Search results for "Laser Spectroscopy"

showing 10 items of 151 documents

The Role of Adenine Excimers in the Photophysics of Oligonucleotides

2009

Energies and structures of different arrangements of the stacked adenine homodimer have been computed at the ab initio CASPT2 level of theory in isolation and in an aqueous environment. Adenine dimers are shown to form excimer singlet states with different degrees of stacking and interaction. A model for a 2-fold decay dynamics of adenine oligomers can be supported in which, after initial excitation in the middle UV range, unstacked or slightly stacked pairs of nucleobases will relax by an ultrafast internal conversion to the ground state, localizing the excitation in the monomer and through the corresponding conical intersection with the ground state. On the other hand, long-lifetime intra…

Models MolecularPhotochemistryUltraviolet RaysMolecular ConformationOligonucleotidesAb initioPhotochemistryExcimerBiochemistryCatalysisNucleobaseColloid and Surface ChemistryUltrafast laser spectroscopySinglet stateQuantitative Biology::BiomoleculesChemistryAdenineDNAGeneral ChemistryConical intersectionInternal conversion (chemistry)Chemical physicsNucleic Acid ConformationSpectrophotometry UltravioletGround stateDimerizationHydrogenJournal of the American Chemical Society
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High-precision measurements of the hyperfine structure of cobalt ions in the deep ultraviolet range

2023

Scientific reports 13(1), 4783 (2023). doi:10.1038/s41598-023-31378-1

MultidisciplinaryPhysics in Generalcollinear laser spectroscopyhyperfine structurespektroskopiadeep ultraviolet600IGISOLkobolttiydinfysiikkaddc:600cobalt[PHYS.PHYS.PHYS-GEN-PH]Physics [physics]/Physics [physics]/General Physics [physics.gen-ph]Scientific Reports
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Performance of a high repetition pulse rate laser system for in-gas-jet laser ionization studies with the Leuven laser ion source @ LISOL

2012

The Leuven Isotope Separator On-Line (LISOL) facility at the Cyclotron Research Center (CRC) Louvain-la-Neuve; The laser ionization efficiency of the Leuven gas cell-based laser ion source was investigated under on- and off-line conditions using two distinctly different laser setups: a low-repetition rate dye laser system and a high-repetition rate Ti:sapphire laser system. A systematic study of the ion signal dependence on repetition rate and laser pulse energy was performed in off-line tests using stable cobalt and copper isotopes. These studies also included in-gas-jet laser spectroscopy measurements on the hyperfine structure of 63Cu. A final run under on-line conditions in which the ra…

Nuclear and High Energy PhysicsActive laser medium29.25.Ni 29.25.Rm 41.85.ArPhysics::OpticsLaser pumping[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]7. Clean energy01 natural sciencesAtmospheric-pressure laser ionizationlaw.inventionlaw0103 physical sciencesUltrafast laser spectroscopyddc:530[PHYS.PHYS.PHYS-INS-DET]Physics [physics]/Physics [physics]/Instrumentation and Detectors [physics.ins-det]Physics::Atomic Physics010306 general physicsInstrumentationDye laserta114010308 nuclear & particles physicsChemistryLaserIon sourceAtomic physicsAtomic vapor laser isotope separationNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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Changes in nuclear structure along the Mn isotopic chain studied via charge radii

2016

The hyperfine spectra of $^{51,53-64}$Mn were measured in two experimental runs using collinear laser spectroscopy at ISOLDE, CERN. Laser spectroscopy was performed on the atomic $3d^5\ 4s^2\ ^{6}\text{S}_{5/2}\rightarrow 3d^5\ 4s4p\ ^{6}\text{P}_{3/2}$ and ionic $3d^5\ 4s\ ^{5}\text{S}_2 \rightarrow 3d^5\ 4p\ ^{5}\text{P}_3$ transitions, yielding two sets of isotope shifts. The mass and field shift factors for both transitions have been calculated in the multiconfiguration Dirac-Fock framework and were combined with a King plot analysis in order to obtain a consistent set of mean-square charge radii which, together with earlier work on neutron-deficient Mn, allow the study of nuclear struc…

