Search results for "Lithium"
showing 10 items of 680 documents
Characterization of Sn-Co nanowires grown into alumina template
2009
Nanowires of Sn-Co alloys were grown inside the channels of anodic alumina membrane by potentiostatic deposition. The scanning electron microscope images showed the formation of cylindrical nanowires whose height was increasing with deposition time. The X-ray patterns did not show significant diffraction peaks, suggesting the formation of amorphous phases. The higher content of Co in the nanowires, in comparison to the initial composition of the electrolytic bath, was attributed to a higher rate of Co electrodeposition. These nanowires seem to possess specific features suitable for innovative application in the field of Li-ion batteries due to their dimensional stability and high specific s…
Structural and Electric Properties of Sodium Lithium Niobate Ceramic Solid Solution Li0.08Na0.92NbO3
2011
A lead-free solid solution Li0.08Na0.92NbO3 was prepared by a two-stage hot-pressing technology. The structure and morphology of Li0.08Na0.92NbO3 were characterised by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The studies of electric conductivity were performed depending on temperature and frequency of electric measuring field on heating and cooling processes. These measurements revealed that the a.c. conductivity changed with the frequency according to the formula: σ(ω)=σ dc +Aω n where n < 1. These results were discussed considering the conduction mechanism as a type of polaron hopping.
Photoelectric fields in doped lithium niobate crystals
2019
Photoinduced light scattering (PILS) in nominally pure stoichiometric and congruent lithium niobate single crystals (LiNbO3), and ones doped with B³⁺, Cu²⁺, Zn²⁺, Mg²⁺, Gd³⁺, Y³⁺, Er³⁺ cations was studied. All crystals have a relatively low effect of photorefraction and are promising materials for frequency conversion, electro-optical modulators and shutters. It was found that the photovoltaic and diffusion fields for some crystals have a maximum at a wavelength of 514.5 nm. All the crystals studied are characterized by a maximum of the integral intensity of the speckle structure of the PILS at a wavelength of 514.5 nm.
Parametric conversion in micrometer and sub-micrometer structured ferroelectric crystals by surface poling
2012
We report on recent technological improvements concerning nonlinear patterning of lithium niobate and lithium tantalate in the micrometer and submicrometer scales using surface periodic poling for ferroelectric domain inversion. The fabricated samples were employed for frequency doubling via quasiphase-matching both in bulk and guided wave geometries, including forward and backward configurations and wavelength conversion in bands C and L. We also investigated short-period quasiperiodic samples with randomly distributed mark-to-space ratios.
Solid polymer electrolytes from a fluorinated copolymer bearing cyclic carbonate pendant groups
2018
International audience; A poly(vinylidene fluoride-co-(2-oxo-1,3-dioxolan-4-yl)methyl 2-(trifluoromethyl)acrylate) random copolymer, poly(VDF-co-MAF-cyCB), with a MAF-cyCB weight fraction of 59% was synthesized via free radical copolymerization of VDF and MAF-cyCB, which is a methacrylate bearing cyclocarbonate side-chain. This copolymer showed nano-structured morphology, where crystalline PVDF-rich domains co-existed with amorphous poly(VDF-co-MAF-cyCB) segments. Solid polymer electrolytes were further obtained by loading the poly(VDF-co-MAF-cyCB) copolymer with various amounts of LiClO4. The added lithium salt was dissolved in the poly(VDF-co-MAF-cyCB) amorphous phase, which allowed the f…
SnCo nanowire array as negative electrode for lithium-ion batteries
2011
Abstract Amorphous SnCo alloy nanowires (NWs) grown inside the channels of polycarbonate membranes by potentiostatic codeposition of the two metals (SnCo- PM ) were tested vs. Li by repeated galvanostatic cycles in ethylene carbonate-dimethylcarbonate – LiPF 6 for use as negative electrode in lithium ion batteries. These SnCo electrodes delivered an almost constant capacity value, near to the theoretical for an atomic ratio Li/Sn of 4.4 over more than 35 lithiation–delithiation cycles at 1 C. SEM images of fresh and cycled electrodes showed that nanowires remain partially intact after repeated lithiation–delithiation cycles; indeed, several wires expanded and became porous. Results of amorp…
Room-Temperature Micropillar Growth of Lithium-Titanate-Carbon Composite Structures by Self-Biased Direct Current Magnetron Sputtering for Lithium Io…
2019
Here, an unidentified type of micropillar growth is described at room temperature during conventional direct-current magnetron sputtering (DC-MS) deposition from a Li4Ti5O12+graphite sputter target under negative substrate bias and high operating pressure. These fabricated carbon-Li2O-TiO2 microstructures consisting of various Li4Ti5O12/Li2TiO3/LixTiO2 crystalline phases are demonstrated as an anode material in Li-ion microbatteries. The described micropillar fabrication method is a low-cost, substrate independent, single-step, room-temperature vacuum process utilizing a mature industrial complementary metal-oxide-semiconductor (CMOS)-compatible technology. Furthermore, tentative considerat…
Scanning near-field optical microscopy (SNOM) of lithium niobate aperiodically poled during growth
2007
In the present work, aperiodically poled lithium niobate (APPLN) was grown, along the a-axis, by the off-centred Czochraski method. The domain formation has been triggered by rare earth doping, using in this case Er3+ and Yb3+ ions. The growth conditions were selected in order to obtain a modulated domain distribution. SNOM measurements have been performed with a Nanonics Imaging Ltd model MultiView 200 TM working in non-contact tapping mode.
Continuous-wave, double-pass second-harmonic generation with 60% efficiency in a single MgO:PPSLT crystal
2014
We present a double-pass scheme for high-efficiency, high-power, second-harmonic generation (SHG) in a single MgO-doped periodically poled stoichiometric lithium tantalate (MgO:PPSLT) crystal. The device is pumped by a single-frequency, continuous-wave fiber amplifier laser system at a wavelength of 1091 nm. For the double-pass scheme, a conversion efficiency of 60% and a harmonic power of 12.8 W at a wavelength of 545.5 nm with a high beam quality of (M2<1.2) is achieved. Compared to single-pass SHG, a double-pass enhancement factor of more than two is observed at the highest fundamental pump power.
Raman Studies of Photorefractive Lithium Niobate Single Crystals
2014
A study of Raman spectra of lithium niobate single crystals: stoichiometric, ostensibly pure congruent LiNbO3, and congruent LiNbO3 containing admixture of yttrium is reported. Raman bands observed in spectra excited by visible laser radiation are thoroughly compared to the same bands excited by infrared laser radiation. The broadening of Raman bands excited by radiation of shorter wavelengths is attributed to photo-refraction induced by visible radiation (514 nm) while being absent under infrared radiation (1064 nm). Attributing the effect of photo-refraction to radiation-induced structural changes in the illuminated part of the crystal lattice the authors interpret the observed broadening…