Search results for "METALS"
showing 10 items of 2013 documents
Structure and composition heterogeneity of a FeAl alloy prepared by one-step synthesis and consolidation processing and their influence on grain size…
2006
Abstract This paper aims to characterize a bulk dense FeAl (47 at.%) alloy synthesized and consolidated by one-step current-activated pressure-assisted processing of nanocrystalline elemental powders. The end-product was analyzed using a combination of scanning (SEM) and transmission electron microscopies (TEM), electron back-scattering diffraction (EBSD) as well as electron probe microanalysis (EPMA). Special attention was paid to verify the grain size (32–89 nm) previously determined by X-ray diffraction peak profile analysis. It has been found that this material displays equiaxed grains (0.8–4 μm in size) and contains limited structural defects like subgrains and dislocations. The EPMA r…
Conformational polymorphs of 1,1,2,2-tetrachloroethane: pressure vs. temperature.
2011
Directional Cl···Cl type I and II interactions govern the low-density aggregation of 1,1,2,2-tetrachloroethane molecules in synclinal conformation in the crystalline state at low temperature, whereas the dense molecular packing in high-pressure is achieved for the antiperiplanar conformers and electrostatically less favored Cl···Cl contacts. The mechanism of transformation between loose and dense associations involves the collapse of Cl···Cl contacts and conformational conversion.
Introducing an amine functionality at the block junction of amphiphilic block copolymers by anionic polymerization strategies
2011
A series of block copolymers bearing a single amino in-chain functionality was synthesized via anionic polymerization of styrene and ethylene oxide. By means of both a conventional and a continuous setup, living polystyrene was quantitatively end functionalized with an oxirane (DBAG) prior to the polymerization of the poly(ethylene oxide) segment. The in-chain amine was conjugated with a fluorescent dye.
Determination of transport and kinetic properties in self-propagating high-temperature synthesis
2007
International audience; Exothermic reactions in solid powders are analyzed using the usual macroscopic modeling based on the heat transfer equation coupled to an Arrhenius type of dynamics. This problem have important applications in the synthesis of intermetallics and ceramic materials which occur when a high temperature reaction wave propagates throughout the system. Understanding the mechanism of such processes are thus crucial in mastering real laboratory experiments. We first analyze the model, both theoretically and numerically, for a set of representative parameters. We then use traditional data analyses procedures to estimate from the temperature profiles the same set of representat…
Combustion synthesis of MoSi2 and MoSi2–Mo5Si3 composites: Multilayer modeling and control of the microstructure
2010
International audience; In this work, we present a multilayer modeling for the formation of molybdenum silicides in the exothermic reaction between Mo and Si under the influence of a temperature pulse. The heating rate can either be a well-controlled ramp or be generated spontaneously by the propagation of a combustion synthesis front. The model addresses the specific situation above the melting point of silicon and describes the solid–liquid reaction taking place in a single representative particle of molybdenum surrounded by the melt of silicon. We obtain a set of kinetic equations for the propagation of the interfaces between the different layers (Mo/Mo5Si3 and Mo5Si3/MoSi2) in the solid…
Vigor F7 projekta ietekme uz redzes funkcijām
2017
Maģistra darbs ir uzrakstīts angļu valodā uz 38 lapām. Tas satur 12 attēlus, 9 tabulas, 26 atsauces uz literatūras avotiem un 4 pielikumus. Galvenais darba mērķis ir nodemonstrēt F7 ierīces ietekmi uz redzes sistēmu un tās funkcijām. Tika veikti divi eksperimenti: Eksperiments I (30 dalībnieki, 10 – 40 g.v.), lai izvērtētu Vigor F7 ierīces ietekmi uz redzes funkcijām; Eksperiments II (20 dalībnieki, sportisti, 14 – 48 g.v.), lai izvērtētu Vigor F7 ierīces ietekmi uz dinamisko iemaņu efektivitāti. Abos eksperimentos novēroja statistiski nozīmīgi atšķirīgus rezultātus gan redzes funkcijām, gan dinamiskajām iemaņām, ja izmantoja F7 ierīci.
On the effectiveness of Finite Element simulation of orthogonal cutting with particular reference to temperature prediction
2007
Abstract Finite Element simulation of orthogonal cutting is nowadays assuming a large relevance; in fact a very large number of papers may be found out in technical literature on this topic. In recent years, numerical simulation was performed to investigate various phenomena such as chip segmentation, force prediction and tool wear. On the other hand, some drawbacks have to be highlighted; due to the geometrical and computational complexity of the updated-Lagrangian formulation mostly used in FE codes, a cutting time of only a few milliseconds can be effectively simulated. Therefore, steady-state thermal conditions are not reached and the simulation of the thermal phenomenon may be ineffect…
Micro and macro mechanical characterization of friction stir welded Ti–6Al–4V lap joints through experiments and numerical simulation
2013
Abstract Lap joints of Ti–6Al–4V were produced and the effect of the main process parameters was studied through macro and micro investigations highlighting mechanical resistance, microhardness profiles, grain size and phase distributions. A dedicated numerical model was used to link the input process parameters to temperature and strain distributions and to the final microstructure in the welded joint. It is found that the strain produced in the stir zone by proper combination of process parameters plays a fundamental role in the final microstructure and mechanical properties of the joints.
CDRX modelling in friction stir welding of AA7075-T6 aluminum alloy: analytical approaches
2007
Abstract Friction stir welding (FSW) is an energy efficient and environmentally “friendly” (no fumes, noise, or sparks) welding process, during which the workpiece are welded together in a solid-state joining process at a temperature below the melting point of the workpiece material under a combination of extruding and forging. Significant microstructural evolution takes place during FSW: in particular continuous dynamic recrystallization (CDRX) phenomena result in a highly refined grain structure in the weld nugget and strongly affect the final joint resistance. In the paper two different analytical models aimed to the determination of the average grain size due to continuous dynamic recry…
Engineering Topological Nodal Line Semimetals in Rashba Spin-Orbit Coupled Atomic Chains
2019
We study an atomic chain in the presence of modulated charge potential and modulated Rashba spin-orbit coupling (RSOC) of equal period. We show that for commensurate periodicities $\lambda=4 n$ with integer $n$, the three-dimensional synthetic space obtained by sliding the two phases of the charge potential and RSOC features a topological nodal line semimetal protected by an antiunitary particle-hole symmetry. The location and shape of the nodal lines strongly depend on the relative amplitude between the charge potential and RSOC.