Search results for "MATTER"

NMR and $\mu^{+}$SR detection of unconventional spin dynamics in Er(trensal) and Dy(trensal) molecular magnets

2019

Measurements of proton nuclear magnetic resonance (H1NMR) spectra and relaxation and of muon spin relaxation (μ+SR) have been performed as a function of temperature and external magnetic field on two isostructural lanthanide complexes, Er(trensal) and Dy(trensal) [where H3trensal=2,2′,2′′-tris-(salicylideneimino)triethylamine], featuring crystallographically imposed trigonal symmetry. Both the nuclear 1/T1 and muon λ longitudinal relaxation rates (LRRs) exhibit a peak for temperatures T < 30 K, associated to the slowing down of the spin dynamics, and the width of the NMR absorption spectra starts to increase significantly at T ∼50 K, a temperature sizably higher than the one of the LRR p…

Luminescence properties of neodymium-doped yttrium aluminium garnet obtained by the co-precipitation method combined with the mechanical process

2005

Nanopowders of yttrium aluminium garnet Y3Al5O12 (YAG) doped with neodymium ions were obtained by the co-precipitation method from the reaction of aluminium and yttrium nitrate and neodymium oxide with ammonia. After washing and drying the hydroxide precursors were calcined at 500, 700, 800 and 900 °C for 1 hour and at 1000 °C for 3 hours. This product was treated by ball milling in a zirconia vial for 0.5, 1.5 and 10 h in order to achieve smaller nanoparticles. The structure, microstructure, morphology and optical properties were investigated by means of diffractometric, microscopic and spectroscopic techniques. The course of the amorphous-to-crystalline transformation was complete after c…

Preparation of Nd:YAG Nanopowder in a Confined Environment

2007

Nanopowder of yttrium aluminum garnet (YAG, Y3Al5O12) doped with neodymium ions (Nd:YAG) was prepared in the water/cetyltrimethylammonium bromide/1-butanol/n-heptane system. Aluminum, yttrium, and neodymium nitrates were used as starting materials, and ammonia was used as a precipitating agent. Coprecipitate hydroxide precursors where thermally treated at 900 degrees C to achieve the garnet phase. The starting system with and without reactants was characterized by means of the small-angle neutron scattering technique. The system, without reactants, is constituted by a bicontinuous structure laying near the borderline with the lamellar phase region. The introduction of nitrates stabilizes th…

Conduction properties of semiconductive multiwalled carbon nanotubes

2022

AbstractWe have undertaken low-temperature conduction measurements on arc-discharge synthesized, semiconducting multiwalled carbon nanotubes (MWNT). The diameters of these are in the range 2.5–10 nm, corresponding to the sizes just above single-walled carbon nanotubes (SWNT), up to middle-sized MWNTs. The energy gap, inversely related to the diameter, varies strongly in this range, and consequently there is a strong dependence of the transport on tube diameter. Certain transport characteristics are much alike those found in SWNTs, such as the ON-state resistance and Coulomb blockade. However, the transport gap has a more complex behavior than the corresponding one in semiconducting SWNTs, a…

Strong field phenomena: Atoms, Molecules, Nanostructures.

Controllable morphology of flux avalanches in microstructured superconductors

2014

The morphology of abrupt bursts of magnetic flux into superconducting films with engineered periodic pinning centers (antidots) has been investigated. Guided flux avalanches of thermomagnetic origin develop a tree-like structure, with the main trunk perpendicular to the borders of the sample, while secondary branches follow well-defi ned directions determined by the geometrical details of the underlying periodic pinning landscape. Strikingly, we demonstrate that in a superconductor with relatively weak random pinning, the morphology of such flux avalanches can be fully controlled by proper combinations of lattice symmetry and antidot geometry. Moreover, the resulting flux patterns can be re…

Pb-PbOHCl Composite Nanowires Synthesized by Galvanic Deposition in Template

2019

In this paper, we report a detailed study on the synthesis of composite nanowires of Pb-PbOHCl via galvanic deposition into the pores of a membrane acting as a template. PbOHCl deposition quantitatively occurs as the solution pH exceeds the value of about 4.12. Simultaneously, owing to the galvanic coupling, electro-deposition of lead occurs, so composite nanowires were formed. The role of different parameters controlling the kinetic evolution of the process, such as oxygen bubbling, solution pH, surface area and type of sacrificial anode were investigated one at a time. The results suggest that every modification accelerating the alkalization of the solution inside the template pores favor…

Intrinsic spin-orbit interaction in diffusive normal wire Josephson weak links: Supercurrent and density of states

2016

We study the effect of the intrinsic (Rashba or Dresselhaus) spin-orbit interaction in superconductor–nanowire–superconductor (SNS) weak links in the presence of a spin-splitting field that can result either from an intrinsic exchange field or the Zeeman effect of an applied field. We solve the full nonlinear Usadel equations numerically [The code used for calculating the results in this paper is available in https://github.com/wompo/Usadel-for-nanowires] and analyze the resulting supercurrent through the weak link and the behavior of the density of states in the center of the wire. We point out how the presence of the spin-orbit interaction gives rise to a long-range spin triplet supercurr…

Optical Properties of III-V Nanowires and Their Application for Charge Transport and Single-Photon Emission

2012

This work covers the optical characterization of III-V semiconductor nanowires and their application for charge transport and for single-photon emission. InAs nanowires have been investigated by Raman scattering and PL spectroscopy. The possibility to grow nanowires with a crystal structure different from its bulk counterpart has aroused a lot of interest in their optical and electronic properties. Here, the optical phonon modes of wurtzite InAs nanowires have been studied by polarized Raman scattering. For the first time, Raman measurements on a single InAs nanowire have revealed the A1(TO) and E2h optical phonon modes of the wurtzite structure. Additional resonant Raman scattering experim…

Blends of Semiflexible Polymers: Interplay of Nematic Order and Phase Separation

2021

Mixtures of semiflexible polymers with a mismatch in either their persistence lengths or their contour lengths are studied by Density Functional Theory and Molecular Dynamics simulation. Considering lyotropic solutions under good solvent conditions, the mole fraction and pressure is systematically varied for several cases of bending stiffness κ (the normalized persistence length) and chain length N. For binary mixtures with different chain length (i.e., NA=16, NB=32 or 64) but the same stiffness, isotropic-nematic phase coexistence is studied. For mixtures with the same chain length (N=32) and large stiffness disparity (κB/κA=4.9 to 8), both isotropic-nematic and nematic-nematic unmixing oc…