Search results for "LF"
showing 10 items of 12543 documents
Aerosol Chemistry Resolved by Mass Spectrometry: Linking Field Measurements of Cloud Condensation Nuclei Activity to Organic Aerosol Composition.
2016
Aerosol hygroscopic properties were linked to its chemical composition by using complementary online mass spectrometric techniques in a comprehensive chemical characterization study at a rural mountaintop station in central Germany in August 2012. In particular, atmospheric pressure chemical ionization mass spectrometry ((-)APCI-MS) provided measurements of organic acids, organosulfates, and nitrooxy-organosulfates in the particle phase at 1 min time resolution. Offline analysis of filter samples enabled us to determine the molecular composition of signals appearing in the online (-)APCI-MS spectra. Aerosol mass spectrometry (AMS) provided quantitative measurements of total submicrometer or…
Magnetic shuffling of coronal downdrafts
2017
Channelled fragmented downflows are ubiquitous in magnetized atmospheres, and have been recently addressed from an observation after a solar eruption. We study the possible back-effect of the magnetic field on the propagation of confined flows. We compare two 3D MHD simulations of dense supersonic plasma blobs downfalling along a coronal magnetic flux tube. In one, the blobs move strictly along the field lines; in the other, the initial velocity of the blobs is not perfectly aligned to the magnetic field and the field is weaker. The aligned blobs remain compact while flowing along the tube, with the generated shocks. The misaligned blobs are disrupted and merged by the chaotic shuffling of …
Testing a theoretical resistance law for overland flow on a stony hillslope
2020
Overland flow, sediments, and nutrients transported in runoff are important processes involved in soil erosion and water pollution. Modelling transport of sediments and chemicals requires accurate estimates of hydraulic resistance, which is one of the key variables characterizing runoff water depth and velocity. In this paper, a new theoretical power–velocity profile, originally deduced neglecting the impact effect of rainfall, was initially modified for taking into account the effect of rainfall intensity. Then a theoretical flow resistance law was obtained by integration of the new flow velocity distribution. This flow resistance law was tested using field measurements by Nearing for the …
The impact of degassing on the oxidation state of basaltic magmas: A case study of Kīlauea volcano
2016
Volcanic emissions link the oxidation state of the Earth's mantle to the composition of the atmosphere. Whether the oxidation state of an ascending magma follows a redox buffer – hence preserving mantle conditions – or deviates as a consequence of degassing remains under debate. Thus, further progress is required before erupted basalts can be used to infer the redox state of the upper mantle or the composition of their co-emitted gases to the atmosphere. Here we present the results of X-ray absorption near-edge structure (XANES) spectroscopy at the iron K-edge carried out for a series of melt inclusions and matrix glasses from ejecta associated with three eruptions of Kīlauea volcano (Hawai…
ATR–FTIR Spectral Analysis and Soluble Components of PM10 And PM2.5 Particulate Matter over the Urban Area of Palermo (Italy) during Normal Days and …
2019
Several epidemiological studies have shown a close relationship between the mass of particulate matter (PM) and its effects on human health. This study reports the identification of inorganic and organic components by attenuated total reflectance-Fourier-transform infrared spectroscopy (ATR-FTIR) analysis in PM10 and PM2.5 filters collected from three air quality monitoring stations in the city of Palermo (Sicily, Italy) during non-Saharan dust events and Saharan events. It also provides information on the abundance and types of water-soluble species. ATR-FTIR analysis identified sulfate, ammonium, nitrate, and carbonate matter characterized by vibrational frequencies at 603, 615, 670, and …
New insights on secondary minerals from Italian sulfuric acid caves
2018
Sulfuric acid minerals are important clues to identify the speleogenetic phases of hypogene caves. Italy hosts ~25% of the known worldwide sulfuric acid speleogenetic (SAS) systems, including the famous well-studied Frasassi, Monte Cucco, and Acquasanta Terme caves. Nevertheless, other underground environments have been analyzed, and interesting mineralogical assemblages were found associated with peculiar geomorphological features such as cupolas, replacement pockets, feeders, sulfuric notches, and sub-horizontal levels. In this paper, we focused on 15 cave systems located along the Apennine Chain, in Apulia, in Sicily, and in Sardinia, where copious SAS minerals were observed. Some of the…
Reaction path models of magmatic gas scrubbing
2016
Gas-water-rock reactions taking place within volcano-hosted hydrothermal systems scrub reactive, water-soluble species (sulfur, halogens) from the magmatic gas phase, and as such play a major control on the composition of surface gas manifestations. A number of quantitative models of magmatic gas scrubbing have been proposed in the past, but no systematic comparison of model results with observations from natural systems has been carried out, to date. Here, we present the results of novel numerical simulations, in which we initialized models of hydrothermal gas-water-rock at conditions relevant to Icelandic volcanism. We focus on Iceland as an example of a "wet" volcanic region where scrubb…
Incised valleys and tidal seaways: the example of the Miocene Uzès-Castillon basin, SE France.
2012
Abstract The sedimentology and stratigraphy of the Miocene deposits of the Uzès-Castillon basin are revisited. This basin, located in SE France at the junction between the perialpine foreland basin and the W Mediterranean margin, sits in a syncline that formed during the latest Cretaceous Pyrenean tectonic phase. It records the succession of shallow-water mixed siliciclastic to dominantly bioclastic carbonates that alternate with shelf marls. The clastic carbonates were accumulated as a stack of subtidal dunes and bars that were formed by tidal currents channelized in a seaway following the syncline axis. The marls indicate deposition in more protected and locally deeper waters, as interflu…
Active tectonics along the south east offshore margin of Mt. Etna: New insights from high-resolution seismic profiles
2018
The offshore margin of Mt. Etna has been shaped by Middle Pleistocene to Holocene shortening and extension and, more recently, by gravity-related sliding of the volcanic edifice. These processes have acted contemporaneously although the gravitational component largely prevails over the tectonic one. In order to investigate this issue, we focused on the main role of active tectonics along the south-eastern offshore of Mt. Etna by means of marine high-resolution seismic data. Seismic profiles revealed post-220 ka sedimentary deposits unconformably overlaying the Lower-Middle Pleistocene Etnean clayey substratum and volcanics of the Basal Tholeiitic phase and the Timpe phase. Offshore Aci Trez…
Stage–Discharge Relationship for an Upstream Inclined Grid with Transversal Bars
2016
AbstractCheck dams with grids upgrading upstream are often used in mountain rivers, where intense sediment transport and steep slopes occur. In some cases, sloping grids are used in the construction of debris flow breakers. In this paper, the outflow process of an upstream-inclined grid with transversal bars is studied by using the dimensional analysis and the incomplete self-similarity theory. Next, the theoretical analysis shows that a power equation can be used for establishing the stage-discharge equation. The coefficient of the power equation depends on both the slope angle and the void ratio, whereas the exponent depends only on the slope angle. Finally, this deduced stage–discharge r…