Search results for "Lithium"
showing 10 items of 680 documents
Synthesis and Structural Characterization of (1,4-Dihydropyrid-1-yl)aluminum Complexes
1999
The reaction between LiAlH(4) and pyridine, 4-methylpyridine, or 3,5-dimethylpyridine results in hydride transfer to the pyridine ring to give tetrakis(pyridine)lithium tetrakis(1,4-dihydropyrid-1-yl)aluminate(III), 1, tetrakis(4-methylpyridine)lithium tetrakis(1,4-dihydro-4-methylpyrid-1-yl)aluminate(III), 2, or tetrakis(3,5-dimethylpyridine)lithium tetrakis(3,5-dimethyl-1,4-dihydropyrid-1-yl)aluminate(III), 3, respectively. We claim that 1, instead of lithium tetrakis(1,4-dihydropyrid-1-yl)aluminate(III), is the compound which is known as Lansbury's reagent. Treatment of trimethylamine-alane, AlH(3).NMe(3), with pyridine yields tris(1,4-dihydropyrid-1-yl)(pyridine)aluminum, 4. It could be…
A comparative evaluation of shear bond strength between feldspathic porcelain and lithium di silicate ceramic layered to a zirconia core? An in vitro…
2020
Background The bond strength between the zirconia core and ceramic veneer is the weakest component in the layered structure. Delamination of veneering ceramic is reported as one of the most frequent problems associated with Veneered Zirconia restorations. The aim of this study is to compare the shear bond strength of lithium di silicate porcelain to that of feldspathic porcelain on a zirconia Substrate. Material and Methods Two groups (group A and B) of zirconia blocks with each group having 20 samples were fabricated according to Schmitz Schulmeyer method. Group A (n =20 ) samples were veneered with feldspathic veneering porcelain and Group B (n=20) samples were veneered with heat pressed …
Low-Frequency Relaxation Phenomena in α-LiIO3: The Nature and Role of Defects
2002
The lithium iodate ionic conduction in the polar c-axis direction is studied between 35 and 470 K for crystals grown in various conditions. So far, to separate processes induced by the nature of electrodes, the impedance spectroscopy technique had been used at room temperature with both metallic and ideally polarizable insulating electrodes, so that a relaxation of space charges was clearly identified. Here, the temperature dependence of the hopping ionic conductivity exhibits quite different activation energies well related to the growth conditions. Following low-temperature Raman and thermodynamic experiments, a new approach based on a vacancy diffusion mechanism is proposed. Experimental…
Techno-Economic Case Study of Micro-Grid System at Soccer Club of Skagerak Arena Norway
2020
The photovoltaic system and battery energy storage can be used in a microgrid system for reducing peak demand from the grid and it enhances overall techno-economic performance of the system. In this work, a functioning micro-grid of 800 kWp photovoltaic system and 1 MWh lithium ion battery, located at Soccer Club of Skagrek Arena (Norway), is used for techno-economic analysis and operational load from years 2015 to 2018. The system performance has been analyzed for understanding the techno-economic operation, and contributions from the PV and battery energy storage for reducing peak demand from the grid. In this study, it has been observed that the integration of PV and battery energy stora…
The design of the DONES lithium target system
2019
Abstract In the framework of the EU fusion roadmap implementing activities, an accelerator-based Li(d,xn) neutron source called DONES (Demo-Oriented early NEutron Source) is being designed within the EUROfusion Work Package Early Neutron Source as an essential irradiation facility for testing candidate materials for DEMO reactor and future fusion power plants. DONES will employ a high speed liquid lithium jet struck by a 125 mA, 40 MeV deuteron beam to generate the intense neutron flux used to irradiate the material samples up to the desired level of displacement damage (˜10 dpa/fpy for iron in 0.3 l) and He production rates (˜10-13 appm He/dpa). In order to rapidly achieve a sound and stab…
