Search results for "MICI"

showing 10 items of 1671 documents

Controlled Delivery of Gentamicin Antibiotic from Bioactive Electrospun Polylactide-Based Ultrathin Fibers

2011

The purpose of this study was to generate ultrathin fibers based on polylactide (PLA) biopolyester with antimicrobial controlled release capacity to treat bacterial infections. To achieve this objective, gentamicin antibiotic was encapsulated into pure PLA fibers, a blend of PLA–collagen and coaxial fibers containing a skin of PLA and a core of collagen using the electrospinning technique. The morphology of the gentamicin-loaded fibers and the antibiotic distribution within the fibers were examined by SEM and TEM. The drug delivery profile of the different electrospun fibers was analyzed using a spectrophotometric method. The performance for treating common possible post-surgical infections…

Materials sciencemedicine.drug_classPseudomonas aeruginosaAntibioticstechnology industry and agricultureCondensed Matter PhysicsAntimicrobialmedicine.disease_causeControlled releaseElectrospinningDrug deliverymedicineGeneral Materials ScienceGentamicinPolymer blendmedicine.drugBiomedical engineeringAdvanced Engineering Materials
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CO2 reduction by C3N4-TiO2 Nafion photocatalytic membrane reactor as a promising environmental pathway to solar fuels

2019

Abstract We investigated CO2 photocatalytic reduction coupling, for the first time in literature, the assets offered by the continuous operating mode using C3N4-TiO2 photo-catalyst embedded in a dense Nafion matrix. The reactor performance was analyzed under UV–vis light in terms of productivity, selectivity and converted carbon. Reaction pressure was specifically investigated for its effect as a “driver” in determining reactor performance, modulating products removal from the reaction volume. In addition, the membrane reactor performance was explored as a function of H2O/CO2 feed molar ratio and contact time. The higher feed pressure (5 bar) led to a lesser MeOH production and a greater am…

Materials sciencesolar fuels2utilizationchemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencesCatalysischemistry.chemical_compoundNafionDesorptionPartial oxidationGeneral Environmental ScienceMembrane reactorProcess Chemistry and Technologytechnology industry and agriculture021001 nanoscience & nanotechnology0104 chemical sciencesCOSolar fuelchemistryChemical engineeringVolume (thermodynamics)Settore CHIM/03 - Chimica Generale E InorganicaPhotocatalysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologySelectivityCarbonCO2 utilizationCO2 utilization Solar fuel
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Experimental study of the pyrolysis of waste bitumen for oil production

2020

Abstract This work focuses on bitumen slow pyrolysis. Mass and energy yields of oil, solid and gas were obtained from pyrolysis experiments using a semi-batch reactor in a nitrogen atmosphere, under three non-isothermal conditions (maximum temperature: 450 °C, 500 °C and 550 °C). The effect of temperature on the product yields was discussed. The gas compositions were analysed using gas chromatography (GC) and the heating value of oil and solid residue was also measured. Using a thermo-gravimetric analyser, kinetic parameters were evaluated through Ozawa-Flynn-Wall (OFW) method. Results showed that oil yield is maximum at 500 °C (50%). Moreover, gas yield increased with increasing pyrolysis …

Maximum temperatureMaterials scienceSettore ING-IND/25 - Impianti Chimici020209 energyAnalyserAnalytical chemistryBitumen Kinetic parameters Oil Product yields Pyrolysis Syngas Thermo-gravimetric analysis Waste to fuel02 engineering and technologyKinetic energy020401 chemical engineeringAsphaltOil production0202 electrical engineering electronic engineering information engineeringHeat of combustionGas chromatography0204 chemical engineeringPyrolysisJournal of the Energy Institute
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Home delivery meal : issue and impact of this service on the nutritional status of older people living at home

2021

Introduction. In old age, the onset of disabilities (physical, cognitive) can lead older adults to have difficulty doing certain tasks of daily life, particularly those related to alimentation (shopping, meal preparation). To alleviate these difficulties, more and more elderly people are using home delivery meal services. The objective of this thesis is to question the place and role of such services in preventing undernutrition in the elderly population. Undernutrition is common in this population and results from an imbalance between nutritional intake and needs. Materials and methods. In this thesis, several approaches were combined. A systematic literature review documented the undernut…

Meals-On-Wheels[SDV.MHEP] Life Sciences [q-bio]/Human health and pathology[SDV.MHEP.GEG]Life Sciences [q-bio]/Human health and pathology/Geriatry and gerontologyHome care servicesDépendanceProtein-Energy MalnutritionDénutritionPortage de repasOlder adultsPersonne âgéeHomebound person[SDV.AEN]Life Sciences [q-bio]/Food and NutritionAide à domicile[SDV.MHEP]Life Sciences [q-bio]/Human health and pathology
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(19)F NMR screening of unrelated antimicrobial peptides shows that membrane interactions are largely governed by lipids.

