Search results for "Linkers"

showing 4 items of 4 documents

Three‐Component Self‐Assembly Changes its Course: A Leap from Simple Polymers to 3D Networks of Spherical Host–Guest Assemblies

2021

Angewandte Chemie / International edition 60(21), 12132 - 12142 (2021). doi:10.1002/anie.202103178

DiffractionMaterials science010402 general chemistryMass spectrometry01 natural sciencesCatalysisSelf‐AssemblyMetalcoordination networksResearch Articleschemistry.chemical_classification010405 organic chemistrypentaphosphaferroceneflexible linkersGeneral ChemistryNuclear magnetic resonance spectroscopyPolymermetallosupramolecular chemistry5400104 chemical sciencesCrystallographychemistryTransmission electron microscopyvisual_artYield (chemistry)ddc:540visual_art.visual_art_mediumSelf-assemblysupramoleculesResearch Article
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Proteome-wide comparison between the amino acid composition of domains and linkers

2018

Objective Amino acid composition is a sequence feature that has been extensively used to characterize proteomes of many species and protein families. Yet the analysis of amino acid composition of protein domains and the linkers connecting them has received less attention. Here, we perform both a comprehensive full-proteome amino acid composition analysis and a similar analysis focusing on domains and linkers, to uncover domain- or linker-specific differential amino acid usage patterns. Results The amino acid composition in the 38 proteomes studied showcase the greater variability found in archaea and bacteria species compared to eukaryotes. When focusing on domains and linkers, we describe …

Proteomics570BacteriaProteomeAmino acid compositionlcsh:Rlcsh:MedicineEukaryotaArchaea570 Life sciencesResearch Notelcsh:Biology (General)Sequence Analysis ProteinCatalytic DomainDomainsAmino Acid SequenceLinkerslcsh:Science (General)lcsh:QH301-705.5570 Biowissenschaftenlcsh:Q1-390BMC Research Notes
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Solid state halogen bonded networks vs. dynamic assemblies in solution: explaining N⋯X interactions of multivalent building blocks

2015

Tetrapyridine functionalized resorcinarene macrocycles were used as multivalent building blocks for the construction of halogen bonded networks with aryl halide linkers. In the solid state, resorcinarene macrocycles and aryl halide linker molecules assembled into interpenetrated, multidimensional halogen bonded networks with porous structure caused by the 3D block scaffold of the resorcinarenes. 19F NMR spectroscopy proved halogen bond formation also in solution, as either upfield or downfield shifts were observed depending on the bivalent or monovalent halogen bond binding mode. The binding mode in solution was explained by density functional theory computations. peerReviewed

chemistry.chemical_classificationHalogen bondta114ChemistryStereochemistryAryl halideSolid-stateGeneral ChemistryResorcinareneCondensed Matter PhysicsCrystallographyhalogen bonded networksHalogenMoleculeGeneral Materials ScienceDensity functional theoryta116Linkerresorcinarene macrocyclesaryl halide linkers
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Antibody-drug conjugates for lymphoma patients: preclinical and clinical evidences

2022

Antibody-drug conjugates (ADCs) are a recent, revolutionary approach for malignancies treatment, designed to provide superior efficacy and specific targeting of tumor cells, compared to systemic cytotoxic chemotherapy. Their structure combines highly potent anti-cancer drugs (payloads or warheads) and monoclonal antibodies (Abs), specific for a tumor-associated antigen, via a chemical linker. Because the sensitive targeting capabilities of monoclonal Abs allow the direct delivery of cytotoxic payloads to tumor cells, these agents leave healthy cells unharmed, reducing toxicity. Different ADCs have been approved by the US Food and Drug Administration (FDA) and the European Medicines Agency (…

cytotoxic payloadlinkersmonoclonal antibodylymphomaAntibody-drug conjugate
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