Search results for "Liquid interface"
showing 3 items of 13 documents
Analysis of adsorption of phospholipids at the 1,2-dichloroethane/water interface by electrochemical impedance spectroscopy: A study of the effect of…
2007
Abstract The adsorption behaviour of a series of phosphatidylcholines (PCs) with saturated carbon chains of different length (DLPC, DPPC, DSPC, DAPC, and DBPC) at the electrified 1,2-dichloroethane/water interface was studied by measuring electrochemical impedance spectroscopy at the polarized interface. Two different trends in the interfacial capacitance were observed for any of the PCs the capacity dependence on the applied potential: strong adsorption occurs at negative potential with a marked decrease of C ( E ); increase of capacity is observed at positive potentials. It is demonstrated that the interfacial lipid adsorption was dependent on phospholipid concentration, applied potential…
Self-Assembled Molecular Rafts at Liquid|Liquid Interfaces for Four-Electron Oxygen Reduction
2011
The self-assembly of the oppositely charged water-soluble porphyrins, cobalt tetramethylpyridinium porphyrin (CoTMPyP(4+)) and cobalt tetrasulphonatophenyl porphyrin (CoTPPS(4-)), at the interface with an organic solvent to form molecular "rafts", provides an excellent catalyst to perform the interfacial four-electron reduction of oxygen by lipophilic electron donors such as tetrathiafulvalene (TTF). The catalytic activity and selectivity of the self-assembled catalyst toward the four-electron pathway was found to be as good as that of the Pacman type cofacial cobalt porphyrins. The assembly has been characterized by UV-visible spectroscopy, Surface Second Harmonic Generation, and Scanning …
Fabrication of DNA origami lattice on silicon surface for DNA-assisted lithography
2022
Metamaterials obtain new properties from having metallized nanoscale features that are often arranged in repeating patterns. In particular, there is a need to create metasurfaces with a negative refractive index. As nanoscale fabrication using conventional top-down methods can be both difficult and time-consuming, bottom-up techniques have gained growing interest. Especially, the DNA origami method can be utilized to assemble lattices with nanoscale features on 2D surfaces, which can then be metallized using DNA-assisted lithography (DALI). This thesis provides a full study of the DNA origami fishnet lattice assembly kinetics and optimization of lattice order on a silicon surface using liqu…