Search results for "Linear"
showing 10 items of 7165 documents
Determination of organic and inorganic mercury species in water and sediment samples by HPLC on-line coupled with ICP-MS.
2009
This paper describes a preconcentration method for Hg(2+) and MeHg(+) in water samples using sodium diethyldithiocarbamate immobilized in polyurethane foam (PU-NaDDC) and an extraction method for several mercury species in sediment samples, including MeHg(+), EtHg(+) and PhHg(+), which is simple, rapid, and uses a single organic solvent. Separation and measurement were done by high-performance liquid chromatography on-line with inductively coupled plasma mass spectrometry (HPLC/ICP-MS). Initially, the test of recovery was applied using procedures compatible with HPLC. Under the optimum extraction conditions, recoveries of 96.7, 96.3 and 97.3% were obtained for MeHg(+), EtHg(+), and PhHg(+),…
A simplified method for estimating the total water vapor content over sea surfaces using NOAA-AVHRR channels 4 and 5
2002
A simplified method for estimating the total amount of atmospheric water vapor, W, over sea surfaces using NOAA-AVHRR Channels 4 and 5 is presented. This study has been carried out using simulated AVHRR data at 11 and 12 /spl mu/m (with MODTRAN 3.5 code and the TIGR database) and AVHRR, PODAAC, and AVISO databases provided by the Louis Pasteur University (Strasbourg-France), NASA-NOAA, and Meteo France, respectively. The method is named linear atmosphere-surface temperature relationship (LASTR). It is based on a linear relationship between the effective atmospheric temperature in AVHRR Channel 4 and sea surface temperature. The LASTR method was compared with the linear split-window relation…
Toward a wave turbulence formulation of statistical nonlinear optics
2012
International audience; During this last decade, several remarkable phenomena inherent to the nonlinear propagation of incoherent optical waves have been reported in the literature. This article is aimed at providing a generalized wave turbulence kinetic formulation of random nonlinear waves governed by the nonlinear Schrodinger equation in the presence of a nonlocal or a noninstantaneous nonlinear response function. Depending on the amount of nonlocal (noninstantaneous) nonlinear interaction and the amount of inhomogeneous (nonstationary) statistics of the incoherent wave, different types of kinetic equations are obtained. In the spatial domain, when the incoherent wave exhibits fluctuatio…
Rapid Evaluation of Oxidized Fatty Acid Concentration in Virgin Olive Oils Using Metal Oxide Semiconductor Sensors and Multiple Linear Regression
2009
This works aims to set up a rapid and nondestructive method to evaluate the advanced oxidation of virgin olive oils (VOOs). An electronic nose based on an array of six metal oxide semiconductor sensors was used, jointly with multiple linear regression (MLR), to predict the oxidized fatty acid (OFA) concentration in VOO samples characterized by different oxidative status. An MLR model constructed using five predictors was able to predict OFA concentration with an average validation error of 9%.
A linear regression-based machine learning pipeline for the discovery of clinically relevant correlates of gait speed reserve from multiple physiolog…
2021
Frailty in older adults is characterized by reduced physiological reserve. Gait speed reserve (GSR: maximum minus usual gait speed) could help identify frailty and act as a proxy for physiological reserve. Utilizing data from 2397 participants aged 50+ from wave 3 of The Irish Longitudinal Study on Ageing, we developed a stepwise linear regression-based machine learning pipeline to select the most important GSR predictors from 34 manually selected features across multiple domains. Variables were selected one at a time such that they maximized the mean adjusted r-squared score from a 5-fold cross-validation. A peak score of (0.16 +/- 0.03) was achieved with 14 variables (giving adjusted-r-sq…
FISCAL READJUSTMENTS IN THE UNITED STATES: A NONLINEAR TIME-SERIES ANALYSIS
2009
We analyze the fiscal adjustment process in the United States using a multivariate threshold vector error regression model. The shift from single-equation to multivariate setting adds value both in terms of our economic understanding of the fiscal adjustment process and the forecasting performance of nonlinear models. We find evidence that fiscal authorities intervene to reduce real per capita deficit only when it reaches a certain threshold and that fiscal adjustment takes place primarily by cutting government expenditure. The results of out-of-sample density forecast and probability forecasts suggest that a shift from a univariate autoregressive model to a multivariate model improves fore…
Threshold cointegration and nonlinear adjustment between goods and services inflation in the United States
2006
In this paper, we model the long-run relationship between goods and services inflation for the United States over the period 1968:1–2003:3. Our empirical methodology makes use of recent developments on threshold cointegration that consider the possibility of a nonlinear relationship between the two inflation series. According to our results, the null hypothesis of linear cointegration would be rejected in favor of a two-regime threshold cointegration model. Consequently, we could expect a cointegrating relationship only when the divergence between services inflation and goods inflation is above the threshold point estimate.
Linus Pauling’s Breakthrough to the Theory of Aromatic Compounds and Hückel’s Reaction
2009
In the mid-1930s Wheland and Pauling set out to find a quantum theoretical basis for Ingold’s general electronic theory of organic reactions. A brief outline of Ingold’s main concepts will provide the necessary background for an evaluation of their contribution and Huckel’s discussion of it.
Magnetic circular and linear dichroism in VUV-photoemission from thin iron films on W(110)
1996
Abstract We report on two different photoemission techniques for ferromagnetic surfaces: the phenomena of magnetic circular and linear dichroism in the angular distribution of photoelectrons MCDAD and MLDAD. MCDAD had already been studied in detail for different systems. Now we are able to compare our MCDAD results from thin iron films on W(110) to new data from magnetic linear dichroism MLDAD. Both effects (MCDAD and MLDAD) have been studied in the identical photon energy region (up to hv = 36 eV). The results will be discussed with respect to a bandstructure calculation.
Nonequilibrium magnetization dynamics of gadolinium studied by magnetic linear dichroism in time-resolved 4f core-level photoemission.
2008
The magnetic linear dichroism of the gadolinium 4f core level is studied in a time-resolved photoemission experiment employing laser pump- and synchrotron-radiation probe pulses. Upon optical excitation of the 5d6s valence electrons with femtosecond laser pulses, the magnetic order in the 4f spin system is reduced. Remarkably, the linear dichroism remains at 80% of the equilibrium contrast while the lattice temperature reaches the Curie temperature due to electron-phonon scattering. Contrasting itinerant ferromagnets, this shows that equilibration between the lattice and spin subsystems takes in Gd about 80 ps and is established in parallel with heat diffusion.