Search results for "MBL"

A crucial role of adamantanoid Cu(II) complexes in the redox systems: CuCl–diallylsulfoxide–O2 and CuCl2–diallylsulfide–O2

2014

Abstract The hypothetically reversible [Cu(I)(diallylsulfoxide)] ↔ O 2 [Cu(II)(diallylsulfide)] system was examined by FTIR spectroscopy and X-ray diffraction. It is stated that the Cu4OCl6 body centered adamantanoid cages, appearing at both the substrate and product sites, act as a template to promote the oxidation of diallylsulfide to diallylsulfoxide or Cu(I) to Cu(II), thus making the reaction irreversible. Each of these two adamantanoid cores possesses a different point symmetry as well as self assembly mode to form two polymorphs of the [Cu4OCl6(diallylsulfoxide)4] complex. Their polymorphic relationships based on the symmetry homology S4 ← Td → C3, as well as the distortion in the Cu…

The EU’s online gambling regulatory approach and the crisis of legal modernity

2014

ONLINE GAMBLING CONTRACTS AS NEW FRONTIERS OF INTERNATIONAL CONSUMER TRANSACTIONS

2016

Entanglement dynamics and relaxation in a few-qubit system interacting with random collisions

2008

The dynamics of a single qubit interacting by a sequence of pairwise collisions with an environment consisting of just two more qubits is analyzed. Each collision is modeled in terms of a random unitary operator with a uniform probability distribution described by the uniform Haar measure. We show that the purity of the system qubit as well as the bipartite and the tripartite entanglement reach time averaged equilibrium values characterized by large instantaneous fluctuations.These equilibrium values are independent of the order of collision among the qubits. The relaxation to equilibrium is analyzed also in terms of an ensemble average of random collision histories. Such average allows for…

Mechanical and electroconductive properties of spatially distributed double stranded DNA arrays on Au (111)

2008

Abstract Conductive AFM was used to investigate electroconductivity through 10 nm long double stranded DNA molecules in mixed monolayers of thioalkylated-DNA and mercaptohexanol (MCH) on Au (111) surface. The distribution of DNA molecules on the surface was analyzed by tapping mode AFM. Measurements performed in lift mode confirmed that the DNA molecules protrude from the surface rather than lie horizontally adsorbed on the interface. The optimal conductivity measurement time, which is shorter than the mechanical relaxation time of oligonucleotide duplexes, was determined. It was concluded that oligonucleotide duplexes have a resistance of the order of ~ 2 Ω ⁎ m at 1 V.

Self — Assembled System: Semiconductor and Virus Like Particles

2008

Virus like nanoparticles (VLP) are in use to be absorbed by cells to cause biological effects. To increase a local concentration of VLP, nanoparticles-carriers bringing the latter to the target cell could be employed. N-type and p-type Si semiconductor nanoparticles, to control adhesion of VLP were applied. Optical absorbance spectra and electron microscopy evidenced that VLP became connected to Si nanoparticles. Moreover, a density of the adhered VLP depended on the type of both semiconductor and VLP.

Self-Assembled System of Semiconductor and Virus Like Nanoparticles

2009

Virus like nanoparticles (VLP) are in use to be absorbed by cells to cause biological effects. To increase a local concentration of VLP, nanoparticles-carriers bringing the latter to the target cell could be employed. N-type and p-type Si semiconductor nanoparticles, to control adhesion of VLP were applied. Optical absorbance spectra and electron microscopy evidenced that VLP became connected to Si nanoparticles. Moreover, a density of the adhered VLP depended on the type of both semiconductor and VLP.

On chip optical nanotweezing for dielectric particles manipulation

2014

On chips optical nanocavities have become useful tools for trapping and manipulation of colloidal objects. In this thesis we study the nanocavities as building blocks for optical forces, trapping and handling of particles. Proof of concept of trapping dielectric microspheres appears as the starting point of the development of lab on chip. In the first chapter we go through the literature of optical forces in free space and integrated optics. The second chapter presents the experimental tools for the characterization of nanocavities and the set-up developed to perform optical measurements with the colloidal particles. The third chapter describes the proof-of-concept trapping of polystyrene p…

Pollination and reproductive success of two colour variants of a deceptive orchid, Dactylorhiza maculata (Orchidaceae)

2002

Polymorphism in petal colour is common in deceptively pollinated plant species. Most of the deceptively pollinated orchids are food frauds, and in most of them, the deception is not mimetic. These plants have conspicuously coloured flowers which they use as the main attractant of naive pollinators. In a field experiment, we studied the response of bumblebees and other types of flower visitors to colour differences between experimentally paired plants of Dactylorhiza maculata, a nectarless food-deceptive species. In addition, pollen removal, an estimate of male fitness, and fruit production, an estimate of female fitness, were measured in the two colour variants. We found a trend of bumblebe…

Note on the ranking of fuzzy numbers: conditions for a total order relation

1988

It is well-known that the set of fuzzy numbers is not ordered. The author states the conditions which have to be satisfied so that the problem of ranking fuzzy numbers has a solution. In fact, the subset of fuzzy numbers, the elements of which are strictly defined and continuous,is endowed with a total order relation.