Search results for "LIES"
showing 10 items of 1093 documents
Effect of the metal dilution on the thermal and light-induced spin transition in [FexMn1−x(bpp)2](NCSe)2: When T(LIESST) reaches T1/2
2008
International audience; The thermal and light-induced spin transition in [FexMn1−x(bpp)2](NCSe)2 (bpp = 2,6-bis(pyrazol-3-yl)pyridine) has been investigated by magnetic susceptibility, photomagnetism and diffuse reflectivity measurements. These complexes display a thermal spin transition and exhibit the light-induced excited spin state trapping (LIESST) effect at low temperature. For each mixed-crystal system, the thermal spin transition temperature, T1/2, and the relaxation temperature of the photo-induced high-spin state, T(LIESST), have been systematically determined. It appears that T1/2 decreases with the metal dilution while T(LIESST) remains unchanged, suggesting that the two interco…
A thermal- and light-induced switchable one-dimensional rare loop-like spin crossover coordination polymer
2019
Rare loop-like isostructural one-dimensional coordination polymer (1D-CP) systems formulated as {Fe(DPIP)2(NCSe)2}n·4DMF (1) and {Fe(DPIP)2(NCSe)2}n·4DMF (2) were obtained by self-assembling FeII and pseudohalide NCX−(X = S, Se) ions in presence of the V-shaped bidentate bridging ligand, namely, N,N′-dipyridin-4-ylisophthalamide (DPIP), and were characterized by elemental analysis, IR spectroscopy, TGA, single crystal X-ray diffraction and powder X-ray diffraction. The magnetic studies show that complex 2 undergoes a complete thermally induced spin crossover (SCO) behavior centered at T1/2 = 120 K with ca. 5 K thermal hysteresis loop and light-induced excited spin state trapping effect (LIE…
An unprecedented hetero-bimetallic three-dimensional spin crossover coordination polymer based on the tetrahedral [Hg(SeCN)4]2− building block
2019
[EN] Self-assembly of octahedral FeII ions, trans-1,2-bis(4-pyridyl) ethane (bpe) bridging ligands and [Hg(XCN)(4)](2-) (X = S (1), Se (2)) tetrahedral building blocks has afforded a new type of hetero-bimetallic Hg-II-Fe-II spin-crossover (SCO) 3D 6,4-connected coordination polymer (CP) formulated {Fe(bpe)[Hg(XCN)(4)]}(n). For X = S (1), the ligand field is close to the crossing point but 1 remains paramagnetic over all temperatures. In contrast, for X = Se (2) the complex undergoes complete thermal induced SCO behaviour centred at T-1/2 = 107.8 K and complete photoconversion of the low spin state into a metastable high-spin state (LIESST effect) with T-LIESST = 66.7 K. The current results…
Thermal and optical switching of bistable iron compounds and possible applications
1993
Abstract Iron(II) coordination compounds with ligand field strengths close to the mean spin pairing energy may undergo thermal spin transition in the solid as well as in the liquid state. The thermodynamically stable state is high spin (HS) 5T2 (under Oh symmetry) with (t2)4 e2 electron configuration above the critical transition temperature Tc, and low spin (LS) 1A1 with (t2)6 electron configuration below Tc. The spin transition curve γHS(T) (molar fraction of HS molecules as function of temperature) can be abrupt or gradual, with or without hysteresis, or even with a plateau near Tc. Tc itself can vary over the whole temperature scale between the liquid helium region up to above room temp…
Metastable electronic states induced by nuclear decay and light
1994
Radioactive atoms incorporated in insulating solid-state compounds create various kinds of chemical and physical “after-effects” upon nuclear disintegration. Mossbauer emission spectroscopy of57Co-labelled coordination compounds has undoubtedly become the most informative technique to detect such after-effects like aliovalent charge and spin states of the nucleogenic iron atom resulting from the57Co(EC)57Fe decay, low energy excitations of crystal field and Zeeman states, linkage isomerism, radical formation with subsequent redox reactions, and others. We have extensively studied57Co-labelled complexes with [CoIIN6] cores employing time-integral and time-resolved Mossbauer emission spectros…
Parental discourses of language ideology and linguistic identity in multilingual Finland
2018
Finland is officially a bilingual country but it is in practice multilingual. In the current study, we examined how mothers and fathers of mixed-language families linguistically identified themselves and others, and how ideological discourses and concepts historically and socially situated in Finland circulated through the parents’ talk. The parents of three families in which at least Finnish, Swedish and English were used on a daily basis were interviewed. A discourse nexus approach showed that the concept of ‘mother tongue(s)’ played a central role and that although all family members were in practice multilingual, there was a strong tendency across the couples to identify themselves and …
Hesitant versus confident family language policy: a case of two single-parent families in Finland
2022
Abstract During the past decade, the field of family language policy has broadened its scope and turned its attention to diverse family configurations in versatile sociolinguistic contexts. The current study contributes to this endeavor by focusing on two single-parent families who live in Finland and who strive to support Russian as a family language. Applying nexus analysis as an epistemological stance and as an analytical lens, the study takes an emic perspective on family language policy. Furthermore, it examines how family language policy is manifested and negotiated during mother–child play and what discourses shape it. The findings reveal two contrasting ways in which family language…
Liver stiffness in chronic hepatitis C virus infection
2019
Abstract Introduction . The severity of liver fibrosis can be assessed noninvasively today by liver stiffness measurements. Vibration-controlled transient elastography, shear wave elastography or magnetic resonance elastography are techniques increasingly used for this purpose. Methods . This article presents the recent advances in the use of new techniques for liver fibrosis assessment in chronic hepatitis C: the correlation between liver stiffness values and liver fibrosis estimated by liver biopsies, the prognosis role of liver stiffness values, their usefulness in monitoring the treatment response, in assessing the severity of portal hypertension and in estimating the presence of esopha…
Frontline Professionals Performing Collaborative Work with Low-Income Families: Challenges across Organizational Boundaries
2020
This article discusses certain challenges relating to interagency collaboration between the Norwegian Labour and Welfare Administration (NAV) and Child Welfare Services (CWS). We have asked what obstacles to holistic work with low-income families who receive measures from NAV and CWS simultaneously can be identified. The departure point is collaboration on a local project at the municipal level. The differences between the views of the individual services (and the mandates based on these views) with regard to parental obligations have proved challenging. Using the theory of institutional logic, we have explored how different logics have influenced these services’ approaches to parenthood an…
From human to artificial mouth, from basics to results
2009
Papier publié également dans : Proceedings en ligne de American Institute of Physics http://proceedings.aip.org/dbt/dbt.jsp?KEY=APCPCS&Volume=1137&Issue=1 (RN 2508; Sensory perception of the flavor release during the eating of a food piece is highly dependent upon mouth parameters. Major limitations have been reported during in vivo flavor release studies, such as marked intra- and inter-individual variability. To overcome these limitations, a chewing simulator has been developed to mimic the human mastication of food samples. The device faithfully reproduces most of the functions of the human mouth. The active cell comprises several mobile parts that can accurately reproduce shear and comp…