Parametric study of the influence of First Wall cooling water on the Water Cooled Lithium Lead Breeding Blanket nuclear response
2019
Abstract In the framework of EUROfusion Work Package International Cooperation R&D activities, a close collaboration has been started among University of Palermo, ENEA Brasimone and ENEA Frascati for the development of the Water Cooled Lithium Lead (WCLL) Breeding Blanket (BB) concept. In this context, a research campaign has been carried out at the University of Palermo in order to investigate the influence of First Wall (FW) cooling water configuration on the nuclear response of the WCLL BB under irradiation in EU-DEMO, in order to gain useful indications for the WCLL BB pre-conceptual designs. To this end, three-dimensional nuclear analyses have been performed by MCNP5 v. 1.6 Monte Carlo…
Element variability in the coralline alga Lithophyllum yemenense as archive of past climate in the Gulf of Aden (NW Indian Ocean)
2017
This study presents the first algal thallus (skeleton) archive of Asian monsoon strength and Red Sea influence in the Gulf of Aden. Mg/Ca, Li/Ca, and Ba/Ca were measured in Lithophyllum yemenense from Balhaf (Gulf of Aden) using laser ablation inductively coupled plasma mass spectrometry, and Mg/Ca ratio oscillation was used to reconstruct the chronology (34 y). Oscillations of element rates corresponding to the algal growth between 1974 and 2008 were compared with recorded climate and oceanographic variability. During this period, sea surface temperatures (SST) in Balhaf recorded a warming trend of 0.55 degrees C, corresponding to an increase in Mg and Li content in the algal thallus of 2.…
Synthesis of bis(diphenylphosphinocyclopentadienyl) yttrium chloride complexes and heterodimetallic derivatives. X-ray structure of bis[(μ-chloro)bis…
1996
Abstract Reaction of lithium diphenylphosphinocyclopentadienide with YCl 3 or YCl 3 (THF) 3 and working lead to the formation of three yttrocene phosphines: the lithium metal adduct isolated as (Ph 2 PC 5 H 4 ) 2 Y(μ-Cl) 2 Li(THF) 2 · 0.5 LiCl ( 1 ), the chloride-bridged dimeric species {(Ph 2 PC 5 H 4 ) 2 Y(μ-Cl)} 2 ( 2 ), and the coordinated monometal species [(Ph 2 PC 5 H 4 ) 2 YCl(THF)] ( 3 ). The X-ray structure of 2 is remarkable in that the crystal exhibits two independent chloride-bridged dimers that differ in the arrangement ( syn, anti ) of the diphenylphosphino groups. Chelation of phosphorus atoms to a molydenum carbonyl moiety is also reported.
A doubly bridged isodicyclopentadienyl zirconium complex: bis{N-(3,5-dimethylphenyl)-N-[(η5-isodicyclopentadien-2-yl)dimethylsilyl]amido-κN}zirconium…
2002
Transmetallation of the dilithium salt of (3,5-dimethyphenylamino)(isodicyclopentadienyl)dimethylsilane by treatment with zirconium tetrachloride in a 2:1 ratio leads to the substitution of all four chloride ligands. With the applied stoichiometry, the title complex, [Zr(C(20)H(25)NSi)(2)].C(4)H(10)O, was obtained and crystallized from diethyl ether. X-ray diffraction characterization showed that both isodicyclopentadienyl ligands (alternatively called 4,5,6,7-tetrahydro-4,7-methano-1H-indene) are complexed to the metal on their exo face in a completely stereoselective manner and that they are eta(5)-bonded to the Zr atom.
Zirconium, hafnium and yttrium complexes containing two linked amido— tetramethylcyclopentadienyl ligands: Synthesis, reactivity and molecular struct…
1998
Abstract Zirconium and hafnium complexes M(η5: η1−C5Me4SiMe2NR′)xCl(4−2x) (M = Zr, Hf; x = 1, 2; R′ = iPr, tBu) containing one or two linked amido-tetramethylcyclopentadienyl ligands C5Me4SiMe2NR′ have been synthesized by the reaction of the dilithium derivative Li2(C5Me4SiMe2NR′) with MCl4(THF)2. The crystal structure of the hafnium complex Hf(η5: η1−C5Me4SiMe2NiPr)2 has been determined by a single-crystal X-ray diffraction study and shows a C2-symmetric helical metallocene, in which the amido ligands are bonded as π-donor ligands with Hf—N bond lengths of 2.115(2) A. The isoelectronic heterobimetallic yttrium complex Li[Y(η5: η1−C5Me4SiMe2NCH2CH2OMe)2] reacts with phenylacetylene to give …