Search results for "LCA"
showing 10 items of 1995 documents
La pierre et les hommes en Bourgogne. Archéologie et histoire d'une ressource en œuvre du Moyen Âge à l'Époque Moderne
2014
In order to go further limits inherent to subject disjunction, or those imposed by sources, periods or sites, this thesis emphasises a multidisciplinary and diachronic approach of stone supply on medieval and modern building sites. Thanks to the confrontation of buildings with different origins and functions, this work tries to dissect process of choices and stone supply network. It finally considers connection between people and a natural ressource.
Le Clos de Vougeot (Côte-d’Or) : nouvelles observations sur les matériaux de construction et la chronologie du bâti médiéval
2009
Mithilfe sehr unterschiedlicherMethoden hat es sich diese Arbeit vor allem zur Aufgabe gemacht, bestimmte Phasen der Baugeschichte des Clos de Vougeot zu verstehen, um die Organisation und die Entwicklungen eines Zisterzienserhofsin Hinsicht auf diesozialen und historischen Wandlungen besser zu verstehen. Diese Studie bot ebenfalls Gelegenheit, die geologischen Eigenschaften der im Clos de Vougeot eingebrachten Baumaterialien genauestens zu untersuchen und neue Erkenntnisse zum Bau dieser Gebäude zu gewinnen und zu präzisieren.
Apolar versus polar solvents: a comparison of the strength of some organic acids against different bases in toluene and in water
2010
The constants of ion-pair formation with 3-nitroaniline (3NO(2)A) for eight halogenoacetic acids (HAAs, 3a-h: TFA, TCA, TBA, DFA, DCA, DBA, MCA, and MBA), and five 2,2-dichloroalkanoic acids containing 3-8 carbon atoms (HAs, 5a-e: DCPA, DCBA, DCMBA, DCVA, and DCOA) have been determined in TOL at 298.1 K. The results obtained brought to evidence for HAAs the formation of ion-pairs with two different stoichiometries (base-acid, 1:1 or 1:2), while in contrast the HAs furnish only the 1:1 pairs. The different steric and electronic requirements of HAAs and HAs seem to be responsible for such an unlikely behavior. At the same time, the acid-catalyzed MRH of the (Z)-phenylhydrazone of 5-amino-3-be…
Noble gas geochemistry in seismic (Umbria, Italy) and volcanic (Grand Comore Island, Indian Ocean) regions: New methodologies and implications
2020
The noble gases are among the most powerful geochemical tools in different geological settings. For this reason, they represent one of the most valuable tracers of geochemical processes whose variations can be straightforwardly ascribed to magmatic/crustal dynamics. In this dissertation, noble gas (He, Ne, Ar) geochemistry applied in both seismic and volcanic regions are presented. The PhD research has firstly been devoted to the test on the field of an auto-sampler for high-frequency collection of the water samples in order to be analysed for their dissolved noble gases. Then, I developed a lab-based methodology for the in-vacuum extraction of noble gases from waters collected in the coppe…
Gas emissions from five volcanoes in northern Chile and implications for the volatiles budget of the Central Volcanic Zone
2014
This study performed the first assessment of the volcanic gas output from the Central Volcanic Zone (CVZ) of northern Chile. We present the fluxes and compositions of volcanic gases (H2O, CO2, H2, HCl, HF, and HBr) from five of the most actively degassing volcanoes in this region—Láscar, Lastarria, Putana, Ollagüe, and San Pedro—obtained during field campaigns in 2012 and 2013. The inferred gas plume compositions for Láscar and Lastarria (CO2/Stot = 0.9–2.2; Stot/HCl = 1.4–3.4) are similar to those obtained in the Southern Volcanic Zone of Chile, suggesting uniform magmatic gas fingerprint throughout the Chilean arc. Combining these compositions with our own UV spectroscopy measurements of …
Effects of reduced pH on shell integrity of a common whelk from a natural undersea CO2 vent community off Vulcano Island, Italy.
2014
Hexaplex trunculus is a widespread Mediterranean gastropod mollusc that plays a crucial role in benthic ecosystem dynamics. Individuals occur in shallow, sublittoral habitats near Vulcano Island, Italy, where an undersea CO2 vent provides a gradient of seawater acidification mimicing future predicted levels of ocean acidification. Individuals were collected from three sites with declining pH [ambient ( pH 8.18), medium (pH 8.05) and low (pH 7.49)]. Dissolution of shells was clearly evident at the medium (smoothing of outer shell ) and low (pitting and holes) pH sites. Scanning electron microcroscopy will provide a qualitative comparative assessment of micro-scale impacts of shell dissolutio…
Certifcazione ambientale di prodotti agroalimentari LCA dell’olio d’oliva
2009
Oggi viene ampiamente riconosciuta l’importanza di valutare gli impatti ambientali connessi alla produzione dei prodotti agroalimentari. L’applicazione della LCA (Life Cycle Assessment) per la valutazione degli impatti ambientali generati dall’intero ciclo di vita del prodotto risulta particolarmente complessa nel campo alimentare. Ciò a causa delle numerose variabili in gioco, connesse, ad esempio, ai sistemi di coltivazione, specie nell’ottica della definizione delle PCR (Product Category Rules) per la redazione della EPD (Environmental Product Declaration). Il presente studio LCA, effettuato su un olio extravergine d’oliva ottenuto da olive prodotte in Sicilia con sistema di coltivazione…
Síntesis de Protoberberinas y Ciclopentil-isoquinoleínas Dopaminérgicas, y Síntesis de Indenopiridinas Melatoninérgicas
2015
Resumen – Discusión de los resultados. En la presente Tesis Doctoral se han desarrollado diversas rutas de síntesis para la obtención de alcaloides isoquinoleínicos, con diferentes esqueletos, y de hexahidroindenopiridinas. Además se han realizado sus correspondientes ensayos farmacológicos, sobre distintas dianas biológicas basándonos en los resultados obtenidos previamente con este tipo de alcaloides de síntesis y/o aislados de la naturaleza, y de moléculas estructuralmente similares. Se ha observado, a lo largo de muchos años, que las IQ son uno de los metabolitos secundarios activos (MSA) más abundantes y de mayor interés farmacológico de los aislados en especies de la familia de las An…
Ozone depletion in tropospheric volcanic plumes
2010
We measured ozone (O3) concentrations in the atmospheric plumes of the volcanoes St. Augustine (1976), Mt. Etna (2004, 2009) and Eyjafjallajökull (2010) and found O3 to be strongly depleted compared to the background at each volcano. At Mt. Etna O3 was depleted within tens of seconds from the crater, the age of the St. Augustine plumes was on the order of hours, whereas the O3 destruction in the plume of Eyjafjallajökull was maintained in 1–9 day old plumes. The most likely cause for this O3 destruction are catalytic bromine reactions as suggested by a model that manages to reproduce the very early destruction of O3 but also shows that O3 destruction is ongoing for several days. Given the o…
Natural Halogen Emissions to the Atmosphere: Sources, Flux, and Environmental Impact
2022
Understanding the atmospheric geochemical cycle of both natural and anthropogenic halogens is important because of the detrimental effect halogens have on the environment, notably on tropospheric and stratospheric ozone. Oceans are the primary natural source for atmospheric Cl, F, Br, and I, but anthropogenic emissions are still important, especially for Cl. While emissions of human-made halocarbons (e.g., chlorofluorocarbons or CFCs) are expected to continue to decrease allowing progressive stratospheric ozone recovery, volcanic activity (e.g., clusters of mid-scale explosive eruptions or large-scale explosive eruptions) might disturb this recovery over the next decades. This review provid…