2014

AbstractMany amphiphilic antimicrobial peptides permeabilize bacterial membranes via successive steps of binding, re-alignment and/or oligomerization. Here, we have systematically compared the lipid interactions of two structurally unrelated peptides: the cyclic β-pleated gramicidin S (GS), and the α-helical PGLa. 19F NMR was used to screen their molecular alignment in various model membranes over a wide range of temperatures. Both peptides were found to respond to the phase state and composition of these different samples in a similar way. In phosphatidylcholines, both peptides first bind to the bilayer surface. Above a certain threshold concentration they can re-align and immerse more dee…

Membrane lipidsAntimicrobial peptidesAmphiphilic antimicrobial peptidesLipid BilayersBiophysicsBiochemistryProtein Structure Secondarychemistry.chemical_compoundMembrane LipidsHumansAmino Acid SequenceProtein PrecursorsLipid bilayerNuclear Magnetic Resonance BiomolecularBacteriaBilayerPeripheral membrane proteinLipid compositionCell MembraneGramicidinBiological membraneRe-alignment in membraneCell BiologyMembraneBiochemistrychemistryGramicidinBiophysicsBacterial membranesSpontaneous curvatureSolid state 19F NMR structure analysis
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A Dialysis Photocatalytic Reactor for the Green Production of Vanillin

2020

In the present work, dialysis was used to recover vanillin while being produced by partial photocatalytic oxidation of ferulic acid in an aqueous solution at ambient temperature. The relatively high value of the permeate flux through a dense polyether-block amide membrane allowed continuously extracting vanillin from the reacting solution, thus avoiding its successive oxidation. The rate of vanillin formation was improved, compared to other reactor configurations, because intermediate compounds permeated from the reacting solution and did not hinder the reaction, while ferulic acid permeated in the opposite direction to partially replenish the reactor with the substrate. The photocatalytic …

Membrane reactor02 engineering and technology010402 general chemistrylcsh:Chemical technology01 natural sciencesDialysis; Green chemistry; Membrane reactors; Photocatalysis; VanillinCatalysisFerulic acidlcsh:Chemistrychemistry.chemical_compoundPhotocatalysiMembrane reactorslcsh:TP1-1185Physical and Theoretical ChemistryPhotocatalysisConcentration polarizationSettore ING-IND/24 - Principi Di Ingegneria ChimicaAqueous solutionMembrane reactorChemistrygreen chemistryVanillinDialysi021001 nanoscience & nanotechnology0104 chemical sciencesMembraneChemical engineeringlcsh:QD1-999Green chemistryvanillinYield (chemistry)VanillinPhotocatalysismembrane reactorsdialysisSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technologyDialysisphotocatalysisCatalysts
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Heterogeneous Photocatalysis and Photoelectrocatalysis: From Unselective Abatement of Noxious Species to Selective Production of High-Value Chemicals

2015

Heterogeneous photocatalysis and photoelectrocatalysis have been considered as oxidation technologies to abate unselectively noxious species. This article focuses instead on the utilization of these methods for selective syntheses of organic molecules. Some promising reactions have been reported in the presence of various TiO2 samples and the important role played by the amorphous phase has been discussed. The low solubility of most of the organic compounds in water limits the utilization of photocatalysis. Dimethyl carbonate has been proposed as an alternative green organic solvent. The recovery of the products by coupling photocatalysis with pervaporation membrane technology seems to be a…

Membrane reactorSettore ING-IND/25 - Impianti ChimiciQuantum yieldPhotochemistryRedoxchemistry.chemical_compoundPhotocatalysi4-METHOXYBENZYL ALCOHOLANATASEAROMATIC ALCOHOLSTIO2 PHOTOCATALYSISGeneral Materials SciencePhysical and Theoretical ChemistrySolubilityAQUEOUS SUSPENSIONSettore ING-IND/24 - Principi Di Ingegneria ChimicaTITANIUM-DIOXIDEChemistryLIGHT IRRADIATIONSubstrate (chemistry)P-ANISALDEHYDEAmorphous phaseWATER OXIDATIONPervaporation membranePARTIAL OXIDATIONChemical engineeringSettore CHIM/03 - Chimica Generale E InorganicaPhotocatalysisPhotoelectrocatalysisDimethyl carbonateWater detoxificationGREEN SYNTHESIS
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Effect of preparation method on the properties of poly(methyl methacrylate)/mesoporous silica composites

