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Synthesis, characterization and study of covalently modified triazole LAPONITE® edges

2020

Abstract LAPONITE® (Lap) clay mineral was successful functionalized by triazole groups in a two steps procedure. First, the Lap edges were modified with 3-azidopropyltrimethoxysilane by traditional heating and microwave irradiation. Microwave irradiation allowed us to obtain high loading onto the Lap edges in lower times compared to those obtained through conventional method. Afterwards, the triazole moieties were obtained by reaction between azido functionalized Lap and propargyl alcohol. The successful functionalization of Lap was proved by thermogravimetric analysis, FT-IR spectroscopy, dynamic light scattering and ζ-potential measurements. Finally, the effects of the surface modificatio…

LAPONITE® Covalent modification Triazole moieties HydrogelThermogravimetric analysisMaterials scienceTriazole020101 civil engineeringGeology02 engineering and technologySettore CHIM/06 - Chimica OrganicaPropargyl alcohol021001 nanoscience & nanotechnology0201 civil engineeringlaw.inventionchemistry.chemical_compoundchemistryChemical engineeringDynamic light scatteringOptical microscopeGeochemistry and PetrologylawCovalent bondSurface modification0210 nano-technologySpectroscopySettore CHIM/02 - Chimica Fisica
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