Search results for "MICI"

Hierarchical modelling of electrodialysis desalination process

2017

In recent years, thanks to the development of ion exchange membranes (IEMs) manufacturing industry, Electrodialysis (ED) is spreading as a viable alternative to the more common membrane desalination processes. Therefore, many research efforts have been recently devoted to studying this process both via experimental and modelling activities. In the present work a novel mathematical model for ED was developed using a multi-scale approach. This method allows to build a hierarchical simulation tool that is able to gauge the impact of all the phenomena involved in the process. The lower-hierarchy model describes the behaviour of the elementary unit of an ED stack, namely cell pair. This model is…

RED Heat-to-Power: conversione di calore di scarto in energia elettrica mediante elettrodialisi inversa a ciclo chiuso

2016

La produzione di energia da gradienti salini si sta affermando come una valida alternativa alle tradizionali fonti di energia rinnovabili. In particolare l’elettrodialisi inversa (RED) è di certo tra le tecnologie più promettenti per effettuare la conversione di gradienti salini in energia utile. Un recente sviluppo è l’utilizzo del processo RED a ciclo chiuso con soluzioni saline artificiali, nel quale le soluzioni in uscita dall’unità RED vengono rigenerate all’interno di un’unità di rigenerazione termica, che ripristina il gradiente salino iniziale. L’utilizzo del sistema a ciclo chiuso premette dunque di convertire calore a bassa temperatura (e.g. calore di scarto a T <70-100°C) in e…

Ion Exchange Membrane deformation and its relevance in Reverse ElectroDialysis

2017

Reverse electrodialysis (RED) is an innovative electro-membrane technology for electric energy generation from two salt solutions with different concentration. This different concentration is the driving force to a selective movement of ions from the concentrate channel to the dilute one oriented by Ion Exchange Membranes (IEMs). Typically, RED stack are made by piling alternatively cation exchange membranes and anion exchange membranes with the aid of spacers or profiles built on the membrane surface. Two electrodic compartments are placed at the two ends of the stack, where the ion flux generated is converted into an electric current able to circulate through an external load connected to…

Coupling CFD simulation with a simplified process model for reverse electrodialysis units

2017

Salinity gradient between two solutions is a renewable source of energy. Among the technologies able to exploit the salinity gradient, reverse electrodialysis (RED) is an electrochemical process for electrical power generation through direct conversion. Ion exchange membranes, piled alternately and separated by net spacers or membrane profiles, are the key elements of a RED stack. A multiplex phenomenology occurs in RED units; Ohmic and non-Ohmic (due to concentration changes) voltage losses and pressure drop are the main issues, and the membrane/channel configuration is crucial for the stack performance. In this framework, mathematical modelling can be a powerful tool for predictive purpos…

Complete Numerical Simulation of Flow Fields in Baffled Stirred Vessels: The Inner-Outer Approach

1994

Greeen Synthesis of Bromine through photocatalysis and ozonation

2017

Greeen Synthesis of Bromine through photocatalysis and ozonation

Br2 production from photocatalysis and/or ozonation of bromide containing aqueous solutions: kinetics and mechanisms

2018

Br2 production from photocatalysis and/or ozonation of bromide containing aqueous solutions: kinetics and mechanisms

Pervaporation membrane reactors (Chapter 3)

2013

CFD simulation of gas-liquid stirred vessels

2006

Computational Fluid Dynamics is an increasingly important tool for carrying out realistic simulations of process apparatuses. As a difference from single phase systems, for multipliase systcms the development of CFD models is still at its early stages. In the present work CFD simulations of gasliquid stirred tanks are reported. All bubbles are assumed to share the same size, and a simplified approach is adopted for the description of momentum exchanges between tile two phases. In particular ir is shown that the only parameter needed for modeling drag forces is bubble terminal velocity. Results show that in a quite wide range encompassing most practical applications, bubble size has a limite…

CFD simulation of gas-liquid hydrodynamics in a rectangular air–lift loop reactor

2006

Computational Fluid Dynamics is an increasingly important tool for carrying out realistic simulations of process apparatuses. As a difference from single phase systems, for multi phase systems the development of CFD models is still at its early stages. Moreover, gas-liquid systems are characterised by an additional complexity level, related to the fact that, as a difference with solid-liquid systems, bubble sizes are not known in advance, being rather the result of formation and breakage-coalescence dynamics, and therefore of complex phenomena related to flow dynamics and interfacial effects. In the present work CFD simulations of gas-liquid air-lift reactors are reported. All bubbles are a…