Search results for "LCA"
showing 10 items of 1995 documents
Distribution of REEs in box-core sediments offshore an industrial area in SE Sicily, Ionian Sea: Evidence of anomalous sedimentary inputs
2009
The distribution of rare earth elements and yttrium (REEs+Y) has been investigated in box-core sediments recovered from four stations in the Sicilian coastal zone seawards of Augusta, one of the most industrialized and contaminated areas in the Mediterranean region. Shale-like REE patterns and low Y/Ho ratios (close to the chondritic ratio) suggest a dominant terrigenous (geogenic) source for REE. Slight enrichment of LREE over the HREE is interpreted as due to preferential adsorptive transfer of LREE from seawater to sediment particles. Samples from offshore cores exhibit slightly positive Gd and negative Ce anomalies. It is here hypothesized that main drivers of anthropogenic Gd flux towa…
Basaltic Rocks Analyzed by the Spirit Rover in Gusev Crater
2004
The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and MiniâThermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain â¤25% megacrysts. Chemical analyses of rocks by the Alpha Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. MoÌssbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. The…
Chronology of early Archaean granite-greenstone evolution in the Barberton Mountain Land, South Africa, based on precise dating by single zircon evap…
1991
We report precise 207Pb/206Pb single zircon evaporation ages for low-grade felsic metavolcanic rocks within the Onverwacht and Fig Tree Groups of the Barberton Greenstone Belt (BGB), South Africa, and from granitoid plutons bordering the belt. Dacitic tuffs of the Hooggenoeg Formation in the upper part of the Onverwacht Group yield ages between 3445 +/- 3 and 3416 +/- 5 Ma and contain older crustal components represented by a 3504 +/- 4 Ma old zircon xenocryst. Fig Tree dacitic tuffs and agglomerates have euhedral zircons between 3259 +/- 5 and 3225 +/- 3 Ma in age which we interpret to reflect the time of crystallization. A surprisingly complex xenocryst population in one sample documents …
Turmoil at Turrialba Volcano (Costa Rica): Degassing and eruptive processes inferred from high-frequency gas monitoring.
2016
Abstract Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San José. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high‐frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2‐rich gas (CO2/Stotal > 4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2 weeks before eruptions, which are acc…
Coseismic Damage at an Archaeological Site in Sicily, Italy: Evidence of Roman Age Earthquake Surface Faulting
2018
Archaeoseismology can provide a useful chronological tool for constraining earthquakes and documenting significant evidence that would otherwise be lost. In this paper, we report a case of surface faulting on ancient man-made structures belonging to the archaeological site of Santa Venera al Pozzo situated along the eastern flank of Mt. Etna volcano in eastern Sicily (southern Italy), which is affected by well-developed tectonic faults. Geological surveys highlight a set of fractures affecting the archaeological ruins, suggesting the occurrence of a capable fault zone across the area. An integrated geophysical survey was carried out in order to identify the main subsurface tectonic disconti…
Gas Leakage From Shallow Ponding Magma and Trapdoor Faulting at Sierra Negra Volcano (Isabela Island, Galápagos)
2022
We report on new volcanic gas composition results acquired in October 2017 at Minas de Azufre, a persistent fumarolic field topping the resurgent Sierra Negra caldera, in the Galápagos archipelago. Our results indicate that the Minas de Azufre fumaroles are moderately hydrous (52–64 mol.% H2O) and rich in CO2 (35–46 mol.%), with total sulfur (ST) being 21–35 times less abundant than CO2. SO2, the most abundant S species, is released at an average rate of 19 ± 9 tons/day. Using a volatile saturation model that provides the composition of magmatic gases at equilibrium with western Galápagos basaltic melt (48 wt. % SiO2) in the 400–0.1 MPa pressure range, we infer that Minas de Azufre fumaroli…
Anomalous Behavior of Zirconium and Hafnium in Volcanic Fumarolic Fluids
2022
The Zirconium and Hafnium concentrations in worldwide fumaroles fed by magmatic fluids reveal that the Zr/Hf ratio is inversely related to the temperature of emission. Lower Zr/Hf ratio values below the chondritic signature are found in fluids having the highest temperature while super-chondritic Zr/Hf ratio values are found in lower temperatures. Sub-chondritic values of the Zr/Hf ratio may be related to larger volatility of Hf-chloride gas species with respect to Zr-Cl gas species, while super-chondritic ratios may correspond to fluid-rock processes resulting from cooling of uprising magmatic fluids. We propose that subchondritic Zr/Hf ratio values in fumaroles associated with high temper…
New insights into magma dynamics during last two eruptions of Mount Etna as inferred by geochemical monitoring from 2002 to 2005
2006
Two distinct eruptive events characterize the volcanic activity at Mount Etna during the 2002 to 2005 period. We identified signals of magma ascent preceding these eruptions by geochemical monitoring of both chemical composition and He-isotope ratio of gas emissions from five locations in the peripheral area of the volcano. The geochemical signals are interpreted using the models proposed by Caracausi et al. (2003a, 2003b) and allow identification of episodes of magma ascent and estimation of the pressures of degassing magma. As observed for the 2001 eruption (Caracausi et al., 2003b), magma ascent probably triggered the onset of the 2002–2003 eruption, and minor events of magma ascent were…
Temporal evolution of the Fogo Volcano magma storage system (Cape Verde Archipelago): a fluid inclusions perspective
2023
The architecture of the magma storage system underneath Fogo Volcano (Cape Verde Archipelago) is characterised using novel fluid inclusion results from fifteen basanites, spanning the last 120 thousand years of volcanic activity, and encompassing a major flank collapse event at -73 ka. Fluid inclusions, hosted in olivine and clinopyroxene, are made of pure CO2, and based on their textural characteristics, are distinguished in early (Type I) and late (Type II) stage. Inclusions homogenize to a liquid phase in the 2.8 to 30.8 degrees C temperature range. Densities values, recalculated assuming an original 10% H2O content at the time of trapping, range from 543 to 952 kg center dot m(-3), and …
Onset of the Messinian Salinity Crisis: Sedimentological, petrographic and geochemical characterization of the pre-salt sediments from a new core (Ca…
2022
The present study aims to reconstruct the environmental changes leading to the Messinian Salinity Crisis during the transition from the Tortonian-Messinian marine conditions to the Messinian evaporitic environments. The core 3AGN2S04, recently drilled in the Caltanissetta Basin (Sicily), was analyzed to reveal the petrographic, mineralogical and geochemical characteristics of the late Tortonian – early Messinian pre-salt sediments. In particular, the facies characterization of the carbonates and organic-rich shales of the Calcare di Base (CdB) member allowed to understand its significance in the paleoenvironmental evolution towards salt deposition and to the reconstruct the brecciation proc…