E. foetida) and (2) intestinal sulfate reducing-bacteria in pure cultures. After exposing animals to inorganic mercury chloride (4 mg kg−1 Hg2+) in soil and sterile soil for ten days, the amount of methylmercury in tissue was measured. Despite sterilization of soil, the accumulation of the organic mercury species in tissue was 51 ng g−1. To elucidate the potentia…

Garnet as a monitor for melt–rock interaction: Textural, mineralogical, and compositional evidence of partial melting and melt‐driven metasomatism

2021

International audience; In this study, we focus on a partially melted garnet-bearing granulite from the Salvador–Esplanade Belt (Salvador da Bahia, Brazil), and examine the behaviour of major and trace elements during partial melting and melt-driven metasomatism. Phase equilibria modelling and U–Th– Pb geochronology show that the sample underwent partial melting during the heating segment of the decompression path from ~1.2 GPa and 675–700° C to ~0.8 GPa and 790°C at c. 2.06 Ga. During the final stage of decompression, from 0.8 to ~0.5 GPa, physical segregation of melt resulted in the establishment of chemical potential gradients and mass transfer between the host granulite and the leucosom…

Corundum Anorthosites-Kyshtymites from the South Urals, Russia: A Combined Mineralogical, Geochemical, and U-Pb Zircon Geochronological Study

2019

Kyshtymites are the unique corundum-blue sapphire-bearing variety of anorthosites of debatable geological origin found in the Ilmenogorsky-Vishnevogorsky complex (IVC) in the South Urals, Russia. Their mineral association includes corundum-sapphire, plagioclase (An61&ndash