Search results for "MICROSTRUCTURE"
showing 10 items of 707 documents
Microstructure, mechanical characteristics and cell compatibility of β-tricalcium phosphate reinforced with biodegradable Fe–Mg metal phase
2015
The use of beta-tricalcium phosphate (β-TCP) ceramic as a bioresorbable bone substitute is limited to non-load-bearing sites by the material׳s brittleness and low bending strength. In the present work, new biocompatible β-TCP-based composites with improved mechanical properties were developed via reinforcing the ceramic matrix with 30 vol% of a biodegradable iron-magnesium metallic phase. β-TCP-15Fe15Mg and β-TCP-24Fe6Mg (vol%) composites were fabricated using a combination of high energy attrition milling, cold sintering/high pressure consolidation of powders at room temperature and annealing at 400 °C. The materials synthesized had a hierarchical nanocomposite structure with a nanocrystal…
Monte Carlo Simulations of Surfaces and Interfaces in Materials
1996
Many applications of materials are controlled by their surface and interface properties. In particular, metallic alloys (but also mixed dielectric materials and amorphous polymer blends) are not homogeneously mixed on a microscopic length scale, although they are macroscopically homogeneous. Depending on the preparation of the sample, there exists a heterophase microstructure, with typical domain sizes, e.g. in the 1 to 102 µm range, separated by interfaces between them. The physical properties of such intrinsic interfaces (grain boundaries between small crystallites, antiphase domain boundaries in ordered alloys, Bloch walls in magnetic materials, etc.) are not only an important controllin…
A Simulation Analysis of the Microstructure of an Order Driven Financial Market with Multiple Securities and Portfolio Choices
2005
In this paper we propose an artificial market where multiple risky assets are exchanged. Agents are constrained by the availability of resources and trade to adjust their portfolio according to an exogenously given target portfolio. We model the trading mechanism as a continuous auction order-driven market. Agents are heterogeneous in terms of desired target portfolio allocations, but they are homogeneous in terms of trading strategies. We investigate the role played by the trading mechanism in affecting the dynamics of prices, trading volume and volatility. We show that the institutional setting of a double auction market is sufficient to generate a non-normal distribution of price changes…
Investigation of characterizing methods for the microstructure of cement
2002
Volumetric, gravimetric, calorimetric, flow methods, mercury porosimetry and laser granulometry were used to investigate the surface structure and the sorption behavior of industrial cements and hydrated cement paste. The suitability of the measuring methods is assessed.
Characterization by solid-state NMR and selective dissolution techniques of anhydrous and hydrated CEM V cement pastes.
2010
International audience; The long term behaviour of cement based materials is strongly dependent on the paste microstructure and also on the internal chemistry. A CEM V blended cement containing pulverised fly ash (PFA) and blastfurnace slag (BFS) has been studied in order to understand hydration processes which influence the paste microstructure. Solid-state NMR spectroscopy with complementary X-ray diffraction analysis and selective dissolution techniques have been used for the characterization of the various phases (C3S, C2S, C3A and C4AF) of the clinker and additives and then for estimation of the degree of hydration of these same phases. Their quantification after simulation of experime…
On the physico-chemical evolution of low-pH and CEM I cement pastes interacting with Callovo-Oxfordian pore water under its in situ CO2 partial press…
2014
International audience; Abstract Within the framework of geological repositories for radioactive waste, structural concretes must be adapted to the underground chemical conditions. CEM I cement-based materials are characterised by high pH that may produce an alkaline plume in the near-field of the repository. In order to avoid this problem, low-pH cements have been designed. This study compares the physico-chemical behaviour of a low-pH material with a CEM I cement paste, both being subjected to leaching by an aqueous solution. An original experimental setup was designed to reproduce the underground conditions using a specific CO2 regulation device. Under these conditions, the low-pH materi…
Investigations on The Micro-Structure of Hardened Cement Pastes
1988
Abstract Creep is a mechanical property, that has to be taken into account in the design of concrete constructions. Earlier studies showed that creep of concrete, among other things, depends on the relative humidity of the environment and on the type of cement used. The origin of creep lies in the hydrated cement paste, which is present between the aggregates. This paper, based on a thesis of H.H. Willems (ref. 1) deals with the relation between the creep behaviour and the microstructure of hardened Portland (PC) and Portland-blastfurnace cement (PBC) pastes. At several relative humidities shrinkage and creep experiments have been performed with thin-walled hollow cylindrical specimens. Nex…
Impact of Thermal Treatment on the Surface of Na0.5Bi0.5TiO3-Based Ceramics
2021
This research was funded by the European Regional Development Fund, grant number 1.1.1.2/VIAA/3/19/558. The Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme, grant number 739508.
Microstructure and mechanical effects of spark plasma sintering in alumina monolithic ceramics
2013
The specific effects of spark plasma sintering (SPS) on the creep behavior, microstructure and mechanical properties of alumina monolithic ceramic were investigated. SPS introduces strains that concentrate at grain boundaries and inhibit crack growth, resulting in an improvement in the flexural strength and fracture toughness. However, creep blocks grain boundary movements and decreases the reliability of the material. These strains can be removed by a post-sintering thermal treatment, which plays an important role in the distribution of dislocations.
Microstructure of Triassic conodont Pseudofurnishius murcianus van den Boogaard: Functional implications
2020
Pseudofurnishius murcianus van den Boogaard is a Triassic conodont with a very characteristic morphology, a blade with a rostral platform heavily denticulated, that makes it easily distinguishable from other coeval species. It is a well-know taxon that has been the object of several palaeobiological works, focused on their apparatus reconstruction, ontogeny and, recently, their P 1 element function. In order to increase our palaeobiology knowledge of this taxon we undertook a histological analysis to corroborate the functional hypothesis established for this conodont. The histological study demonstrated the presence of different microstructural types, suggesting that they are functional ada…