Search results for "LENI"
showing 10 items of 756 documents
Mo 3 Q 7 (Q = S, Se) Clusters Containing Dithiolate/Diselenolate Ligands: Synthesis, Structures, and Their Use as Precursors of Magnetic Single‐Compo…
2013
The coordination chemistry of dithiolene and diselenolene ligands towards the all-selenium [Mo3Se7Br6]2– dianion has been investigated. Complexes (nBu4N)2[Zn(dmit)2] (dmit = 1,3-dithia-2-thioxo-4,5-dithiolate) and (nBu4N)2[Zn(dsit)2] (dsit = 1,3-dithia-2-thioxo-4,5-diselenolate) were employed as ligand precursors. The (nBu4N)2[Zn(dmit)2] complex in acetonitrile at reflux showed unexpected reactivity with [Mo3Se7Br6]2– dianion in which the inner Se atoms were replaced by S (all but the μ3-Se atom) to afford a series of mixed chalcogen [Mo3Se7–xSx(dmit)3]2– (x = 0–6) dianions. Reaction of the [Mo3S4Se3Br6]2– dianion with (nBu4N)2[Zn(dmit)2] under similar conditions also produced a mixed dmit-…
Animal Models of Stress - Current Knowledge and Potential Directions
2021
Finding new therapies and new antidepressant agents is of high clinical priority given that many cases of depressive disorder do not respond to conventional monoaminergic antidepressants such as selective serotonin reuptake inhibitors, tricyclic antidepressants, and monoamine oxidase inhibitors The authors demonstrated that electroacupuncture and fluoxetine, a second-generation antidepressant categorized as a selective serotonin reuptake inhibitor (Perez-Caballero et al , 2014), regulate the expression of key proteins in the calmodulin kinase (CAMK) signaling pathway, which are related to depression in the hippocampi of rats (Takemoto-Kimura et al , 2017;Xie et al , 2019) In a paper on “Sho…
Myślenie dialogiczne. W polu gry o prawdę etyczną
2019
Przedmiotem analiz artykułu jest pojęcie myślenia dialogicznego. Jest ono różne od pojęcia dialogu–literackiej figury, która służy do przekazywania poglądów filozoficznych. Myślenie dialogiczne, jako merytorycznie nowy sposób uprawiania filozofii, pojawia się dopiero w początkach XX w. Zrodziło się ono jako sprzeciw wobec redukcyjnych metod nauk przyrodniczych i przeniesienia ich w obszar myśli humanistycznej i antropologicznej. W ten sposób powstał nowy nurt filozoficzny – filozofia dialogu. Rozwijał się w duchu uwag krytycznych kierowanych pod adresem dotychczasowej tradycji filozofii zachodniej. W artykule przedstawione zostały konstytutywne cechy myślenia dialogicznego. Najpierw przepro…
Nanowires for NEMS Switches
2020
Nanoelectromechanical systems (NEMS) are a promising novel technology for operation in extreme conditions (e.g. high temperature and radiation levels), where complementary semiconductor technology devices might fail due to electronic instability. An example for a NEMS device is a nanowire-based switch, which employs mechanical deflection of a nanowire to open and close an electrical circuit. To date, assembly and operation of individual nanowire based NEMS switches have been successfully demonstrated at laboratory level, but their further technological development remains a challenge. This chapter gives an insight into the current advances in applications of nanowires for NEMS switches. Syn…
An electrochemical route towards the fabrication of nanostructured semiconductor solar cells
2010
This work presents our preliminary results regarding an electrochemical process which allows the growth of nanostructured materials by means of nanopore templates. Also we analyze possible applications of this process to fabricate nanostructured semiconductors, such as CIGS, suitable for photovoltaic devices, and we consider the implications from the perspective of characterization techniques and device modelling when using such a technology.
Selenium Nanoparticles Synthesized via a Facile Hydrothermal Method
2012
Crystalline selenium nanostructures were synthesized from the reaction of a GeSe3 glass with water at 85°C for 144 hours. The hydrolysis of the Ge-Se bonds releases Se fragments in the solution where they form a colloidal suspension of amorphous nanospheres. The later evolve toward a more stable hexagonal phase (trigonal) leading to the anisotropic growth of one-dimensional monocrystalline structures. Filaments, bars and tubes of monocrystalline trigonal selenium were obtained with diameters ranging from 10 nm to 1 µm and aspect ratio up to 180. This simple process in aqueous solution opens new perspectives for the synthesis of 1D nanoparticles of trigonal selenium at large scale.
Selenium and tellurium nanomaterials
2018
Abstract Over the last 40 years, the rapid and exponential growth of nanotechnology led to the development of various synthesis methodologies to generate nanomaterials different in size, shape and composition to be applied in various fields. In particular, nanostructures composed of Selenium (Se) or Tellurium (Te) have attracted increasing interest, due to their intermediate nature between metallic and non-metallic elements, being defined as metalloids. Indeed, this key shared feature of Se and Te allows us the use of their compounds in a variety of applications fields, such as for manufacturing photocells, photographic exposure meters, piezoelectric devices, and thermoelectric materials, t…
Çështja e gjuhës greke gjatë gjysmës së dytë të shekullit XVIII dhe kontributi i Tommaso Stanislao Velastit për lëvizjen e filohelenizmit napolitan
2022
Il saggio ricostruisce l'attività intellettuale di T. S. Velasti e illumina il suo contributo alla definizione della questione della lingua greca alla luce della documentazione inedita conservata presso l'Archivio del Seminario Greco Albanese di Palermo, dove trovò riparo dopo la soppressione della Compagnia di Gesù in Sicilia nel 1767. The essay reconstructs the intellectual activity of T. S. Velasti and illuminates his contribution to the definition of the question of the Greek language in the light of the unpublished documentation preserved in the Archives of the Greek Albanian Seminary in Palermo, where he found shelter after the suppression of the Society of Jesus in Sicily in 1767.
Vascular complications following bladder drained, simultaneous pancreas-kidney transplantation: the University of Miami experience
2000
Vascular complications remain a significant nonimmunologic source of pancreas allograft loss. From February 1993 through January 1998, we performed 98 simultaneous pancreas-kidney transplantations (SPK) using pancreatic exocrine bladder drainage in patients with type 1 insulin-dependent diabetes mellitus and end-stage renal disease. They originally received quadruple immunosuppression, and since May 1997 triple immunosuppression protocol (tacrolimus, mycophenolate mofetil, and steroids). The patients' mean age was 37 years (range 24-53 years), including 50 women and 48 men with a mean follow-up of 42 months. The overall rate of vascular complications was 6% (5 patients). The vascular compli…
Sequential Hepatogenic Transdifferentiation of Adipose Tissue-Derived Stem Cells: Relevance of Different Extracellular Signaling Molecules, Transcrip…
2009
Adipose tissue contains a mesenchymal stein cell (MSC) population Known as adipose-derived stein cells (ASCs) capable of differentiating into different cell types. Our aim was to induce hepatic transdifferentiation of ASCs by sequential exposure to several combinations of cytokines, growth factors, and hormones. The most efficient hepatogenic protocol includes fibroblastic growth factors (FGF) 2 and 4 and epidermal growth factor (EGF) (step 1), hepatocyte growth factor (HGF), FGF2, FGF4, and nicotinamide (Nic) (step 2), and oncostatin M (OSM), dexamethasone (Dex), and insulin-tranferrin-selenium (step 3). This protocol activated transcription factors [GATA6, Hex, CCAAT/enhancer binding prot…