Search results for "LCA"

Characterisation and origin of hydrothermal waters at São Miguel (Azores) inferred by chemical and isotopic composition

2017

Abstract This study focuses on the characterisation and origin of hydrothermal waters discharging from three main active volcanoes (Furnas, Fogo and Sete Cidades) at Sao Miguel, where 33 water with temperatures ranging between 13 and 97 °C, and 5 precipitate samples were collected. The developed conceptual model for this active hydrothermal system reveals that all waters can be classified by Na-HCO 3 , Na-Cl and Na-SO 4 types and are of meteoric origin. This is confirmed by the stable hydrogen and oxygen isotope data that are positioned close to the local meteoric water line (− 4.1‰ ≤ δ 18 O H2O  ≤ 5.2‰; − 17.6‰ ≤ δD H2O  ≤ 20.4‰), except for the Na-Cl type water at Ferraria (Sete Cidades a…

Ultrapotassic Mafic Rocks as Geochemical Proxies for Post-collisional Dynamics of Orogenic Lithospheric Mantle: the Case of Southwestern Anatolia, Tu…

2012

High-Mg ultrapotassic volcanic rock occurrences of lamproitic affinity are exposed in southwestern Anatolia, mostly within the Menderes Massif. From north to south the lamproitic volcanism shows increasingly younger ages ranging from 20 to 4 Ma. Volcanism is contemporaneous with more voluminous shoshonitic, high-K calc-alkaline, and ultrapotassic magmatic activity in the Simav-Selendi, Usak, Kirka, Koroglu, Afyon and Isparta-Golcuk areas. The southward decrease in the age of the volcanism correlates with changes in geochemical composition, particularly a decrease in Sr-87/Sr-86, Pb-207/Pb-204, Zr/Nb and Th/Nb, and an increase in Nd-143/Nd-144, Hf-176/Hf-177, Pb-206/Pb-204, Pb-208/Pb-204 and…

Origin of methane and light hydrocarbons in natural fluids emissions: A study from Greece.

2018

Abstract Greece, a country characterised by intense seismic and volcanic activity, has a complex geodynamic and geological setting that favours the occurrence of many gas manifestations. In this study, we address the origin of CH 4 and light hydrocarbons in cold and thermal emissions discharging along the Hellenic territory. Also, we investigate their possible relationship with the main geochemical composition of the gases and the different geological settings of the sampling sites. For this purpose we collected 101 new samples that were analysed for their chemical (O 2 , N 2 , CH 4 , CO 2 , He, Ne, Ar, H 2 , H 2 S and C 2 -C 6 hydrocarbons) and isotopic (R/R A , δ 13 C-CO 2 , δ 13 C-CH 4 a…

Gas geochemistry and CO2 output estimation at the island of Milos, Greece

2018

Abstract Twenty gas samples have been collected from the natural gas manifestations of Milos Island, the majority of which is found underwater along its coast. Furthermore, three anomalous degassing fumarolic areas (Kalamos, Paleochori and Adamas) have been recognized on-land. Almost all the gases are CO2-dominated with CO2 ranging from 88 to 99% vol for the samples taken underwater, while the on-land manifestations show a wider range (15–98%) due to air contamination. Methane reaches up to 1.0% vol, H2 up to 3.2% vol and H2S up to 3.5% vol indicating a hydrothermal origin of the gases. The isotope composition of He points out to mantle contributions up to 45%, while the C-isotope compositi…

Volcanic activity and gas emissions along the South Sandwich Arc

2020

AbstractThe South Sandwich Volcanic Arc is one of the most remote and enigmatic arcs on Earth. Sporadic observations from rare cloud-free satellite images—and even rarer in situ reports—provide glimpses into a dynamic arc system characterised by persistent gas emissions and frequent eruptive activity. Our understanding of the state of volcanic activity along this arc is incomplete compared to arcs globally. To fill this gap, we present here detailed geological and volcanological observations made during an expedition to the South Sandwich Islands in January 2020. We report the first in situ measurements of gas chemistry, emission rate and carbon isotope composition from along the arc. We sh…

A free plate surface and weak oceanic crust produce single-sided subduction on Earth

2012

[1] Earth’s lithosphere is characterized by the relative movement of almost rigid plates as part of global mantle convection. Subduction zones on present-day Earth are strongly asymmetric features composed of an overriding plate above a subducting plate that sinks into the mantle. While global self-consistent numerical models of mantle convection have reproduced some aspects of plate tectonics, the assumptions behind these models do not allow for realistic single-sided subduction. Here we demonstrate that the asymmetry of subduction results from two major features of terrestrial plates: (1) the presence of a free deformable upper surface and (2) the presence of weak hydrated crust atop subd…

Pathways and fate of REE in the shallow hydrothermal aquifer of Vulcano island (Italy)

2019

Abstract We investigated the geochemical behaviour of major and Rare Earth Elements (REE), together with oxygen and deuterium isotopic composition in the aquifer of Vulcano, the southernmost island of the Aeolian archipelago (Italy). Studied wells, located at different distances from the crater, are characterised by different contributions of the rising volcanic fluids. In particular, those located in the proximity of La Fossa crater are affected by a strong interaction with volcanic-hydrothermal fluids and show REE behaviour similar to that of fresh rocks, suggesting a congruent dissolution of the solid matrix. Samples from the other wells, located in an area where the volcanic deposits ar…

2016

Recent gas flux measurements have shown that Strombolian explosions are often followed by periods of elevated flux, or “gas codas,” with durations of order a minute. Here we present UV camera data from 200 events recorded at Stromboli volcano to constrain the nature of these codas for the first time, providing estimates for combined explosion plus coda SO2 masses of ≈18–225 kg. Numerical simulations of gas slug ascent show that substantial proportions of the initial gas mass can be distributed into a train of “daughter bubbles” released from the base of the slug, which we suggest, generate the codas, on bursting at the surface. This process could also cause transitioning of slugs into cap b…

Ultraviolet Imaging of Volcanic Plumes: A New Paradigm in Volcanology

2017

Ultraviolet imaging has been applied in volcanology over the last ten years or so. This provides considerably higher temporal and spatial resolution volcanic gas emission rate data than available previously, enabling the volcanology community to investigate a range of far faster plume degassing processes, than achievable hitherto. To date this has covered rapid oscillations in passive degassing through conduits and lava lakes, as well as puffing and explosions, facilitating exciting connections to be made for the first time between previously rather separate sub disciplines of volcanology. Firstly, there has been corroboration between geophysical and degassing datasets at ≈ 1 Hz e…

THE BLACK GOLD THAT CAME FROM THE SEA. A REVIEW OF OBSIDIAN STUDIES AT THE ISLAND OF USTICA

2018

Volcanism has produced a natural glass called obsidian that during prehistoric times, from Neolithic to the Metal Ages, was considered a valuable raw material in order to produce efficient cutting tools. Ustica, a small and solitary island in the southwestern Tyrrhenian Sea, despite being volcanic, did not generate any obsidian. Yet the island's soils return large quantities of obsidian fragments, residues of prehistoric use. Where did this material, defined by some archaeologists as the Black Gold of prehistory, come from? This article reviews the archaeometric studies on Ustica’s obsidians, carried out since the middle o f the 1990s, to answer this question. The obsidians of Ustica have b…