Search results for "LCA"
showing 10 items of 1995 documents
Modulació de l'artritis gotosa per dues molècules inhibidores de la caspasa-1
2020
L’artritis gotosa es una de les malalties articulars més freqüents d’artritis inflamatòria. Es produeix per la deposició d’urat monosòdic (MSU) en les articulacions, donant lloc a episodis aguts d’inflamació, que poden ser persistents i arribar a cronificar-se. La fagocitosi dels cristalls d’MSU pels neutròfils i macròfags genera la producció de ROS i l’activació de l’NFkappaB, alliberant citocines i activant l’NLRP3. Aquest inflamasoma indueix l’activació de la caspasa1 i la consegüent producció de les formes actives IL1beta i IL18. Les calcones són un grup de la família dels flavonoides, que han demostrat propietats antiinflamatòries i antiartrítiques, actuant sobre diverses dianes terapè…
The behaviour of trace elements during the volcanic ash-liquid interaction. Example of marine and human systems.
2011
I processi d’interazione solido-liquido sono alla base dei meccanismi che governano la disponibilità degli elementi in tracce in fase liquida. In questo lavoro tali processi sono stati studiati attraverso l’utilizzo degli elementi delle Terre Rare (REE) che come serie di elementi, per le loro peculiari caratteristiche sono degli ottimi traccianti di processi geochimici. Lo scopo della prima parte di questo lavoro è stato quello di studiare la reattività di un particolato vulcanico durante l’interazione con un’acqua marina sintetica. Tale indagine è stata effettuata attraverso esperimenti di tipo batch, per un periodo massimo di 6 mesi. Ulteriori indagini sono state effettuate aggiungendo Na…
The role of melt composition on aqueous fluid vs. silicate melt partitioning of bromine in magmas
2018
International audience; Volcanogenic halogens, in particular bromine, potentially play an important role in the ozone depletion of the atmosphere. Understanding bromine behaviour in magmas is therefore crucial to properly evaluate the contribution of volcanic eruptions to atmospheric chemistry and their environmental impact. To date, bromine partitioning between silicate melts and the gas phase is very poorly constrained, with the only relevant experimental studies limited to investigation of synthetic melt with silicic compositions. In this study, fluid/melt partitioning experiments were performed using natural silicate glasses with mafic, intermediate and silicic compositions. For each co…
Major ions and trace elements composition of rainwater around the two industrial areas of Milazzo and Priolo Gargallo (Sicily - Italy)
2023
This database shows the concentration of major ions and trace elements in rainwater from two polluted industrial areas of Sicily, Milazzo and Priolo Gargallo, collected from June 2018 to July 2019, through a network of 11 bulk collectors to sample bulk atmospheric deposition, for a total of 131 samples collected. Different sources, both natural and anthropogenic, for both major ions and trace elements have been recognised. This study also highlighted some critical issues with common methods of sampling and analysing atmospheric deposition. The analysis and comparison of two different aliquots, filtered and unfiltered rainwater, has shown that the filtration method removes from the sample a …
Chemistry of atmospheric depositions over two polluted industrial areas of Sicily (Italy)
2021
Dry and wet depositions provide the pathways through which particles and gases emitted into the atmosphere return to the Earth’s surface. Bulk deposition is defined as the sum of dry and wet deposition, which is characterized by water-soluble and insoluble chemical species. Recent studies (e.g. Castillo et al., 2017) showed that most of the atmospheric deposition in Europe occurs in the wet form, but in southern European regions the role of dry contribution can be as significant as that of wet deposition. In the framework of the multidisciplinary project “CISAS” (Centro Internazionale di Studi Avanzati su Ambiente, ecosistema e Salute umana), bulk depositions were monthly sampled over two p…
Mount Etna volcanic emissions signature on the chemical composition of bulk atmospheric deposition in Sicily, Italy.
2022
Mt. Etna, on the eastern coast of Sicily (Italy), is one of the most active and most intensely monitored volcanoes on the Earth, widely recognized as a big source of volcanic gases, such as CO2, SO2, halogens, and many trace elements, including technological critical elements (TCEs), to the atmosphere on a regional and global scale. Mt. Etna emissions account for a significant percentage of the worldwide average volcanic budget and especially during eruptive periods, its products can be dispersed over great distances and they influence the chemical composition of the atmosphere of other continents too. The current knowledge about the geochemical cycle of TCEs is still scarce, nevertheless, …
A Low Cost Customizable Micro-ROV for Environmental Research - Applications, Advances and Challenges
2016
Summary Several shallow submarines areas are characterized by considerable releases of hydrocarbon gases, which, during earthquakes or volcanic activity, may suddenly and violently occur. In some instances, changes in chemical and physical properties of gas emissions, which are generated by geothermal systems connected to the volcanoes’ plumbing system, are important precursors of volcanic activity and useful indices for the study of the geothermal field. Furthermore, some superficial structures such faults, landslide slopes or archaeological relics should be studied with such a high detail that geophysical and bathymetric surveys are unable to provide. In response to the needs increasingly…
Experimental Crystallization of a High-K Arc Basalt: the Golden Pumice, Stromboli Volcano (Italy)
2006
International audience; The near-liquidus crystallization of a high-K basalt (PST-9 golden pumice, 49·4 wt % SiO2, 1·85 wt % K2O, 7·96 wt % MgO) from the present-day activity of Stromboli (Aeolian Islands, Italy) has been experimentally investigated between 1050 and 1175°C, at pressures from 50 to 400 MPa, for melt H2O concentrations between 1·2 and 5·5 wt % and {Delta}NNO ranging from –0·07 to +2·32. A drop-quench device was systematically used. AuPd alloys were used as containers in most cases, resulting in an average Fe loss of 13% for the 34 charges studied. Major crystallizing phases include clinopyroxene, olivine and plagioclase. Fe–Ti oxide was encountered in a few charges. Clinopyro…
Phaenocompsopogon pustulatus n.gen.n. sp., a calcareous alga from the lacustrine rotliegend of the Saar-Nahe Basin (SW-Germany)
1992
Phaenocompsopogon pustulatus n. gen. n. sp. is a calcareous freshwater alga, probably of rhodophycean affinity. The fossils are mainly known from one locality in the Lower Permian of the Saar-Nahe Basin. The algal remains form a packstone in the Reckweilerhof-Bank of the Altenglan Formation. The simple thallus branches irregularly y-shaped and is covered with abundant pustules. An axial canal is characteristic, as are distinct cell features of an inner and outer cortex surrounding a structureless medulla. Most fossils are silicified and often three-dimensionally preserved. The algae lived in a wave-dominated environment, probably in offshore shallow water. The limited occurrence suggests sp…
Environmental impact of Mt. Etna’s degassing: volcanogenic trace elements bioaccumulation in two endemic plant species (Senecio aethnensis and Rumex …
2010
A biomonitoring survey, above tree line level, using two endemic species (Senecio aethnensis and Rumex aethnensis)was performed on Mt. Etna, in order to evaluate the dispersion and the impact of volcanic atmospheric emissions. Samples of leaves were collected in summer 2008 from 30 sites in the upper part of the volcano (1500-3000 m a.s.l). Acid digestion of samples was carried out with a microwave oven, and 44 elements were analyzed by using plasma spectrometry (ICP-MS and ICP-OES). The highest concentrations of all investigated elements were found in the samples collected closest to the degassing craters, and in the downwind sector, confirming that the eastern flank of Mt. Etna is the mos…