Search results for "LCA"
showing 10 items of 1995 documents
Continuous monitoring of hydrogen and carbon dioxide at Mt Etna
2013
article i nfo This study assessed the use of an H2 fuel cell as an H2-selective sensor for volcano monitoring. The resolution, repeatability, and cross-sensitivity of the sensor were investigated and evaluated under known laboratory conditions. A tailor-made device was developed and used for continuously monitoring H2 and CO2 at Mt Etna throughout 2009 and 2010. The temporal variations of both parameters were strongly correlated with the evolution of the volcanic activity during the monitoring period. In particular, the CO2 flux exhibited long-term variations, while H2 exhibited pulses immediately before the explosive activity that occurred at Mt Etna during 2010.
Intercomparison of volcanic gas monitoring methodologies performed on Vulcano Island, Italy
2004
[1] Volcanic gas emissions from fumaroles on the rim of La Fossa crater, Vulcano Island, Italy, were measured simultaneously using direct sampling (for H2O, CO2, total sulfur, HCl and HF), filter packs (for SO2, HCl, HF) and short-path active-mode FTIR measurements (for H2O, CO2, SO2, HCl and HF) in an intercomparison study in May 2002. The results show that Cl/F ratios were in good agreement between all three methods, and that FTIR and direct sampling determined comparable proportions of CO2 and H2O. Amounts of total S observed in direct sampling data were approximately double the amounts of SO2 measured with filter packs and FTIR. This difference could be attributed either to the fact FTI…
Tunable diode laser measurements of hydrothermal/volcanic CO<sub>2</sub> and implications for the global CO<sub&am…
2014
Abstract. Quantifying the CO2 flux sustained by low-temperature fumarolic fields in hydrothermal/volcanic environments has remained a challenge, to date. Here, we explored the potential of a commercial infrared tunable laser unit for quantifying such fumarolic volcanic/hydrothermal CO2 fluxes. Our field tests were conducted between April 2013 and March 2014 at Nea Kameni (Santorini, Greece), Hekla and Krýsuvík (Iceland) and Vulcano (Aeolian Islands, Italy). At these sites, the tunable laser was used to measure the path-integrated CO2 mixing ratios along cross sections of the fumaroles' atmospheric plumes. By using a tomographic post-processing routine, we then obtained, for each manifestati…
Geochemical characterisation of the alkaline and hyperalkaline groundwater in the Othrys Ophiolite Massif, central Greece
2021
The complex geology of Greece includes two important parallel running ophiolitic belts. The Othrys Massif in central Greece belongs to the westernmost of them. In the current study, 33 water samples from cold hyperalkaline and hypothermal (T < 40°C) alkaline springs and 30 gas samples (either dissolved or free) were collected at 17 different sites in and around this wide ophiolite outcrop, aiming to determine the origin of fluids and evidence gas-water-rock interaction processes taking place in the area. Water samples were analysed for their chemical (major ions and trace elements) and isotope (d18O-H2O, d2H-H2O) composition. They can be subdivided into alkaline (pH <11) of both Mg-Ca…
Major-ion bulk deposition around an active volcano (Mt. Etna, Italy)
2005
Bulk atmospheric deposition of major cations (Na, K, Ca, Mg) and anions (Cl, F, SO4) were measured at 15 sites around an active volcano, Mount Etna, from 2001 to 2003. Their composition indicates several natural sources, among which deposition of plume-derived volcanogenic gas compounds is prevalent for F, Cl and S. Plume-derived acidic compounds are also responsible for the prevailing acidic composition of the samples collected on the summit of the volcano (pH in the 2.45–5.57 range). Cation species have complex origin, including deposition of plume volcanogenic ash and aerosols and soil-dust wind re-suspension of either volcanic or carbonate sedimentary rocks. Variation of the deposition …
Mafic and ultramafic enclaves in Ustica Island lavas: Inferences on composition of lower crust and deep magmatic processes
2005
Abstract Ustica Island, southern Tyrrhenian Sea, is constituted of Quaternary alkaline volcanics. A variety of enclaves representative of deep to supra-crustal settings were recently found in a hawaiitic lava flow. Enclaves consist of: (i) Ultramafic meta-cumulates, i.e. clinopyroxenites and wherlites characterized by variably deformed porphyroclastic to granoblastic textures. (ii) Mafic cumulates, i.e. gabbros (± amphibole) and troctolites, the first often characterized by frequent amphibole breakdown coronas (olivine + Ti-augite + plagioclase + magnetite + ilmenite + rhonite) in response to an H 2 O decrease during the ascent, while the troctolites interpreted as meta-cumulates. (iii) Mic…
Radiative heat power at Stromboli volcano during 2000–2011: Twelve years of MODIS observations
2012
Abstract Twelve years of night-time MODIS (Moderate Resolution Imaging Spectroradiometer) observations, has been analysed to detect and quantify the radiative heat power emitted by Stromboli volcano (from March 2000 to September 2011). Using an accurate background subtraction of the MODIS signal at 4 μm, we were able to discriminate two main regimes of thermal radiation, related to different levels of volcanic activity. Effusive eruptions (occurred on December 28, 2002 and February 27, 2007) radiated at an average of ~ 186 MW with a frequency of alert detection of 50–95%. Conversely, during the typical strombolian activity, an average of ~ 9 MW is radiated, with a frequency of alert detecti…
Magmatic signature in acid rain at Masaya volcano, Nicaragua: Inferences on element volatility during lava lake degassing
2021
Abstract Major, minor and trace element concentrations of single rainfall events were investigated at Masaya volcano (Nicaragua) in order to determine the relative contributions of volcanogenic elements. Most of the samples were collected in the summit area of the volcano around the Santiago crater, and two samples, representative of the local background, were collected at a 4.3 km upwind site. Samples from the summit are very acidic with pH down to 2.14 and contain large amounts of volcanogenic elements that can be clearly distinguished from the local background. These elements are released into the atmosphere from the continuously degassing lava lake of the Santiago crater, Masaya volcano…
A geochemical traverse along the “Sperchios Basin – Evoikos Gulf” graben (Central Greece): Origin and evolution of the emitted fluids
2014
The studied area is a 130 km long fast spreading graben in Central Greece. Its complex geodynamical setting includes both the presence of a subduction slab at depth responsible for the recent (Quaternary) volcanic activity in the area and the western termination of a tectonic lineament of regional importance (the North-Anatolian fault). A high geothermal gradient is made evident by the presence of many thermal springs with temperatures from 19 to 82 °C, that discharge along the normal faults bordering the graben. In the period 2004–2012, 58 gas and 69 water samples were collected and their chemical and isotopic analysis revealed a wide range of compositions. Two main groups of thermal water…
Local Earthquake Tomography in the Southern Tyrrhenian Region of Italy: Geophysical and Petrological Inferences on the Subducting Lithosphere
2009
We obtained a high-resolution seismic tomography of the Ionian lithosphere subduction using a new approach based on: (a) the Double-Difference technique for inversions and (b) the statistical post-processing of a great number of preliminary models (Weighted Average Model, WAM method); the latter was used to increase reliability and resolution. In the tomographic model, the high-velocity portion of the steeply dipping Ionian slab is well imaged, as is an underlying low-Vp (≈7.0 km/s) aseismic region. We propose that the low-velocity region can be assigned to a partially hydrated (serpentinized) mantle of the subducting Ionian slab, which progressively dehydrates with depth in dense high-pres…