Search results for "LC"

Geogenic and atmospheric sources for volatile organic compounds in fumarolic emissions from Mt. Etna and Vulcano Island (Sicily, Italy)

2012

In this paper, fluid source(s) and processes controlling the chemical composition of volatile organic compounds (VOCs) in gas discharges from Mt. Etna and Vulcano Island(Sicily, Italy) were investigated. The main composition of the Etnean and Volcano gas emissions is produced by mixing, to various degrees, of magmatic and hydrothermal components. VOCs are dominated by alkanes, alkenes and aromatics, with minor, though significant, concentrations of O-, S- and Cl(F)-substituted compounds. The main mechanism for the production of alkanes is likely related to pyrolysis of organic-matterbearing sediments that interact with the ascending magmatic fluids. Alkanes are then converted to alkene and …

First volatile inventory for Gorely volcano, Kamchatka

2012

We report here the very first assessment of volatile flux emissions from Gorely, an actively degassing volcano in Kamchatka. Using a variety of in situ and remote sensing techniques, we determined the bulk plume concentrations of major volatiles (H2O 93.5%, CO2, 2.6%, SO2 2.2%, HCl 1.1%, HF 0.3%, H2 0.2%) and trace-halogens (Br, I), therefore estimating a total gas release of 11,000 tons·day−1 during September 2011, at which time the target was non-eruptively degassing at 900°C. Gorely is a typical arc emitter, contributing 0.3% and 1.6% of the total global fluxes from arc volcanism for CO2 and HCl, respectively. We show that Gorely's volcanic gas (H2O/SO2 43, CO2/SO2 1.2, HCl/SO2 0.5) is a…

Gas Emissions From the Western Aleutians Volcanic Arc

2021

The Aleutian Arc is remote and highly active volcanically. Its 4,000 km extent from mainland Alaska to Russia’s Kamchatka peninsula hosts over 140 volcanic centers of which about 50 have erupted in historic times. We present data of volcanic gas samples and gas emission measurements obtained during an expedition to the western-most segment of the arc in September 2015 in order to extend the sparse knowledge on volatile emissions from this remote but volcanically active region. Some of the volcanoes investigated here have not been sampled for gases before this writing. Our data show that all volcanoes host high-temperature magmatic-hydrothermal systems and have gas discharges typical of volc…

The recent Nyiragongo (Democratic Republic of Congo) eruption: the impact of volcanic ash fallout on drinking water and edible plants

2022

Nyiragongo is an active intraplate volcano well known for its fascinating persistent lava lake inside the crater and is recognized as one of the most dangerous volcanoes in the world as more than two million people live on its slopes, 18-25 km far from the main crater. It is located in the Virunga Volcanic Province (VVP), in the western branch of the East African Rift System (EARS), at the intersection between the Democratic Republic of Congo, Rwanda, and Uganda. Unexpectedly, on 22 May 2021, Nyiragongo produced three different lateral lava flows in the low flanks and significant amounts of volcanic gas and ash were emitted from the summit crater. For several weeks, the ash fallout strongly…

Plume chemistry provides insights into the mechanisms of sulfur and halogen degassing at basaltic volcanoes,

2004

This paper deals with sulfur, chlorine and fluorine abundances in the eruptive volcanic plume of the huge October 2002-January 2003 eruption of Mount Etna, aiming at relating the relevant compositional variations observed throughout with changes in eruption dynamics and degassing mechanisms. The recurrent sampling of plume acidic volatiles by filter-pack methodology revealed that, during the study period, S/Cl and Cl/F ratios ranged from 0.1-6.8 and 0.9-5.6, respectively. Plume S/Cl ratios increased by a factor of ∼10 as volcanic activity drifted from paroxysmal lava fountaining (mid- and late November) to passive degassing and minor effusion (early January), and then decreased to the low v…

A wider view on possible causes of observed BrO/SO2 – CO2/SO2 correlations – during volcanic degassing variations

2013

New Techniques for real-time volcanic gas measurements: the UV camera

2012

In this study, I take advantage of a novel technique - the UV camera - to image SO2 emissions from the Italian volcanoes with improved high temporal resolution. Here, this technique has been updated to a new configuration (dual-camera system), which combines higher temporal resolution (0.5-1.2 Hz) and improved accuracy relative to the single-camera setup. The methodology has been extensively tested and improved, whilst developing a user-friendly control software (Vulcamera) and a calibration technique (in tandem DOAS-SO2 quartz cells calibration), which simplify instrument deployment, acquisition and data analysis. A first application was focused on SO2 gas flux measurements at individual fuma…

Gas fluxes and compositions of two active volcanoes in Northern Chile: Lascar and Lastarria

2013

The Central Andes Volcanic Zone of northern Chile comprises a ~1200 km long volcanic district extending from the Atacama region on the northe to the Arica and Parinacota region.Lascar and Lastarria are among the most actively degassing volcanoes of the several (more than 30) potentially active in the region. They both host persistent fumarolic fields and generate sustained plumes above the main craters. Here, we report on simultaneous in-situ and remote volcanic gas measurements aimed at obtaining the very first degassing budget for major volatiles released by these fumarolic fields. Using quick deployable scanning DOAS and SO2 camera systems we obtained time-averaged SO2 fluxes of ~ 500 t …

The impact of Mt. Etna volcanic emissions on the atmospheric deposition: developments and improvements during three decades of studies

2022

Volcanic emissions are an important source of gases and particles to the atmosphere. Mount Etna discharges a permanent volcanic plume consisting of water vapor and gaseous species (CO2, SO2, HCl and HF, mainly), metals, acid droplets, and solid particles. This plume interacts with meteoric water during precipitations events, so the chemical signature of the plume is impressed on the rainwater. Over the past 32 years, the impact of Etna's emissions on atmospheric deposition has been investigated in many research projects by our team. Sampling methodologies and analytical procedures have been improved over the years. The first study of the concentration of water-soluble inorganic ions in week…

Plume composition changes during the birth of a new lava lake - Nyamulagira volcano, DR Congo

2016

Nyamulagira, in the Virunga Volcanic Province (VVP), Democratic Republic of Congo, is one of the most active volcanoes in Africa. The volcano is located about 25 km north-northwest of Lake Kivu in the Western Branch of the East African Rift System (EARS) with a distance of only 15 km to Nyiragongo, which is well known for its decades-old active lava lake. Nyamulagira is a shield volcano with a 3058 m high and 2000 m wide summit caldera. The volcano is characterized by frequent eruptions, which occur both from the summit crater and from the flanks (31 flank eruptions over the last 110 years). Due to the low viscosity lava, although significantly higher than the one of Nyiragongo, wide lava f…