Search results for "LEM"

Sewage sludge as cheap alternative to microalgae as feedstock of catalytic hydrothermal liquefaction processes

2019

Abstract Production of biocrude through hydrothermal liquefaction (HTL) of sewage sludge (SS) and Chlorella vulgaris was investigated. NiMo/Al2O3 (KF 851), CoMo/Al2O3 (KF 1022) and activated carbon felt, tested as catalysts at 598 K for 30 min, did not change the biocrude yield but significantly improved its quality. Quantitative sulfur removal and lower oxygen content were found in biocrude when KF 851 and KF 1022 were used with C. vulgaris. The same catalysts decreased O/C and S/C ratio of the biocrude from SS. The highest HHV (38.19 MJ/kg) and H/C ratio (1.65) and the lowest O/C (0.11) of the biocrude from SS were obtained with the cheaper activated carbon felt. A new product phase, prob…

Metal distribution in the process of lignocellulosic ethanol production from heavy metal contaminated sorghum biomass

2016

II) Wood pellets for home heating can be considered environmentally friendly fuels? Heavy metals determination by inductively coupled plasma-optical …

2016

Abstract The aim of the present study was to determine the concentrations of twelve potentially hazardous elements in wood pellet ashes obtained by the combustion of 13 pellet brands for sale in Italy, the impact of adding the ashes to soils and health risk of operator due to dust exposure. Samples were analysed by Inductively Coupled Plasma Optical Emission Spectrometry. The concentrations of heavy metals in ashes from stoves ranged from 0.41 to 7.2 mg kg − 1 for As, from 1.3 to 12 mg kg − 1 for Sb, from 1.8 to 12 mg kg − 1 for Zn, from 0.23 to 0.8 mg kg − 1 for Pb, from 0.18 to 2.8 mg kg − 1 for Ni, from 0.09 to 1.0 mg kg − 1 for Cd, from 0.46 to 3.4 mg kg − 1 for Cr, from 0.94 to 2.7 mg …

Evaluating the material resource efficiency of secondary aluminium production: A Monte Carlo-based decision-support tool

2019

The contamination of aluminium streams during the different life cycle stages by alloy mixing and/or accumulation of foreign elements, in combination with the limited melt purification options during remelting, represents an important limiting factor in recycling. Consequently, in secondary aluminium production, primary aluminium is used to dilute the concentration of the residual elements, and alloying elements are added to adjust the composition to the target alloy specifications. However, adding elements, for which their refinement in a subsequent recycling step is problematic, results in permanent down-cycling or ‘quality losses’. Hence, it is crucial to more efficiently control the com…

Heavy metal uptake by plants from wastewater of different pulp concentrations and contaminated soils

2021

There is a lack of information on the extent of mineral extraction by plants from wastewater in arid and semi-arid environments in developing countries. This research assesses the performance of Alhagi and Mallow plant species for the absorption of heavy metals around the tailings dam of a copper mine in Iran. The industrial wastewater, known as the pulp, from the copper mine site has different concentrations of heavy metals. In a laboratory setting the plants were cultivated and irrigated with different pulp concentrations (0, 20, 40, 60, 80, and 100%) in water. Heavy metals (chromium, manganese, cadmium, and lead) accumulation in the aerial parts and roots of the plants, and the in-situ s…

Ashes from Sewage Sludge and Bottom Sediments as a Source of Bioavailable Phosphorus

2018

Phosphorus is an element necessary for the growth of plants. As phosphate rock gets depleted, it becomes an increasingly scarce resource. Therefore, it seems necessary to implement simple methods of cheap and effective phosphorus recovery from waste. The ashes of municipal sewage sludge and bottom sediments constitute particularly valuable sources of phosphorus. However, these materials usually carry significant amounts of pollutants, including heavy metals. Optimization of ash phosphorus sequential extraction methods from a thermal conversion of sewage sludge and bottom sediments allows to select an effective and simple technology of phosphorus recovery, while maintaining low heavy metal p…

Smart Urban Energy Districts and Energy Policies

2018

The deployment of smart cities appears a strategic factor for reducing environmental impact and increasing competitivity of economic systems across the world. Although terminology is similar worldwide, the different political assets and social enviroments largely affect the development models. Drivers indeed are quite different, such as the speed at which transformations take place. As a result, implementation of measures is carried out differently and realizations of smart city projects can be strongly different. Europe, China and U.S.A. approaches are compared in this paper to provide the reader with a broader view about different smart city implementations, with a focus on the electricit…

Analysis of uncontrolled phosphorus precipitation in anaerobic digesters under thermophilic and mesophilic conditions.

2019

This study compares the operation of mesophilic and thermophilic anaerobic digestion of sewage sludge and their effects in uncontrolled phosphorus precipitation. The research has been carried out using a pilot plant consisting of two digesters of 1.6 m3 working volume, treating the mixed sludge of Alzira WWTP (Valencia, Spain). The digesters were operated in parallel, at different conditions: mesophilic (38 ± 2.0°C) and thermophilic (55 ± 2.5°C) temperatures and organic loading rates (OLR) ranging from 1.1 to 1.7 kg volatile solids (VS) m−3 d−1 and different hydraulic retention times (HRT) 20, 15 and 12 days. Uncontrolled precipitation was evaluated through P, Mg and Ca mass balances in bot…

Large multiple neighborhood search for the soft-clustered vehicle-routing problem

2021

Abstract The soft-clustered vehicle-routing problem (SoftCluVRP) is a variant of the classical capacitated vehicle-routing problem. Customers are partitioned into clusters and all customers of the same cluster must be served by the same vehicle. In this paper, we present a large multiple neighborhood search for the SoftCluVRP. We design and analyze multiple cluster destroy and repair operators as well as two post-optimization components, which are both based on variable neighborhood descent. The first allows inter-route exchanges of complete clusters, while the second searches for intra-route improvements by combining classical neighborhoods (2-opt, Or-opt, double-bridge) and the Balas-Simo…

Convergence of direct recursive algorithm for identification of Preisach hysteresis model with stochastic input

2015

We consider a recursive iterative algorithm for identification of parameters of the Preisach model, one of the most commonly used models of hysteretic input-output relationships. The classical identification algorithm due to Mayergoyz defines explicitly a series of test inputs that allow one to find parameters of the Preisach model with any desired precision provided that (a) such input time series can be implemented and applied; and, (b) the corresponding output data can be accurately measured and recorded. Recursive iterative identification schemes suitable for a number of engineering applications have been recently proposed as an alternative to the classical algorithm. These recursive sc…