Search results for "Light Scattering"
showing 10 items of 464 documents
Studies of the physicochemical and structural properties of self-assembling cationic pyridine derivatives as gene delivery agents.
2015
New amphiphilic pyridine derivatives containing dodecyloxycarbonyl substituents at positions 3 and 5 and cationic moieties at positions 2 and 6 have been designed and synthesised. Compounds of this type can be considered as synthetic lipids. The corresponding 1,4-dihydropyridine (1,4-DHP) derivatives have earlier been proposed as a promising tool for plasmid DNA (pDNA) delivery in vitro. In this work studies of the self-assembling properties of amphiphilic pyridine derivatives leading to the formation of liposomes, determination of particle size, zeta-potential and critical micelle concentration (CMC) with dynamic light scattering (DLS) measurements are described. Furthermore, thermal analy…
Light-Scattering and -Absorption of Nanoparticles
2012
To understand the optical response of nanoparticles to the incident light, a theoretical description is needed, which is given in this chapter. In a first approximation, these optical properties can be described using a quasi-static model, which assumes a particle-size much smaller than the wavelength of the light. The derivation of the polarizability of a sphere, which describes its optical properties, and further extensions for spheroidal, rod-shaped and coated particles are given in Sect. 2.2.
Giant Dzyaloshinskii-Moriya Interaction and Room-Temperature Nanoscale Skyrmions in CoFeB/MgO Heterostructures
2021
Magnetic skyrmions in heavy metal (HM)/CoFeB/MgO structures are of particular interest for skyrmion-based magnetic tunnel junction (MTJ) devices because of their reliable generation, stability and read-out through purely electrical methods. To optimize the properties, such as stability, a strong Dzyaloshinskii-Moriya interaction (DMI) is required at room temperature. Here, using first-principles calculations, we demonstrate that giant DMI can be obtained in Ir/CoFe structures with an Fe-terminated configuration. Moreover, Brillouin light scattering measurements show that indeed Ta/Ir/Co20Fe60B20/MgO thin films with perpendicular magnetic anisotropy exhibit a large DMI value (1.13 mJ/m2), wh…
Probing dynamics of dense suspensions: three-dimensional cross-correlation technique
1997
We describe the realization of a novel three-dimensional (3D) cross-correlation scheme, which provides the possibility to measure dynamic structure factors of highly concentrated colloidal samples without contributions of multiply scattered light. The apparatus is easier to align and more compact than the two-colour cross-correlation apparatus, which is commercially available. This should make the 3D cross-correlation set-up more convenient for routine applications, for example in industrial laboratories. We describe the set-up and discuss some special features of the optical components.
Single Particle Motion of Hard-Sphere-Like Polymer Micronetwork Colloids Up to the Colloid Glass Transition
1997
Polymer micronetwork spheres swollen in a good solvent can be regarded as colloids which require no special stabilisation to avoid aggregation. Their interactions can be timed by changing the degree of internal crosslinking. The phase behaviour and the static structure factor demonstrate that crosslink density of 1:10 (inverse number of monomer units between crosslinks) is sufficient to achieve hard sphere behaviour. We designed a host-tracer system consisting of core-shell micronetwork spheres (core: polystyrene; shell: poly-t-butylacrylate) in a host of refractive-indexmatched poly-t-butylacrylate micronetwork colloids. Employing a crosslink density of 1:10 and tuning the polydispersity s…
In-situ integrating nephelometer measurements of the scattering properties of atmospheric aerosols at an urban coastal site in western Mediterranean
2012
Abstract Measurements of aerosol scattering properties obtained during the period from March 2006 to December 2010 at Valencia (Spain) have been analyzed. The total aerosol scattering (σsp) and backscattering (σbsp) coefficients were measured using a TSI Model 3563 three-wavelength integrating nephelometer. From the measurements of σsp and σbsp, it was possible to determine also the scattering Angstrom exponent (αs). For the entire measurement period, the mean values (±standard deviation) at 550 nm are: 80 ± 50 Mm−1 for σsp; 8 ± 5 Mm−1 for σbsp; and 1.6 ± 0.3 for αs. These results indicate a moderate polluted atmosphere characterized by fine particles. The daily variation for all seasons sh…
Colloidal electro-phoresis in the presence of symmetric and asymmetric electro-osmotic flow
2018
We characterize the electro-phoretic motion of charged sphere suspensions in the presence of substantial electro-osmotic flow using a recently introduced small angle super-heterodyne dynamic light scattering instrument (ISASH-LDV). Operation in integral mode gives access to the particle velocity distribution over the complete cell cross-section. Obtained Doppler spectra are evaluated for electro-phoretic mobility, wall electro-osmotic mobility and particle diffusion coefficient. Simultaneous measurements of differing electro-osmotic mobilities leading to asymmetric solvent flow are demonstrated in a custom made electro-kinetic cell fitting standard microscopy slides as exchangeable sidewall…
Miniaturized liquid chromatography coupled on-line to in-tube solid-phase microextraction for characterization of metallic nanoparticles using plasmo…
2018
Abstract This tutorial aims at providing guidelines for analyzing metallic nanoparticles (NPs) and their dispersions by using methods based on miniaturized liquid chromatography with diode array detection (MinLC-DAD) and coupled on-line to in-tube solid-phase microextraction (IT-SPME). Some practical advice and considerations are given for obtaining reliable results. In addition, this work outlines the potential applications that set these methodologies apart from microscopy-related techniques, dynamic light scattering, single particle ICP-MS, capillary electrophoresis, field-flow fractionation and other chromatographic configurations, which are discussed and mainly seek to accomplish size …
Born-Infeld Gravity: Constraints from Light-by-Light Scattering and an Effective Field Theory Perspective
2021
By using a novel technique that establishes a correspondence between general relativity and metric-affine theories based on the Ricci tensor, we are able to set stringent constraints on the free parameter of Born-Infeld gravity from the ones recently obtained for Born-Infeld electrodynamics by using light-by-light scattering data from ATLAS. We also discuss how these gravity theories plus matter fit within an effective field theory framework.
Metal ions modulate thermal aggregation of betalactoglobulin: a join chemical and physical characterization
2014
Abstract Molecular basis of the role played by Cu 2 + and Zn 2 + ions during the thermal aggregation processes of beta-lactoglobulin (BLG) was studied by using a joint application of different techniques. In particular, Raman spectroscopy was very useful in identifying the different effects caused by the two metals at molecular level (i.e. changes in His protonation state, disulfides bridge conformation, and micro-environment of aromatic residues), evidencing the primary importance of the protein charge distribution during the aggregation process. Both metal ions are able to act on this factor and favor the protein aggregation, but Zn 2 + is able to alter the natural conformational state of…