Nuclear and High Energy PhysicsField (physics)N=28FOS: Physical sciences114 Physical sciences01 natural sciencesSpectral line0103 physical sciencesPROGRAMNuclear Physics - ExperimentNeutronNuclear Experiment (nucl-ex)LASER SPECTROSCOPY010306 general physicsSpectroscopyCALCIUM ISOTOPESNuclear ExperimentHyperfine structureisotopesPhysicsisotoopitta114010308 nuclear & particles physicsNuclear structureSHIFTShyperfine spectraOrder (ring theory)Charge (physics)mangaaniQUADRUPOLE-MOMENTSnuclear structuremanganeseSHELL-MODELlaser spectroscopyNEUTRONPräzisionsexperimente - Abteilung BlaumAtomic physicsPhysical Review C
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Change in structure between the $I = 1/2$ states in $^{181}$Tl and $^{177,179}$Au

2018

Abstract The first accurate measurements of the α-decay branching ratio and half-life of the I π = 1 / 2 + ground state in 181Tl have been made, along with the first determination of the magnetic moments and I = 1 / 2 spin assignments of the ground states in 177,179Au. The results are discussed within the complementary systematics of the reduced α-decay widths and nuclear g factors of low-lying, I π = 1 / 2 + states in the neutron-deficient lead region. The findings shed light on the unexpected hindrance of the 1 / 2 + → 1 / 2 + , 181Tl → g 177 Aug α decay, which is explained by a mixing of π 3 s 1 / 2 and π 2 d 3 / 2 configurations in 177Aug, whilst 181Tlg remains a near-pure π 3 s 1 / 2 .…

Nuclear and High Energy PhysicsHadronNuclear physicsThallium nuclei[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciences0103 physical sciencesddc:530Nuclear Physics - ExperimentLaser spectroscopy010306 general physicsSpin (physics)PhysicsMagnetic moment010308 nuclear & particles physicsBranching fractionLandé g-factorGold nucleiDecay spectroscopylcsh:QC1-9993. Good healthNuclear deformationPräzisionsexperimente - Abteilung BlaumAtomic physicsGround stateNucleonlcsh:PhysicsDimensionless quantity
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Resonance ionization schemes for high resolution and high efficiency studies of exotic nuclei at the CRIS experiment

2019

© 2019 This paper presents an overview of recent resonance ionization schemes used at the Collinear Resonance Ionization Spectroscopy (CRIS) setup located at ISOLDE, CERN. The developments needed to reach high spectral resolution and efficiency will be discussed. Besides laser ionization efficiency and high resolving power, experiments on rare isotopes also require low-background conditions. Ongoing developments that aim to deal with beam-related sources of background are presented. ispartof: Nuclear Instruments & Methods In Physics Research Section B-Beam Interactions With Materials And Atoms vol:463 pages:398-402 ispartof: location:SWITZERLAND, CERN, Geneva status: published

Nuclear and High Energy PhysicsHigh resolution7. Clean energy01 natural sciencesResonance ionization spectroscopylaw.inventionNuclear physicslawIonization0103 physical sciencesDalton Nuclear InstituteNuclear structurePhysics::Atomic PhysicsSpectral resolution010306 general physicsSpectroscopyInstrumentationPhysicsLarge Hadron Collider010308 nuclear & particles physicsDelayed ionizationNuclear structureLaser3. Good healthResearchInstitutes_Networks_Beacons/dalton_nuclear_instituteResonance ionizationHigh-resolution laser spectroscopyNuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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New developments of the in-source spectroscopy method at RILIS/ISOLDE

