Search results for "LIMIT"

On Non-Gaussian limiting laws for certain statistics of Wigner Matrices

2013

This paper is a continuation of our papers [12-14] in which the limiting laws of fluctuations were found for the linear eigenvalue statistics Tr j(M(n)) and for the normalized matrix elements √n̅jjj(M(n)) of differentiable functions of real symmetric Wigner matrices M(n) as n →∞. Here we consider another spectral characteristic of Wigner matrices, xnA [j] = Tr j(M(n))A(n), where {A(n)}∞n=1 is a certain sequence of non-random matrices. We show first that if M(n) belongs to the Gaussian Orthogonal Ensemble, then xnA [j] satisfies the Central Limit Theorem. Then we consider Wigner matrices with i.i.d. entries possessing the entire characteristic function and find the limiting probability law f…

An on-line system for preconcentration and determination of lead in wine samples by FAAS

2002

A flow injection method has been developed for the direct determination of free available Pb(II) and total Pb content in wine samples. The method is based on the chemical sorption of Pb(II), from pH 7 buffered solutions, on a packed polyurethane foam column, modified by addition of 2-(2-benzothiazolylazo)-p-cresol (BTAC). After this step, lead was directly eluted with a stream of 0.1 mol l(-1) HCl into an air C(2)H(2) flame in which lead was determined by atomic absorption spectrometry. Total lead was analyzed after sample digestion with nitric acid and hydrogen peroxide, being free available lead determined by direct sample on-line preconcentration and elution. The method provides a limit …

Scopolamine analysis in beverages: Bicolorimetric device vs portable nano liquid chromatography

2021

Abstract Scopolamine (SCP) is often involved in sexual assaults and robberies, particularly in recreational environments. Therefore, analytical tools are required for the analysis of this compound amenable for the field. In this work, a sensor for SCP is described based on the entrapment of KMnO4 into polydimethylsiloxane (PDMS). The possibility of using KMnO4 in combination with the reagent 1,2-naphtoquinone-4-sulfonate (NQS) giving a double sensor acting as a bicolorimetric device is also demonstrated. In contact with the sample, the PDMS composite delivers MnO4−, which reacts rapidly with SCP under basic conditions causing a change of the color of the solution that can be related to the …

Date-rape evidence through fast determination of γ-butyrolactone in adulterated beverages.

2021

Abstract An infrared spectroscopy (IR) based methodology has been developed to determine γ-butyrolactone (GBL) in adulterated beverages. The proposed method permits the direct screening of GBL in beverages and involves a minimum sample treatment requiring less than 2 min for quantitative determination of GBL. Sensitivity of IR method was improved by using liquid-liquid extraction (LLE) providing detection limits of 0.023 mg g−1. Accuracy of the proposed methodology was evaluated through the analysis of soft beverages and alcoholic cocktails spiked with GBL at concentration levels ranging from 0.075 to 10 mg g−1 providing recovery values from 91 to 100%. GBL was determined in twelve blind-sp…

Content Variation of Iron and Copper in Wine Obtained from Wine Vineyards Recas

2013

Abstract Wine grapes are brought to the center in baskets, plastic containers, wooden bene, or more modern like metal bene. From picking and transport can be transmitted to grapes, the iron or copper from all equipment on metal and after will be transmitted also to wines produced. It must therefore control of how was made the insulation of protective metal bene to avoid contact the metal with grapes. The aim of this work involves evaluating the content of iron and copper in wines and vineyards of Recas. The results indicated that the values determined by methods Photocolorimeters were within normal limits and revealed that the level of iron and copper in samples analyzed were not influenced…

Intersezioni ai bordi del linguaggio. Note su Wittgenstein e Heidegger

2008

Modelling of thermal stresses in bearing steel structure generated by electrical current impulses

2018

This work is the study of one particular candidate for white etching crack (WEC) initiation mechanism in wind turbine gearbox bearings: discharge current impulses flowing through bearing steel with associated thermal stresses and material fatigue. Using data/results from previously published works, the authors develop a series of models that are utilized to simulate these processes under various conditions/local microstructure configurations, as well as to verify the results of the previous numerical studies. Presented models show that the resulting stresses are several orders of magnitude below the fatigue limit/yield strength for the parameters used herein. Results and analysis of models …

Analytic evaluation of Raman intensities in coupled-cluster theory

2007

We present the first implementation for the analytic calculation of polarizability derivatives using coupled-cluster theory. These derivatives are related to the intensity of bands seen in Raman spectroscopy, and are therefore important quantities that can also be measured experimentally. The required theory of analytic third derivatives is discussed and also connected to response theory to allow the calculation of frequency-dependent quantities. This work includes the use of a string-based general coupled-cluster/configuration-interaction program which makes the calculation of Raman intensities for arbitrary coupled-cluster or configuration-interaction methods up to the full configuration-…

Modified Gaussian models applied to the description and deconvolution of peaks in chiral liquid chromatography.

2020

Abstract The description of the profiles of chromatographic peaks has been studied extensively, with a large number of proposed mathematical functions. Among them, the accuracy achieved with modified Gaussian models that describe the deviation of an ideal Gaussian peak as a change in the peak variance or standard deviation over time, has been highlighted. These models are, in fact, a family of functions of different complexity with great flexibility to adjust chromatographic peaks over a wide range of asymmetries and shapes. However, an uncontrolled behaviour of the signal may occur outside the region being fitted, forcing the use of different strategies to overcome this problem. In this wo…

Optimization of the first wall for the DEMO water cooled lithium lead blanket

2015

The maximum heat load capacity of a DEMO First Wall (FW) of reasonable cost may impact the decision of the implementation of limiters in DEMO. An estimate of the engineering limit of the FW heat load capacity is an essential input for this decision. This paper describes the work performed to optimize the FW of the Water Cooled Lithium-Lead (WCLL) blanket concept for DEMO fusion reactor in order to increase its maximum heat load capacity. The optimization is based on the use of water at typical Pressurised Water Reactors conditions as coolant. The present WCLL FW with a waved plasma-faced surface and with circular channels was studied and the heat load limit has been predicted with FEM analy…