2019

The preparation method of a polymer composite and the filler loading are amongst the factors that influence the properties of the final composites. This article studies the effect of these factors on the thermal stability and thermal degradation kinetics of poly(methyl methacrylate) (PMMA)/mesoporous silica (MCM-41) composites filled with small amounts of MCM-41. The PMMA/MCM-41 composites were prepared through in situ polymerisation and melt mixing methods, with MCM-41 loadings of 0.1, 0.3, and 0.5 wt.%. The presence of MCM-41 increased the thermal stability of PMMA/MCM-41 composites prepared by melt mixing, but in the case of the in situ polymerised samples, the MCM-41 accelerated the deg…

Mesoporous silica (MCM-41)Thermal degradation kineticThermal degradation kineticsMelt mixingIn situ polymerisationFOS: Environmental engineeringPoly(methyl methacrylate) (PMMA)Environmental engineeringSettore CHIM/07 - Fondamenti Chimici Delle Tecnologie13C {1H} CP-MAS-NMRSettore CHIM/02 - Chimica Fisica
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Evaluation of the Purity of Magnesium Hydroxide Recovered from Saltwork Bitterns

2022

Magnesium has been listed among the 30 critical raw materials by the European Union. In recent years, many green and sustainable alternative Mg2+ sources have been sought to satisfy the EU’s demand and to avoid mineral ore consumption. In this context, saltwork bitterns, the by-products of solar sea salt production, have attracted much attention thanks to their high Mg2+ concentrations (up to 80 g/L) and low Ca2+ and bicarbonate contents (<0.5 g/L). Although investigations on Mg2+ extraction from bitterns in the form of Mg(OH)2(s) have already been performed, product purity has never been properly addressed. Mg(OH)2(s) is a chemical compound of great interest and extensive utility in num…

Mg(OH)<sub>2</sub>(s); brucite; precipitation; mineral recovery; circular economy; seawater valorizationSettore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciCircular economyGeography Planning and DevelopmentBrucitePrecipitationMineral recoveryAquatic ScienceSeawater valorizationbrucite circular economy Mg(OH)2 mineral recovery precipitation seawater valorizationBiochemistry:Enginyeria química::Impacte ambiental [Àrees temàtiques de la UPC]Green chemistryQuímica verdaAigua de marSeawaterSettore CHIM/01 - Chimica AnaliticaMg(OH)2(s)Water Science and Technology
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Different approaches for the solar photocatalytic removal of micro-contaminants from aqueous environment: Titania vs. hybrid magnetic iron oxides

2019

Abstract This work reports on the light-induced heterogeneous photodegradation of four micro-contaminants (MCs): Carbamazepine (C), Flumequine (F), Ibuprofen (I), and Sulfamethoxazole (S), using two different heterogeneous advanced oxidation processes. The first one is the semiconductor photocatalysis, run in the presence of the suspension of a home prepared TiO2 (TiO2 HP); the second one is an heterogeneous photo-Fenton process run in the presence of a hybrid magnetic nanomaterial (MB3) with an iron oxides core and an organic shell made of bio-based substances (BBS) isolated from urban biowaste. The two materials work upon two different mechanisms and were already tested (and the action me…

Micro-contaminantMaterials sciencePhoto-FentonCHIM/03 - CHIMICA GENERALE ED INORGANICAMicro-contaminants202 engineering and technology010402 general chemistry01 natural sciences7. Clean energyRedoxCatalysisNanomaterialsCatalysisMicro-contaminants; TiO2; Photocatalysis; Water treatments; Photo-Fenton; Magnetic materialsPhotocatalysiTiOTiO2Water treatmentPhotocatalysisPhotodegradationMagnetic materialsMagnetic materialAqueous solutionWater treatmentsGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesPilot plantChemical engineering13. Climate actionPhotocatalysisDegradation (geology)Settore CHIM/07 - Fondamenti Chimici Delle Tecnologie0210 nano-technology
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