2013

At the CERN ISOLDE facility, long isotope chains of many elements are produced by proton-induced reactions in target materials such as uranium carbide. The Resonance Ionization Laser Ion Source (RILIS) is an efficient and selective means of ionizing the reaction products to produce an ion beam of a chosen isotope. Coupling the RILIS with modern ion detection techniques enables highly sensitive studies of nuclear properties (spins, electromagnetic moments and charge radii) along an isotope chain, provided that the isotope shifts and hyperfine structure splitting of the atomic transitions can be resolved. At ISOLDE the campaign to measure the systematics of isotopes in the lead region (Pb, Bi…

Nuclear and High Energy PhysicsIon beamNuclear physics[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex]01 natural sciences7. Clean energyISOLTRAPIonNuclear physicsIonization0103 physical sciencesPhysics::Atomic PhysicsLaser spectroscopy010306 general physicsSpectroscopyNuclear ExperimentInstrumentationHyperfine structureRresonance laser ionization010308 nuclear & particles physicsChemistryResonanceIon sourceIsotope shiftHyperfine structureAtomic physics
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Theoretical and experimental study of primary radiation defects in KNbO3 perovskite crystals

2000

Abstract The results of large-scale computer simulations of point defects – F-type electron centers and hole polarons bound to a potassium vacancy – in perovskite KNbO3 crystals are presented. One-site polarons and two-site (molecular) polarons are expected to coexist, both are characterized by close absorption energies around 1 eV. The transient absorption spectra and decay kinetics observed after ns-pulsed electron beam irradiation have been measured for different KNbO3 crystals. The relaxation kinetics of the optical density vary considerably for different impurity concentrations and sample stoichiometries. Experimental data are discussed in the light of the presented calculations.

Nuclear and High Energy PhysicsMaterials scienceElectronPolaronCrystallographic defectCondensed Matter::Materials ScienceImpurityVacancy defectUltrafast laser spectroscopyCondensed Matter::Strongly Correlated ElectronsAtomic physicsAbsorption (electromagnetic radiation)InstrumentationPerovskite (structure)Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
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Collinear laser spectroscopy of stable palladium isotopes at the IGISOL facility

2020

AbstractCollinear laser spectroscopy on stable palladium isotopes was performed at the IGISOL facility in Jyväskylä in preparation for an experiment on its neutron-rich isotopes. Five transitions from different initial atomic states were tested, with the goal of finding the most spectroscopically efficient. The observed intensities afforded a comparison with atomic-level population predictions based on charge-exchange calculations. For some transitions hyperfine parameters of 105Pd were measured, which were found to be in good agreement with literature values. A King plot analysis was performed using the measured isotope shifts and known charge radii from literature to determine the atomic …

Nuclear and High Energy PhysicsMaterials scienceField (physics)collinear laser spectroscopyPopulationspektroskopiachemistry.chemical_elementPhysics Atomic Molecular & Chemical7. Clean energy01 natural sciences010305 fluids & plasmas0103 physical sciencesSHIFTPhysics::Atomic PhysicsIGISOLPhysical and Theoretical Chemistry010306 general physicsSpectroscopyeducationHyperfine structureeducation.field_of_studyScience & TechnologyIsotopePhysicsCondensed Matter PhysicspalladiumAtomic and Molecular Physics and OpticsPhysics NuclearPhysics Condensed MatterchemistryIsotopes of palladiumPhysical SciencesHYPERFINE-STRUCTUREAtomic physicsydinfysiikkaPalladium
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Laser spectroscopy and β-decay asymmetry from on-line implanted nuclei

1985

The method of collinear laser spectroscopy is combined with s-radiation detected optical pumping by implanting the optically oriented atoms into a cubic crystal.

Nuclear and High Energy PhysicsMaterials sciencePhysics::OpticsResonanceCrystal structureCubic crystal systemCondensed Matter PhysicsAtomic and Molecular Physics and OpticsOptical pumpingBeta particleUltrafast laser spectroscopyPhysics::Atomic PhysicsPhysical and Theoretical ChemistryAtomic physicsSpectroscopyHyperfine structureHyperfine Interactions
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