Search results for "LCA"

Stratospheric aerosol-Observations, processes, and impact on climate

2016

Interest in stratospheric aerosol and its role in climate have increased over the last decade due to the observed increase in stratospheric aerosol since 2000 and the potential for changes in the sulfur cycle induced by climate change. This review provides an overview about the advances in stratospheric aerosol research since the last comprehensive assessment of stratospheric aerosol was published in 2006. A crucial development since 2006 is the substantial improvement in the agreement between in situ and space-based inferences of stratospheric aerosol properties during volcanically quiescent periods. Furthermore, new measurement systems and techniques, both in situ and space based, have be…

The analcime problem and its impact on the geochemistry of ultrapotassic rocks from Serbia

2004

AbstractTertiary ultrapotassic volcanic rocks from Serbia occasionally display low levels of K2O and K2O/ Na2O. In these rocks, analcime regularly appears as pseudomorphs after pre-existing leucite microphenocrysts. The process ofleucite transformation in Serbian ultrapotassic rocks is very thorough: fresh leucite survives only in ugandites from the Koritnik lava flows as well as in rare inclusions in Cpx. This paper focuses on the impact of ‘analcimization’ on the mineralogy and geochemistry ofthe Serbian ultrapotassic rocks, using the samples where leucite survived as a monitor for the process.Analcimization has had a great impact on the geochemistry of the rocks, but affects only a restr…

Three-dimensional kernel-based coda attenuation imaging of caldera structures controlling the 1982-84 Campi Flegrei unrest

2019

Abstract Coda-wave attenuation imaging has risen as a state-of-the-art technique to depict volcanic structures using their dispersion effects. The 1982–84 seismic and deformation unrest at Campi Flegrei caldera (Italy) is a unique example of non-eruptive volcanic activity in a structured caldera. Here, we propose the first application of 3D coda-attenuation kernels to image caldera structures at multiple frequencies during unrest. Using sensitivity kernels is necessary to assess the effective resolution of coda imaging in highly heterogeneous volcanoes. The technique relies on the solution of Paasschens' equations in the framework of radiative transfer theory. The results map coda attenuati…

2015

Large volcanic eruptions are major geohazards, so identifying their frequency in the geologic record is critical for making predictions and hazard assessments. Following the discovery of a thick (18 cm) tephra layer in marine sediments from Integrated Ocean Drilling Program (IODP) Site U1396 between Montserrat and Guadeloupe in the Caribbean Sea, we document here how high-precision Pb isotopes, trace elements, and grain morphological analyses of the tephra can be used, together with volcanological models, to identify a large (Volcanic Explosivity Index ?6) Plinian eruption from Basse-Terre, Guadeloupe, at ca. 2.36 Ma. This previously unrecognized eruption is believed to be the largest docum…

Turmoil at Turrialba Volcano (Costa Rica): Degassing and eruptive processes inferred from high-frequency gas monitoring

2016

Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San Jose. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high-frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2-rich gas (CO2/S-total>4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2weeks before eruptions, which are accompanied by…

H2O-content and temperature limit the explosive potential of rhyolite magma during Plinian eruptions

2019

Abstract Recent rhyolite eruptions on Earth have demonstrated their capacity to produce a multitude of hazards, including ash formation lasting months and impacting the large reaches of the southern hemisphere. Nevertheless, the underlying mechanisms driving these eruptions are not yet fully understood. Magmatic volatiles, especially H2O, dictate whether volcanic eruptions proceed explosively or effusively. Experimental evidence for the role played by H2O in driving explosive fragmentation is rare, in particular in the eruption of rhyolitic magma. Here we show that when hydrous rhyolitic obsidians from Chaiten Volcano (Chile) are experimentally heated above their glass transition temperatur…

Ultraviolet camera measurements of passive and explosive (Strombolian) sulphur dioxide emissions at Yasur volcano, Vanuatu

2020

Here, we present the first ultraviolet (UV) camera measurements of sulphur dioxide (SO2) flux from Yasur volcano, Vanuatu, for the period 6–9 July 2018. These data yield the first direct gas-measurement-derived calculations of explosion gas masses at Yasur. Yasur typically exhibits persistent passive gas release interspersed with frequent Strombolian explosions. We used compact forms of the “PiCam” Raspberry Pi UV camera system [1,2] powered through solar panels to collect images. Our daily median SO2 fluxes ranged from 4 to 5.1 kg s−1, with a measurement uncertainty of −12.2% to +14.7%, including errors from the gas cell calibration drift, uncertainties in plume direction and distance, and…

Mapping fumarolic fields in volcanic areas: A methodological approach based on the case study of La Fossa cone, Vulcano island (Italy)

2016

Abstract Changes in the activity state of a volcano can be inferred by monitoring the steam flux from fumarolic fields, in terms of 4D (x, y, z, time) variations in temperature and extension of the zone. During the last decades, several studies in this field have been conducted worldwide, and at Vulcano island (Italy) in particular. Both direct and remotely sensed measurements have been used for identifying thermally anomalous areas, but the possible role of the hydrothermal alteration of volcanic products, producing a sealing effect that obscures the surface thermal evidence of fumarolic activity, have never been explored. The novelty of the present study, carried out at La Fossa cone (Vul…

First observations of the fumarolic gas output from a restless caldera: Implications for the current period of unrest (2005-2013) at Campi Flegrei

2013

[1] The fumarolic gas output has not been quantified for any of the currently deforming calderas worldwide, due to the lack of suitable gas flux sensing techniques. In view of resumption of ground uplift (since 2005) and the associated variations in gas chemistry, Campi Flegrei, in southern Italy, is one of the restless calderas where gas flux observations are especially necessary. Here we report the first ever obtained estimate of the Campi Flegrei fumarolic gas output, based on a set of MultiGAS surveys (performed in 2012 and 2013) with an ad-hoc-designed measurement setup. We estimate that the current Campi Flegrei fumarolic sulphur (S) flux is low, on the order of 1.5–2.2 tons/day, sugg…

A new approach for the measurement of gaseous elemental mercury (GEM) and H2S in air from anthropogenic and natural sources: Examples from Mt. Amiata…

2017

Real-time measurements of GEM and H2S discharged from natural and anthropogenic sources are a valuable tool to investigate the dispersion dynamics of these contaminants in air. In this study, a new approach to measure GEM and H2S concentrations in air, carried out by coupling a portable Zeeman atomic absorption spectrometer with high frequency modulation of light polarization (Lumex RA-915M) and a pulsed fluorescence gas analyzer (Thermo Scientific Model 450i), was applied to two distinct areas: (i) in the surroundings of Piancastagnaio (Siena, Central Italy), located in the eastern flanks of Mt. Amiata (a 200,000Â years old volcano), where three geothermal plants are operating and whose ex…