Search results for "MASS SPECTROMETRY"
showing 10 items of 2544 documents
Mass spectrometric studies on pyridine-piperazine-containing ligands and their complexes with transition metals formed in solution.
2001
Electrospray ionization (ESI) and matrix-assisted laser desorption/ionization (MALDI) methods were used to study open-chain piperazine-containing ligands (L) and their complexes formed with transition-metal salts. ESI and MALDI measurements were performed with a Fourier transform ion cyclotron resonance (FT-ICR) and a time-of-flight (TOF) mass spectrometer, respectively. Only singly charged complexes, between one ligand and one or several metal ions, were formed in the ESI measurements. Because the net charge was always one, one or several counterions were attached to the complex. Under ESI conditions, the complexes formed between the ligands and metal (Co, Ni, Cu, and Cd) salts were [L + M…
<title>Compact multi-functional skin spectrometry set-up</title>
2006
A portable fibre-optic spectrometry set-up has been assembled and tested for applications in skin diffuse reflectance spectrometry, laser fluorescence spectrometry and multi-wavelength reflection photoplethysmography (multi-PPG) studies. The spectrometry set was tested by diffuse reflectance and fluorescence measurements for diagnostics of skin vascular malformations and pigmented diseases such as nevi and melanoma . In addition, studies of microcirculation in blood vessels located at different depths from the skin surface were performed by the multi-PPG method. The results of skin diffuse reflectance and autofluorescence showed differences in spectra of healthy and pathologic skin. The par…
Uncertainties on the determination of the strong coupling αs from the energy evolution of jet fragmentation functions at low z
2014
The QCD coupling alpha_s is determined at NLO*+NMLLA accuracy from the comparison of experimental jet data to theoretical predictions of the energy-evolution of the parton-to-hadron fragmentation function moments (multiplicity, peak, width, skewness) at low fractional hadron momentum z. From the existing e+e- and e-p jet data, we obtain alpha_s(m_Z^2) = 0.1195 +/- 0.0021 (exp.) {+0.0015}_{-0.0} (scale) at the Z mass. The uncertainties of the extracted alpha_s value are discussed.
Occurrence of pharmaceuticals in municipal wastewater treatment plants and receiving surface waters in Central and Southern Finland
2016
The presence of five selected pharmaceuticals, four anti-inflammatory drugs, diclofenac, ibuprofen, ketoprofen, naproxen, and an antiepileptic drug carbamazepine, was determined at four municipal wastewater treatment plants (WWTPs) and in the receiving waterway near the city of Jyväskylä, in central Finland and also in the River Vantaa. First, an analytical method was developed including a pretreatment and purification followed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) in the multiple reaction monitoring mode. The studied pharmaceuticals were detected from influents and effluents of four municipal WWTPs and from surface water of eight locations along the water …
Mass Spectroscopy in Penning Trap
2009
While mass spectrometry in Paul traps serves well mainly for molecular analysis in chemistry, Penning traps provide high accuracy and precision. The technique is based on the fact that the ratio of cyclotron frequencies ω c = (Q/M)B of two ions in the same magnetic field B gives directly the ratio of their masses ω c(1)/ω c(2) = M(2)/M(1). If carbon-12 as the standard of the atomic mass scale is used as reference, the mass of the ion of interest is obtained directly in atomic units. Although the cyclotron frequency is not an eigenfrequency of the Penning trap, it can be obtained from combinations of ω+, ω, and ω z as evident from the set of equations (1.31)-(1.33). In the ideal case of a pe…
Influence of Biomass Combustion Products on Element Content and Thermal Stability of Latvian Sheep Breed Wool Filter Fibres
2020
Sheep wool is natural, easy obtainable, renewable and biodegradable material with a perspective application as a sorbent in filters for purification of industrial emissions from various environmental pollutants. The element content and thermal stability of Latvian dark-headed sheep wool filter fibres was analysed and described before and after exposure to biomass combustion products. Based on the obtained results, it is concluded that the sheep wool filter fibres can sorb various gaseous combustion products, such as carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx), however, the sorption processes of these gases are irreversible. The obtained results of total reflection X…
The Influence of Chemical Composition of Commercial Lemon Essential Oils on the Growth of Candida Strains
2013
Candida yeasts are saprophytes naturally present in the environment and forming colonies on human mucous membranes and skin. They are opportunistic fungi that cause severe and even fatal infections in immunocompromised individuals. Several essential oils, including eucalyptus, pine, cinnamon and lemon, have been shown to be effective against Candida strains. This study addresses the chemical composition of some commercial lemon essential oils and their antifungal potential against selected Candida yeast strains. Antifungal potential and minimum inhibitory concentrations were determined for six commercial lemon essential oils against five Candida yeast strains (Candida albicans 31, Candida t…
Temperature effects explain continental scale distribution of cyanobacterial toxins
2018
Insight into how environmental change determines the production and distribution of cyanobacterial toxins is necessary for risk assessment. Management guidelines currently focus on hepatotoxins (microcystins). Increasing attention is given to other classes, such as neurotoxins (e.g., anatoxin-a) and cytotoxins (e.g., cylindrospermopsin) due to their potency. Most studies examine the relationship between individual toxin variants and environmental factors, such as nutrients, temperature and light. In summer 2015, we collected samples across Europe to investigate the effect of nutrient and temperature gradients on the variability of toxin production at a continental scale. Direct and indirect…
Availability of extractives from various Norway spruce (Picea abies) stumps assortments
2022
Stumps and knotwood of Norway spruce (Picea abies) are valuable sources of wood extractives. Although lignans from knotwood have already been utilized in value-added products, the behavior and valorization of stump-derived extractives are less studied. In this study, the composition of lipophilic and hydrophilic extractives, particularly lignans, from various spruce stump samples (stump bottom, stump heart, and crushed stump samples) stored outside were studied. Lipophilic and hydrophilic extracts were separated with an accelerated solvent extraction (ASE) apparatus using n-hexane and hot water, respectively. The detailed extractives content of samples was then determined by gas chromatogra…
A multiresidue analytical method for trace level determination of antibiotics and antiretroviral drugs in wastewater and surface water using SPE-LC-M…
2016
An analytical method for simultaneous determination of seven commonly used antibiotics and three antiretrovirals in surface water and urban wastewater at the ng L−1 level has been developed. The method involves concentration and clean-up by solid phase extraction (SPE) followed by identification and quantification by liquid chromatography tandem mass spectrometry (LC-ESI-MS/MS). The use of matrix-matched calibration curves constructed by spiking surface water was evaluated for quantification and compared with the internal standard method using isotopically labelled compounds. The method gave absolute recoveries of 41–116% with most of the compounds having recoveries >50%. The LOQs ranged fr…