Search results for "LIMIT"

Design of experiment approach for the optimization of polybrominated diphenyl ethers determination in fine airborne particulate matter by microwave-a…

2015

Abstract A sensitive and selective procedure for the determination of 12 polybrominated diphenyl ethers (BDE-28, BDE-49, BDE-47, BDE-66, BDE-100, BDE-119, BDE-99, BDE-155, BDE-154, BDE-153, BDE-139 and BDE-183) in airbone particulate matter (PM2.5) at trace level has been developed. The proposed method includes extraction PM2.5-bound PBDEs by microwave-assisted extraction (MAE) followed by gel permeation chromatography (GPC) clean-up and determination by GC-MS/MS using a programmed temperature vaporizer (PTV) in large volume injection (LVI) mode to introduce the sample to the chromatographic system. A design of experiment (DoE) approach was used for the optimization of large volume injectio…

First results on dark matter annihilation in the Sun using the ANTARES neutrino telescope

2013

A search for high-energy neutrinos coming from the direction of the Sun has been performed using the data recorded by the ANTARES neutrino telescope during 2007 and 2008. The neutrino selection criteria have been chosen to maximize the selection of possible signals produced by the self-annihilation of weakly interacting massive particles accumulated in the centre of the Sun with respect to the atmospheric background. After data unblinding, the number of neutrinos observed towards the Sun was found to be compatible with background expectations. The 90% CL upper limits in terms of spin-dependent and spin-independent WIMP-proton cross-sections are derived and compared to predictions of two sup…

TWO NEW FAMILIES OF PLATICURTIC CURVES FOR LIMITED INTERVALS

2006

Determination of 40 currently used pesticides in airborne particulate matter (PM 10) by microwave-assisted extraction and gas chromatography coupled …

2011

A confirmatory and sensitive procedure has been developed for the determination of 40 currently used pesticides (Cups) in airborne particulate matter (PM 10) at trace level. The proposed method includes extraction of PM 10-bound pesticides by microwave-assisted extraction (MAE) followed by a gel permeation chromatography (GPC) clean-up and determination by GC-MS/MS. The injection mode and the main parameters in MS/MS were optimized. The matrix effect was also evaluated. Recoveries ranged from 70 to 120% except for pyrimethanil and pirimicarb. The limit of quantification (LOQ) ranged from 1.32 to 39.47 pg m(-3), when air volumes of 760 m(3) were collected. The method was applied to 38 sample…

The suitability of a topographical instrument for an integrated approach to the cartography of posidonia-oceanica meadows

1993

A large-scale map of the phytobenthic communities and, in particular, of the Posidonia oceanica meadow in the Bay of Mondello (Palermo, Italy) was made. The map was set up from aerial photography, which was verified by divers along ground-lines. The upper limit of the underwater vegetation, with special reference to the Posidonia oceanica meadow, was accurately located using a geodimeter. This topographical instrument proved to be very useful in realizing such cartography.

On-fibre solid-phase microextraction coupled to conventional liquid chromatography versus in-tube solid-phase microextraction coupled to capillary li…

2006

This paper compares the advantages and disadvantages of two different configurations for the extraction of triazines from water samples: (1) on-fibre solid-phase microextraction (SPME) coupled to conventional liquid chromatography (LC); and (2) in-tube SPME coupled to capillary LC. In-tube SPME has been effected either with a packed column or with an open capillary column. A critical evaluation of the main parameters affecting the performance of each method has been carried out in order to select the most suitable approach according to the requirements of the analysis. In the on-fibre SPME configuration the fibre coating was polydimethylsiloxane (PDMS)-divinylbenzene (DVB). The limits of de…

B-mode versus A-mode ultrasonographic measurements of mucosal thickness in vivo

2002

Abstract Objective: The objective of this study was to compare the measurement accuracy of A-mode and B-mode ultrasonographic assessments of palatal masticatory mucosal thickness in vivo. Study Design: Thickness of palatal masticatory mucosa in the molar region of 50 volunteers was measured once with a B-mode ultrasound device (10 MHz) combined with a standoff for intraoral applications. At identical reading points thickness was also assessed with an A-mode device (5 replicates) and by needle probing for determination of true thickness. Results: On average true thickness ranged between 2.9 and 3.3 mm (95% confidence intervals; median, 3.1 mm). B-mode ultrasonography overestimated truth by 0…

Vertical distribution of AhR-activating compounds in sediments contaminated by modernized pulp and paper industry

2013

Increased ethoxyresorufin-O-deethylase (EROD) activity is a sensitive biomarker of exposure to the chemicals which activate the aryl hydrocarbon receptor (AhR) and induce the cytochrome P450 system, such as many polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs) and polychlorinated biphenyls (PCBs). Pulp bleaching was one of the main sources of PCDDs and PCDFs until elemental chlorine free (ECF) and total chlorine free bleaching processes since 1990s have remarkably decreased but not completely eliminate discharges of these chemicals. In addition, historically contaminated sediments may act as a source of these persistent contaminants. In this study, the contam…

Drawing and extruding: Theoretical and approximate formulas

1969

The problem of drawing of wires and of strips has been treated in several studies; among these the studies of Sachs seem essential. However, the results deduced according to similar theories are not always in accordance with the experimental results: reduction of area or of thickness are in fact usually smaller than those resulting from the theory. This is in dependance of the fact that Sachs has adopted the Limiting Condition of Yielding by v. Mises, according to which the limit values of stress in traction and compression are equal. More recently other AA. (Alberti, Noto La Diega, Bugini), admitting the Limiting Condition of Yielding by A. (or of the Paraboloid of Revolution) of which we …

Large Number Asymptotics for Two-Component Systems with Self-Consistent Coupling

2014

We shall consider the large number asymptotics of particle models for partial differential equations describing two component mixtures with simplest kind of self-consistent couplings. We shall recall in particular two examples related to different classes of models, the first one having both particle-like components and the second one having only one particle-like component (the other being described as a fluid); for these examples, different techniques on the probabilistic and analytic point of view are to be used to rigorously prove the convergence to a limit of the self-consistent terms in a “mean-field”-like asymptotics. The two models were analysed resp. in Bernardin and Ricci (Kinet R…