Search results for "LENI"

CCDC 225461: Experimental Crystal Structure Determination

2004

Related Article: M.G.Basallote, F.Estevan, M.Feliz, M.J.Fernandez-Trujillo, D.A.Hoyos, R.Llusar, S.Uriel, C.Vicent|2004|Dalton Trans.||530|doi:10.1039/b315841a

Lattice sites of diffused gold and platinum in epitaxial ZnSe layers

2000

Abstract The lattice location of diffused gold and platinum in zinc selenide (ZnSe) epitaxial layers was studied using the Rutherford backscattering (RBS) channeling technique. Thin Au and Pt films were evaporated onto ZnSe samples. The Au/ZnSe samples were annealed at 525°C and the residual Au film was removed by etching. Channeling angular scan measurements showed that about 30% of Au atoms were close to substitutional site (displaced about 0.2 A). In the case of the Pt/ZnSe samples the annealing temperatures ranged from 600°C to 800°C. The Pt minimum yields along 〈1 0 0〉 direction were close to the random value, varying from 80% to 90%. The measured Pt angular scans along 〈1 0 0〉 and 〈1 …

2015

Biphenols are important structure motifs for ligand systems in organic catalysis and are therefore included in the category of so-called "privileged ligands". We have developed a new synthetic pathway to construct these structures by the use of selenium dioxide, a stable, powerful, and commercially available oxidizer. Our new, and easy to perform protocol gives rise to biphenols and diaryl selenides depending on the solvent employed. Oxidative treatment of phenols in acetic acid yields the corresponding biphenols, whereas conversion in pyridine results in the preferred formation of diaryl selenides. As a consequence, we were able to isolate a broad scope of novel diaryl selenides, which cou…

Synthesis, reactivity and structural studies of selenide bridged carboranyl compounds.

2006

Reaction of the lithium salt Li[1-R-1,2-closo-C(2)B(10)H(10)] with selenium under mild conditions, followed by hydrolysis gave the diselenide compound (1-Se-2-R-1,2-closo-C(2)B(10)H(10))(2) in contrast to the well-reported mercapto compounds 1-SH-2-R-1,2-closo-C(2)B(10)H(10) obtained using a similar synthetic procedure. Details for the preparation and X-ray structural characterisation of the new compounds (2-Me-1,2-closo-C(2)B(10)H(10))(2)Se, (1-Se-2-R-1,2-closo-C(2)B(10)H(10))(2) (R = Me, Ph, ) are specified. To further explore the mechanism of the dimerization reaction, the complex [Au(1-Se-2-Me-1,2-closo-C(2)B(10)H(10))(PPh(3))] was synthesized, confirming the existence of the intermedia…

A Selenium-Nitrogen Chain with Selenium in Different Oxidation States

2017

Selenium mobilization in soils due to volcanic derived acid rain: An example from Mt Etna volcano, Sicily

2011

International audience; The significant amounts of selenium (Se) emitted by volcanoes may have important impact on human health due to the narrow range between nutrition requirement and toxic effects for living organisms upon Se exposure. Although soils play a key role in determining the level in food and water and thereby human health, little is known about the behaviour of Se in volcanic soils. In this work we evaluated the Se release during rainwater–soil interaction under controlled conditions using soils collected on the flanks of Etna volcano and synthetic rain. Selenium concentrations in soil leachate solutions displayed a spatial distribution, which cannot be explained by plume depo…

Carbon and oxygen stable isotope compositions of late Pleistocene mammal teeth from dolines of Ajoie (Northwestern Switzerland)

2014

AbstractFossils of megaherbivores from eight late Pleistocene 14C- and OSL-dated doline infillings of Ajoie (NW Switzerland) were discovered along the Transjurane highway in the Swiss Jura. Carbon and oxygen analyses of enamel were performed on forty-six teeth of large mammals (Equus germanicus, Mammuthus primigenius, Coelodonta antiquitatis, and Bison priscus), coming from one doline in Boncourt (~ 80 ka, marine oxygen isotope stage MIS5a) and seven in Courtedoux (51–27 ka, late MIS3), in order to reconstruct the paleoclimatic and paleoenvironmental conditions of the region. Similar enamel δ13C values for both periods, ranging from − 14.5 to − 9.2‰, indicate that the megaherbivores lived i…

Debitage by fracturing in the osseous industry of Cova del Parpalló (Gandía-Valencia, Spain): A preliminary study

2016

Abstract The excavations carried out by L. Pericot from 1929 to 1931 in the Cova del Parpallo documented the Gravettian in the base, a Solutrean layer, and a Magdalenian. This sequences comprise an exceptional assemblage of portable art because of the number of plaquets/objects and the great chronological amplitude. With all this information, Parpallo was included in the reduced list of reference sites to organize the European Upper Paleolithic sequence in the first half of the 20th century. The Magdalenian layers were organized in four phases, following H. Breuil's classical proposal. Changes in bases morphology and decorative topics on osseous points permitted this correlation, identifyin…

The Solutrean - Magdalenian Transition: a view from Iberia

2012

The paper examines the Upper SolutreaneArchaic Magdalenian/Badegoulian succession on the base of lithic and bone tool production, chrono-stratigraphic data and radiocarbon dates from the Cantabrian and Mediterranean regions of Iberia, mainly the areas of Asturias and Valencia (Spain). The discussion considers a reduced number of variables (characteristic stone tools, bone points and decoration techniques) and highlights the elements in common. The analysis concerning the transformation of lithic production at Cova del Parpallo provides new data for the Upper SolutreaneArchaic Magdalenian/ Badegoulian transition.

Land use change, soil erosion and alluvial dynamic in the lower Doubs Valley over the 1st millenium AD (Neublans, Jura, France)

2003

International audience; Geochemical and particle size analyses, surface scanning magnetic susceptibility, microscopic charcoal counting and pollen analysis, have been carried out on two cores from the lower Doubs valley in order to reconstruct the land use history. The interpretation of anthropogenic pollen indicators and micro-charcoal deposits is discussed in relation to the lithological variation of sedimentary accumulation and evolution of the settlement. The environmental changes which occurred during the 1st and the 6th century AD reflect the impact of human activities on the landscape in the immediate surroundings of the site. Multiproxy indicators indicate that soil erosion as a con…