Search results for "MATERIA"
showing 10 items of 33501 documents
2D Hydro-Mechanical-Chemical Modeling of (De)hydration Reactions in Deforming Heterogeneous Rock: The Periclase-Brucite Model Reaction
2020
Deformation at tectonic plate boundaries involves coupling between rock deformation, fluid flow, and metamorphic reactions, but quantifying this coupling is still elusive. We present a new two-dimensional hydro-mechanical-chemical numerical model and investigate the coupling between heterogeneous rock deformation and metamorphic (de)hydration reactions. We consider linear viscous compressible and power-law viscous shear deformation. Fluid flow follows Darcy's law with a Kozeny-Carman type permeability. We consider a closed isothermal system and the reversible (de)hydration reaction: periclase and water yields brucite. Fluid pressure within a circular or elliptical inclusion is initially bel…
High‐resolution stimulated Raman spectroscopy and analysis of line positions and assignments for the ν 2 and ν 3 bands of 13 C 2 H 4
2016
High-resolution stimulated Raman spectra of13C2H4 in the regions of the ν2 and ν3 Raman active modes have been recorded at two temperatures (145 and 296 K) based on the quasi continuous-wave (cw) stimulated Raman spectrometer at Instituto de Estructura de la Materia IEM-CSIC in Madrid. A tensorial formalism adapted to X2Y4 planar asymmetric tops with D2h symmetry (developed in Dijon) and a program suite called D2hTDS (now part of the XTDS/SPVIEW spectroscopic software) were proposed to analyze and calculate the high-resolution spectra. A total of 103 and 51 lines corresponding to ν2 and ν3 Raman active modes have been assigned and fitted in wavenumber with a global root mean square deviatio…
Intermediate-depth earthquake generation and shear zone formation caused by grain size reduction and shear heating
2015
cited By 23; The underlying physics of intermediate-depth earthquakes have been an enigmatic topic; several studies support either thermal runaway or dehydration reactions as viable mechanisms for their generation. Here we present fully coupled thermomechanical models that investigate the impact of grain size evolution and energy feedbacks on shear zone and pseudotachylite formation. Our results indicate that grain size reduction weakens the rock prior to thermal runaway and significantly decreases the critical stress needed for thermal runaway, making it more likely to result in intermediate-depth earthquakes at shallower depths. Furthermore, grain size is reduced in and around the shear z…
Shear zone junctions: Of zippers and freeways
2017
Abstract Ductile shear zones are commonly treated as straight high-strain domains with uniform shear sense and characteristic curved foliation trails, bounded by non-deforming wall rock. Many shear zones, however, are branched, and if movement on such branches is contemporaneous, the resulting shape can be complicated and lead to unusual shear sense arrangement and foliation geometries in the wall rock. For Y-shaped shear zone triple junctions with three joining branches and transport direction at a high angle to the branchline, only eight basic types of junction are thought to be stable and to produce significant displacement. The simplest type, called freeway junctions, have similar shear…
Modelling of stylolite geometries and stress scaling
2012
International audience; In this contribution we present numerical simulations of stylolite growth to decipher the effects of initial rock heterogeneity and stress on their morphology. We show that stylolite growth in a rock with a uniform grain size produces different patterns than stylolite growth in a rock with a bimodal grain size distribution. Strong pinning of large heterogeneities produce stylolite structures that are dominated by pronounced teeth, whereas a uniform grain size leads to spikes and a roughness that shows variable wavelengths. We compare the simulated stylolites with natural examples and show that the model can reproduce the real structures. In addition we show that stro…
Textural-chemical changes and deformation conditions registered by phyllosilicates in a fault zone (Pic de Port Vieux thrust, Pyrenees)
2017
International audience; Synkinematic phyllosilicates in fault zones can be used to deduce the deformation mechanisms and the conditions of fault activity, as their chemical composition, crystal structure and texture can record the different stages of deformation and fluid-rock interactions. The Pic de Port Vieux, a second-order thrust related to the major Gavarnie thrust in the southern central part of the Pyrenees Axial Zone, juxtaposes Triassic pelites of the hanging wall and Cretaceous limestones of the footwall. In order to investigate the mineralogical and geochemical changes and constrain the deformation conditions of thrusting, characterization of phyllosilicates was performed along …
Simulation of nitrous oxide emissions from wheat-cropped soils using CERES
2005
Estimation of nitrous oxide (N2O) emissions from arable soils, in relation to crop fertilization, is essential to devise strategies to mitigate the impact of agriculture on global warming. This paper presents the development and test of a N2O model resulting from the linkage of a dynamic soil-crop simulation model (CERES) with two sub-models of N2O production and reduction in soils. These sub-models (NOE and NGAS) account for both the nitrification and denitrification pathways. The resulting models (CERES–NOE and CERES–NGAS) were tested against experimental data collected on three contrasting wheat-cropped soils representative of the Beauce agricultural region in France. Although the input …
The Chevroches zodiacal cap and its Burgundy relations
2009
AbstractThe excavation of an unexplored secondary agglomeration in Chevroches (France), from 2001 to 2002 has led to the discovery of a bronze dome of a type unknown in the Ancient world. It is inscribed with three lines in Greek transcribing Egyptian and Roman months, and the twelve signs of the Zodiac. This paper presents the first observations and some other finds from similar objects in Burgundy.
Characterization of a Newly Developed Aircraft-Based Laser Ablation Aerosol Mass Spectrometer (ALABAMA) and First Field Deployment in Urban Pollution…
2011
We present here the development and first field deployment of a novel Aircraft-based Laser ABlation Aerosol MAss spectrometer (ALABAMA), which is capable of measuring the chemical composition and size of individual ambient aerosol particles in the size range between 150 and 900 nm. The instrument uses a continuous wave 532 nm laser to size and detect the particles, a pulsed 266 nm laser to ablate and ionize the particles, and a bipolar, Z-shaped time-of-flight mass spectrometer to detect positive and negative ions. The ALABAMA fits into a 19"-aircraft rack of 150 cm height and has a total weight of 140 kg, thus currently being one of the smallest and lightest-weight instruments of its type.…
Phase equilibrium constraints on pre-eruptive conditions of recent felsic explosive volcanism at Pantelleria Island, Italy.
2010
International audience; We present experimental phase equilibria carried out on a pantelleritic bulk-rock composition with a peralkalinity index [PI = molar (Na2O + K2O)/Al2O3] = 1*4, which is representative of the most energetic pumice fall eruption of the resurgent post-caldera volcanism on Pantelleria island. For the explored conditions (P = 25-150 MPa; T = 680-800°C; H2Omelt up to 6 wt %; fO2 ≤ NNO, where NNO is nickel-nickel oxide buffer) clinopyroxene is the liquidus phase followed by alkali feldspar and then quartz. The crystallization of amphibole is limited to temperatures below 700°C. Aenigmatite crystallizes near the liquidus for P ≥ 100 MPa. When clinopyroxene is the sole liquid…