Search results for "LOAD"
showing 10 items of 1967 documents
ChemInform Abstract: Optical Switches with Biplanemers Obtained by Intramolecular Photocycloaddition Reactions of Tethered Arenes
2013
The dimerization of anthracene by a [4π + 4π] cycloaddition is one of the oldest and best known reactions in photochemistry. In the series of tethered bichromophoric arenes, this reaction type could be extended to anthracene–naphthalene, naphthalene–naphthalene and recently even to anthracene–benzene and naphthalene–benzene systems. Cyclophanes, which can be regarded as twofold or multiple tethered systems, are not discussed here. The cycloisomerizations are performed by irradiation at the long-wavelength absorption (λ > 270 nm), whereas shorter wavelengths (λ < 270 nm) lead to cycloreversions, which can be also achieved by a thermal route. The systems represent therefore a P- and T-type ph…
Photochemical formation of [4.4.4](1,3,5)cyclophanes from 1,3,5-tris(3-phenylpropenoyl)benzenes
2004
Abstract Irradiation of 1,3,5-tris(3-phenylpropenoyl)benzene ( 1a ) yields in solution a dimer 2a by a threefold head-to-head/anti [2π+2π]cycloaddition. The stereochemistry of this [4.4.4](1,3,5)cyclophane was determined by 1H and 13C NMR studies including NOE measurements and a calculation of the AA′MM′ spin pattern of the methine protons. In contrast to the solution photochemistry, which is presumably controlled by the arrangement of an excimer, the irradiation in the crystalline state leads by a topochemical control to a dimer 3a , which contains a single four-membered ring.
From local measures to regional impacts: Modelling changes in nutrient loads to the Baltic Sea
2021
Study Region: Our study region is the Baltic Sea Drainage Basin (BSDB), which covers an area of 1.8 Mio km2 distributed over 14 countries in northern Europe. Study Focus: We use a large-scale hydrological and nutrient transport model (E-HYPE) to model basin-wide impacts of measure scenarios on the Baltic Sea, where eutrophication is a critical issue for the marine ecosystem. We constructed measure scenarios based on stakeholder acceptance, established in workshops in different regions around the Baltic. These measures include local stream reach to catchment scale measures aiming to reduce nutrient transport into the stream network (buffer strips, stormwater ponds) and measures aiming to red…
Physical Load and Preventive Measures in Metal Manufacturing Industry
2020
In today’s advanced work environment, workers are still exposed to ergonomic risks in the work environment and employees are exposed physically hard work that includes moving loads and frequent repetitive movements at fast pace. For the ergonomic risk analysis and workload assessment, three work operations with the high physical activity were selected: the welder’s workplace, the ironing board sorting line and the ironing board’s packing station. Subjective and objective ergonomics research methods were used. Research results show that employees in selected work operations are exposed to a fast work speed and often, monotonous movements at the sorting line and lifting heavy loads at the iro…
OMC: An Optical Monitoring Camera for INTEGRAL
1998
The INTEGRAL payload has been designed to study simultaneously gamma-ray sources in a wide field of view over many decades in energy (around 2 eV + 4 keV − 20 MeV) and thus make a major contribution to short time-scale high-energy astrophysics. The OMC will observe the optical emission from the prime targets of the gamma-ray instruments with the support of the x-ray monitor. This capability will provide invaluable diagnostic information on the nature and the physics of the sources over a broad wavelength range. The main scientific objectives will be: (1) to monitor the optical emission from the sources observed by the gamma- and x-ray instruments, measuring the time and intensity structure …
THE UFFO SLEWING MIRROR TELESCOPE FOR EARLY OPTICAL OBSERVATION FROM GAMMA RAY BURSTS
2013
While some space born observatories, such as SWIFT and FERMI, have been operating, early observation of optical after grow of GRBs is still remained as an unexplored region. The Ultra-Fast Flash Observatory (UFFO) project is a space observatory for optical follow-ups of GRBs, aiming to explore the first 60 seconds of GRBs optical emission. Using fast moving mirrors to redirect our optical path rather than slewing the entire spacecraft, UFFO is utilized to catch early optical emissions from GRB within 1 sec. We have developed the UFFO Pathfinder Telescope which is going to be on board of the Lomonosov satellite and launched in middle of 2012. We will discuss about scientific potentials of t…
The INTEGRAL experiment
1998
The International Gamma-ray Astrophysics Laboratory (INTEGRAL) is conceived as the next logical step in gamma-ray astronomy after the US Compton Gamma-Ray Observatory (CGRO) and the French/Russian SIGMA mission. The INTEGRAL scientific payload consists of two main instruments (Imager and Spectrometer) and two monitor instruments (X-Ray Monitor and Optical Transient Camera). The INTEGRAL spectrometer "SPI" is optimized for detailed measurements of gamma-ray lines and mapping of diffuse sources. It combines a coded aperture mask with an array of large volume, high-purity germanium detectors. The detectors make precise measurements of the gamma-ray energies over the 20 keV-8 MeV energy range. …
The EUSO Data Simulation and Analysis Tree
2004
The "Extreme Universe Space Observatory - EUSO" is the first Space mission devoted to the exploration of the outermost bounds of the Universe through the investigation of the Extremely-High Energy Cosmic Rays, EECR, using the Earth atmosphere as a giant detector. The objective is to obtain a detailed description of the Cosmic Ray spectrum beyond 5×1019 eV together with a map of the arrival directions. EUSO will detect EECR looking at the streak of fluorescence light produced when such a particle interacts with the atmosphere. The signal will be detected after its propagation upward from the dark Earth atmosphere to the EUSO telescope accommodated, as external payload, on the International S…
The X-ray gas scintillation spectrometer experiment on the first spacelab flight
1985
The First Spacelab mission, launched on Space ShuttleFlight STS-9 in November 1983 carried a multidisciplinary payload which was intended to demonstrate that valuable scientific results can be achieved from such short duration missions. The payload complement included a spectrometer to undertake observations of the brighter cosmic X-ray sources. The primary scientific objectives of this experiment were the study of detailed spectral features in cosmic X-ray sources and their associated temporal variations over a wide energy range from about 2 up to 30 keV. The instrument based on the gas scintillation proportional counter had an effective area of some 180 cm2 with an energy resolution of ∼9…
Non-stationary spectral moments of base excited MDOF systems
1988
The paper deals with the evaluation of non-stationary spectral moments of multi-degree-of-freedom (MDOF) line systems subjected to seismic excitations. The spectral moments of the response are evaluated in incremental form solution by means of an unconditionally stable step-by-step procedure. As an application, the statistics of the largest peak of the response are also evaluated.