Search results for "METAL"
showing 10 items of 7908 documents
Embryonic Growth of Face-Center-Cubic Silver Nanoclusters Shaped in Nearly Perfect Half-Cubes and Cubes.
2016
Demonstrated herein are the preparation and crystallographic characterization of the family of fcc silver nanoclusters from Nichol’s cube to Rubik’s cube and beyond via ligand-control (thiolates and phosphines in this case). The basic building block is our previously reported fcc cluster [Ag14(SPhF2)12(PPh3)8] (1). The metal frameworks of [Ag38(SPhF2)26(PR′3)8] (22) and [Ag63(SPhF2)36(PR′3)8]+ (23), where HSPhF2 = 3,4-difluorothiophenol and R′ = alkyl/aryl, are composed of 2 × 2 = 4 and 2 × 2 × 2 = 8 metal cubes of 1, respectively. All serial clusters share similar surface structural features. The thiolate ligands cap the six faces and the 12 edges of the cube (or half cube) while the phosp…
NIR-absorbing transition metal complexes with redox-active ligands
2020
Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region. Peer reviewed
II) Wood pellets for home heating can be considered environmentally friendly fuels? Heavy metals determination by inductively coupled plasma-optical …
2016
Abstract The aim of the present study was to determine the concentrations of twelve potentially hazardous elements in wood pellet ashes obtained by the combustion of 13 pellet brands for sale in Italy, the impact of adding the ashes to soils and health risk of operator due to dust exposure. Samples were analysed by Inductively Coupled Plasma Optical Emission Spectrometry. The concentrations of heavy metals in ashes from stoves ranged from 0.41 to 7.2 mg kg − 1 for As, from 1.3 to 12 mg kg − 1 for Sb, from 1.8 to 12 mg kg − 1 for Zn, from 0.23 to 0.8 mg kg − 1 for Pb, from 0.18 to 2.8 mg kg − 1 for Ni, from 0.09 to 1.0 mg kg − 1 for Cd, from 0.46 to 3.4 mg kg − 1 for Cr, from 0.94 to 2.7 mg …
Experimental Investigation into the Effect of Pyrolysis on Chemical Forms of Heavy Metals in Sewage Sludge Biochar (SSB), with Brief Ecological Risk …
2021
Experimental investigations were carried out to study the effect of pyrolysis temperature on the characteristics, structure and total heavy metal contents of sewage sludge biochar (SSB). The changes in chemical forms of the heavy metals (Zn, Cu, Cr, Ni, Pb and Cd) caused by pyrolysis were analyzed, and the potential ecological risk of heavy metals in biochar (SSB) was evaluated. The conversion of sewage sludge into biochar by pyrolysis reduced the H/C and O/C ratios considerably, resulting in stronger carbonization and a higher degree of aromatic condensation in biochar. Measurement results showed that the pH and specific surface area of biochar increased as the pyrolysis temperature increa…
To incinerate or not? - Effects of incineration on the concentrations of heavy metals and leaching efficiency of post-precipitated sewage sludge (RAV…
2020
The major element and heavy metal concentrations of post-precipitated sewage sludge (PPS) and its ash residue (PPA) were determined using microwave digestion followed by inductively coupled plasma optical emission spectrometry (ICP-OES) and mass spectrometry (ICP-MS). To the best of our knowledge, this has not been previously done. In both PPS and PPA the heavy metal concentrations were clearly below the average concentrations than those encountered in sewage sludge in Europe. The leaching efficiency of the metal (Al/ Fe) used as a precipitation agent from post-precipitated sludge and its ash residue with phosphoric acid was also investigated with previously optimized leaching conditions. T…
Study Regarding the Optimal Milling Parameters for Finishing 3D Printed Parts from ABS and PLA Materials
2018
Abstract In this paper we proposed to identify the optimum milling parameter required for finishing processes performed on 3Dprinted parts from ABS and PLA materials. We have identified the optimum milling parameters for a constant spindle speed of 3500 rot/min for face milling and profile contouring operations with different tools diameters. The study was performed on 3D printed specimens from ABS and PLA materials.
Mechanical and metallurgical characterization of AA6082-T6 sheet-bulk joints produced through a linear friction welding based approach
2020
In the last decades, new flexible manufacturing processes have been developed to face the demands, by many industrial fields, for highly customized complex functional parts. The peculiar design of these components often overcomes conventional sheet metal and bulk metal forming processes capabilities. In order to face this issue, new hybrid techniques, capable of exploit key advantages of different processes, have to be developed. In this study, a method to obtain sheet-bulk joints, based on the Linear Friction Welding process, is proposed. The feasibility of the technique was investigated through an experimental campaign carried out with varying pressure and oscillation frequency using AA60…
Analysis of Electrical Energy Demands in Friction Stir Welding of Aluminum Alloys
2017
Abstract Manufacturing processes, as used for discrete part manufacturing, are responsible for a substantial part of the environmental impact of products. Despite that, most of metalworking processes are still poorly documented in terms of environmental footprint. To be more specific, the scientific research has well covered conventional machining processes, concerning the other processes there is a lack of knowledge in terms of environmental load characterization instead. The present paper aims to contribute to fill this knowledge gap and an energetic analysis of Friction Stir welding (FSW) is presented. Following the CO2PE! methodological approach, power studies and a preliminary time stu…
Failure maps to assess bearing performances of glass composite laminates
2018
Aim of this article is the assessment of the bearing mechanical performances of pin-loaded glass laminates as function of their geometrical configuration. To this concern, 32 specimens having different hole diameter (D), laminate width (W), and hole center to laminate free edge distance (E) have been tested under bearing conditions. The maximum bearing stress and the stress-displacement curves were analyzed as function both of hole to laminate free edge distance E and hole diameter D. Moreover, an experimental 2D failure map was created by placing the experimental results (i.e., the kind of failure mechanism occurred for each geometrical configuration) in the plane E/D versus W/D ratios. In…
Geometrical deviation of end-of-life parts as a consequence of reshaping by single point incremental forming
2021
AbstractPutting in place circular economy strategies is an urgent challenge to face. In this scenario, manufacturing processes play a relevant role as efficient material reuse enabler. Scientists have to make an effort either to find new process or to rethink old process to reprocess end-of-life (EoL) component to recover both material and functions. In this paper, single point incremental forming (SPIF) process is used for reshaping sheet metal EoL components. The entire process chain was replicated including both deep drawing process (to imitate the end-of-life component) as well as SPIF operations (to obtain the reshaped components). The geometrical deviation as a consequence of SPIF ope…