Search results for "MIDI"

Syntheses and Structures of Magnesium and Zinc Boraamidinates: EPR and DFT Investigations of Li, Mg, Zn, B, and In Complexes of the [PhB(NtBu)2]•- An…

2006

The first magnesium and zinc boraamidinate (bam) complexes have been synthesized via metathetical reactions between dilithio bams and Grignard reagents or MCl2 (M = Mg, Zn). The following new classes of bam complexes have been structurally characterized:  heterobimetallic spirocycles {(L)μ-Li[PhB(μ-NtBu)2]}2M (6a,b, M = Mg, L = Et2O, THF; 6c, M = Zn, L = Et2O); bis(organomagnesium) complexes {[PhB(μ3-NtBu)2](MgtBu)2(μ3-Cl)Li(OEt2)3} (8) and {[PhB(μ3-NtBu)2](MgR)2(THF)2} (9a, R = iPr; 9b, R = Ph); mononuclear complex {[PhB(μ-NDipp)2]Mg(OEt2)2} (10). Oxidation of 6a or 6c with iodine produces persistent pink (16a, M = Mg) or purple (16b, M = Zn) neutral radicals {Lx-μ-Li[PhB(μ-NtBu)2]2M}• (L …

In Search of the [PhB(μ-NtBu)2]2As• Radical: Experimental and Computational Investigations of the Redox Chemistry of Group 15 Bis-boraamidinates

2008

DFT calculations for the group 15 radicals [PhB(μ-NtBu)2]2M• (M = P, As, Sb, Bi) predict a pnictogen-centered SOMO with smaller contributions to the unpaired spin density arising from the nitrogen and boron atoms. The reactions of Li2[PhB(μ-NR)2] (R = tBu, Dipp) with PCl3 afforded the unsolvated complex LiP[PhB(μ-NtBu)2]2 (1a) in low yield and ClP[PhB(μ-NDipp)2] (2), both of which were structurally characterized. Efforts to produce the arsenic-centered neutral radical, [PhB(μ-NtBu)2]2As•, via oxidation of LiAs[PhB(μ-NtBu)2]2 with one-half equivalent of SO2Cl2, yielded the Zwitterionic compound [PhB(μ-NtBu)2As(μ-NtBu)2B(Cl)Ph] (3) containing one four-coordinate boron center with a B−Cl bond.…

In-situ measurements of hemp-lime insulation materials for energy efficiency improvement

2018

Abstract Reduction of the CO2 emissions in the atmosphere is one of the goals set forth by the European Union, hence various directives have been adopted, such as the European directive 2012/27/EU on energy efficiency, i.e. ensuring from 2019 the construction of the near-zero energy buildings (nZEB). The construction segment plays a very important part in solving the current global problem of the greenhouse gas emissions and related processes of global warming, because in certain countries (i.e. in Latvia) it represents more than a half of the total energy consumption. Hence the necessity to elaborate means on how to boost the energy efficiency of the buildings meanwhile not rising pressure…

An Original Approach to Active Climate Control Based on Equilibrium Moisture Content (EMC) as Set Point in a Middle-Age Building in Palermo, Italy

2019

In the frame of a more sustainable approach to climate control, a long term strategy has been developed and is under advanced phase of implementation by technical staff of the University of Palermo in an important building, Palazzo Steri, owned by the University. The monumental room under climate control, the Sala dei Baroni (also known as Sala Magna), has a precious wooden ceiling where the previously loadbearing elements are covered with wooden painted panels. Many of them, painted in the fourteenth c, underwent important restorations in the past due to climate related damage (cracks, warpings, paint layer delamination) and biological infestations. The room is currently undergoing an impo…

Anesthesia for Euthanasia Influences mRNA Expression in Healthy Mice and after Traumatic Brain Injury

2014

Tissue sampling for gene expression analysis is usually performed under general anesthesia. Anesthetics are known to modulate hemodynamics, receptor-mediated signaling cascades, and outcome parameters. The present study determined the influence of anesthetic paradigms typically used for euthanization and tissue sampling on cerebral mRNA expression in mice. Naïve mice and animals with acute traumatic brain injury induced by controlled cortical impact (CCI) were randomized to the following euthanasia protocols (n=10-11/group): no anesthesia (NA), 1 min of 4 vol% isoflurane in room air (ISO), 3 min of a combination of 5 mg/kg midazolam, 0.05 mg/kg fentanyl, and 0.5 mg/kg medetomidine intraperi…

How to Use the DHT22 Sensor for Measuring Temperature and Humidity with the Arduino Board

2016

Abstract The objective of this paper is to achieve a functional system in terms of hardware and software, to measure temperature and humidity. Also, this system will allow to monitoring the time. In this, we use an Arduino board with interfacing a sensor placed in local environment to measure temperature and humidity. The paper aims to achieve the following goals: - achieving a functional system in terms of hardware and software that allows measuring and monitoring temperature, humidity and the time; - using a development board for the communication with the sensor and clock; - implementation a program that allows requirements.

157 Patient satisfaction and safety of sedation using perineurial dexmedetomidine in axillary brachial plexus block for wrist surgery

2021

Background and Aims Dexmedetomidine is known to prolong the duration of regional block while its sedative effect when administered perineurally is unknown.[1] We aim to evaluate the effect of perineural Dexmedetomidine on the systemic sedation in patients after axillary brachial plexus block (ABPB). Methods This prospective randomized control trial includes 78 patients undergoing wrist surgery receiving ABPB. The study was conducted with the approval of Ethics Committee of Riga Stradins University. Patients were randomized into two groups – control (CG) (N=39) and study group (SG) (N=39). Both groups received ABPB with a standard dose of local anaesthetics. The study group also received 100…

Monitoraggio del contenuto idrico del suolo in un versante calanchivo in Sicilia

2008

The effectiveness of various types of ventilation on air quality in multi-family buildings

2017

Przepisy prawne oraz normy obligują do kontroli systemów wentylacji budynków jedynie pod względem prędkości strumienia powietrza, co niestety nie zawsze gwarantuje zalecaną ze względów zdrowotnych jakość powietrza. W pracy podjęto badania skuteczności różnych typów wentylacji wielorodzinnych budynków mieszkalnych, ze szczególnym uwzględnieniem wentylacji naturalnej, stanowiącej najczęściej spotykane rozwiązanie w budynkach mieszkalnych w Polsce. Badano wpływ skuteczności wentylacji na podstawowe parametry charakteryzujące jakość powietrza, tj. stężenie ditlenku węgla, wilgotność względną oraz temperaturą. Badano również możliwość regulacji pracy systemu wentylacji budynków wielorodzinnych w…

Effects of statins, fibrates, rosuvastatin, and ezetimibe beyond cholesterol: the modulation of LDL size and subclasses in high-risk patients.

2007

Increasing evidence suggests that the quality-rather than just the quantity-of low-density lipoproteins (LDLs) exerts a great influence on cardiovascular risk. LDLs comprise multiple subclasses with discrete size and density, and different physicochemical composition, metabolic behaviors, and atherogenicity. Individuals generally cluster into 2 broad subgroups. Most have a predominance of large LDLs, and some have a higher proportion of small particles. Small, dense LDLs are good predictors of cardiovascular events and progression of coronary artery disease. Their predominance has been accepted as an emerging cardiovascular risk factor by the National Cholesterol Education Program Adult Tre…