Search results for "MINERALOGY"
showing 10 items of 1516 documents
Diffuse and focused carbon dioxide and methane emissions from the Sousaki geothermal system, Greece
2006
[1] We report first data on chemical composition of the gas emitted by the geothermal system of Sousaki, Greece. Gas manifestations display typical geothermal gas composition with CO2 as the main component and CH4 and H2S as minor species. Soil gas composition derives from the mixing of two end-members (atmospheric air and geothermal gas). Soil CO2 fluxes range from<2 to 33,400 g m−2 d−1. The estimated diffuse output of hydrothermal CO2, estimated for an area of 0.015 km2, is about 630 g s−1, while a tentative estimation of CH4 diffuse output gave a value of about 1.15 g s−1. Point sources accounted for lower flux values of ∼26 g s−1 of CO2, ∼0.1 g s−1 of CH4 and ∼0.02 g s−1 of H2S.
Selenium and heavy metals content in some Mediterranean soils
2010
Abstract The study of metal contents in industrial, agricultural or/and polluted soils compared with natural or unpolluted soils is currently necessary to obtain reference values and to assess soil contamination. Nonetheless, very few works published appear in international journals on elements like Se, Li and Sr in Spanish soils. This study determines the total levels of Se, Li, Sr, As, Cd, Co, Cr, Cu, Ni, Pb, V, Zn, Fe, Mn and Ba in 14 natural (unpolluted) soils (Gypsisols, Leptosols, Arenosols and Acrisols), 14 agricultural soils (Anthrosols, Fluvisols and Luvisols), and 4 industrial–urban affected-surface soil horizons (Anthrosols and Fluvisols) of Eastern Spain. The geochemical baselin…
Production and properties of doped PSN electro-optical ceramics
1997
Due to multifunctionality the transparent ferroelectric ceramics is attractive to solid state chemistry and physics as a promising material for active electro-optic elements. To study doping effects on the technological processing and properties, ceramic samples of Pb1-xZxSc1/2Nb1/2O3, have been prepared, where Z: (1) Ba (0 less than or equal to x less than or equal to 1), (2) rare-earth elements: Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu (x equals 0.1), (3) PbSc1/2Nb1/2O3 doped with 5 wt.% of rare-earth oxides. Ceramic characteristics, dielectric and electro-optical parameters have been measured. Differential thermal analysis (DTA), and x-ray diffraction are used to study the infl…
Data repeatability and acquisition techniques for Time-Domain Spectral Induced Polarization
2013
The Time Domain Induced Polarization (TDIP) technique is widely used in applied geophysics, particularly for environmental issues, for instance for delineating landfills or detecting leachate percolation. Because the reliability of IP data remains an issue at the field scale, this paper deals with the factors controlling data quality and compares different arrays and acquisition parameters for optimal collection of data in the field. The first part focuses on repeatability experiments carried out in the former Horlokke landfill (Denmark), in order to infer the degree of which a signal can be reproduced over time. Results show a good repeatability, with on average less than 10% of difference…
Field-portable Mössbauer spectroscopy on Earth, the Moon, Mars, and beyond
2011
ABSTRACT Iron occurs naturally as Fe 2+ , Fe 3+ , and, to a lesser extent, as Fe 0 . Many fundamental (bio)geochemical processes are based on redox cycling between these oxidation states. Mossbauer spectroscopy provides quantitative information about the distribution of Fe among its oxidation states, identification of Fe-bearing phases, and relative distribution of Fe among those phases. Portable, miniaturised Mossbauer spectrometers were developed for NASA9s Mars Exploration Rovers (in operation since 2004) and provide a means for non-destructive, in-situ field investigations. On Mars, these instruments provided evidence for aqueous activity with implications for habitability, were applied…
Laser-Induced Breakdown Spectroscopy for Rapid Elemental Analysis of Drillcore
2013
Abstract The elemental and mineralogical contents of rock drillcore can be analyzed using a variety of methods. For efficient exploration the characterization of the drillcore should be performed rapidly, so that the further drillings can be better planned and unnecessary costs can be reduced. In this paper, laser-induced breakdown spectroscopy (LIBS) is studied as a potential rapid on-line method for automated elemental analysis of drillcore. The method is based on a pulsed laser beam that transforms a small volume of the sample into plasma. Individual elements in the plasma have characteristic emission patterns detectable by a spectrometer. Based on the measured spectra the amount of diff…
Testing of the region of Murcia soils by near infrared diffuse reflectance spectroscopy and chemometrics.
2008
A partial least squares near infrared (PLS-NIR) method has been developed for the determination of several physicochemical parameters in soils from different locations of the Region of Murcia. The method was based on the proper chemometric treatment of diffuse reflectance spectra of soil samples. Reflectance spectra were scanned from samples stored in glass vials in the NIR region between 800 and 2600 nm, averaging 36 scans per spectrum at a resolution of 8 cm(-1). Models were built using reference data of 39 samples selected from a dendrogram obtained after hierarchical cluster analysis of NIR spectra of soils and prediction parameters were established from a validation set of 109 addition…
Conditions of dust sampling in pneumatic conveying through the horizontal pipeline
2007
Abstract The paper presents the results of examinations on the reciprocal relation between the isokinetic coefficient H of sampling, the quantity of measured mass concentration and the measuring usefulness of a dust sample aspired from the stream of solgas conveyed pneumatically in the horizontal pipeline. In gravimetric measurements of two-phase flows, the conditions under which aspiration is carried out, are extremely important. Available theoretical considerations and practical experiments usually concern aspiration in the vertical channels, where the manner of making measurements is universally known and it does not express any reservations. However, it is often necessary to conduct tes…
Experimental assessment of application of gravimetric measurements for pneumatic conveying in horizontal pipelines
2008
Abstract Available theoretical considerations and practical experiments usually concern aspiration in the vertical pipelines, where the procedure of making measurements is universally known and it does not express any reservations. However, it is often necessary to conduct test in the systems of horizontal conveying of solgas, where the conditions of taking a representative sample, even for the sake of the significant effect of the gravitational force, many vary from those suggested for measurements in the systems with vertical flow. The present paper contains the results of tests which determine usability of the gravimetric method in measurements of flow parameters of two-phase gas–solid m…
Hardening of bio-silica in sponge spicules involves an aging process after its enzymatic polycondensation: evidence for an aquaporin-mediated water a…
2011
Abstract Background Spicules, the siliceous skeletal elements of the siliceous sponges, are synthesized enzymatically via silicatein. The product formed, bio-silica, constitutes their inorganic matrix. It remained unexplored which reactions are involved in molding of the amorphous bio-silica and formation of a solid and rigid biomaterial. Methods Cell and molecular biological techniques have been applied to analyze processes resulting in the hardening of the enzymatically synthesized bio-silica. The demosponge Suberites domuncula has been used for the studies. Results Cell aggregates (primmorphs) from the sponge S . domuncula , grown in the presence of Mn-sulfate, form spicules that compris…