Search results for "MINERALOGY"
showing 10 items of 1516 documents
Spectrochemical Rubidium-Strontium Method for Geological Age Determination
1960
The age values of lepidolites from South Africa and from Varutrask as well as that of a microcline from Varutrask have been determined and are discussed in connection with determination according to the potassium-argon method, applied to the same materials A method is suggested which allows the spectrochemical determination of Rb and Sr with sufficient accuracy. The isotopic composition is determined by means of a Fabry-Perot etalon and hollow-cathode excitation, investigating the hyper-fine structure of the Sr line at 4078 A.
Reproducibility of trace element time-series (Na/Ca, Mg/Ca, Mn/Ca, Sr/Ca, and Ba/Ca) within and between specimens of the bivalve Arctica islandica – …
2017
Abstract Trace element time-series in bivalve mollusk shells and other (biogenic) materials can potentially serve as environmental proxies. Yet, the applicability of element-to-calcium ratios is often challenging, because non-environmental factors such as vital effects distort or mask environmental signals. If a trace element time-series is driven by an environmental factor, it should be reproducible within and between coeval specimens of the same species. In the present study, we tested whether time-series of trace element-to-calcium ratios can be reproduced within and between coeval specimens of the bivalve Arctica islandica and thus whether an external signal is encoded in the temporal v…
Controls on strontium and barium incorporation into freshwater bivalve shells ( Corbicula fluminea )
2017
Abstract Trace elements of bivalve shells can potentially serve as proxies of environmental change. However, to reconstruct past environments using the geochemical properties of the shells and determine the degree to which the element levels are biologically influenced, it is essential to experimentally determine the relationship between environmental variables and the element composition of the shells. To disentangle possible controls on the incorporation of strontium and barium into freshwater bivalve shells, we conducted controlled laboratory experiments using the extremely salinity and temperature tolerant Asian clam, Corbicula fluminea as a model species. Bivalves were reared for five …
Stylolite interfaces and surrounding matrix material: Nature and role of heterogeneities in roughness and microstructural development
2010
Rough pressure solution interfaces, like stylolites, are one of the most evident features of localized slow deformation in rocks of the upper crust. There is a general consensus that the development of these rough structures is a result of localized, stress enhanced, dissolution of material along a fluid filled interface, but little is known on the initiation of this roughness. The aim of this article is to reveal the role of heterogeneities initially present in the host-rock on roughness initiation. This should give insights on whether stylolite roughness is generated by a stress-induced instability or by the presence of disorder in the material (i.e. quenched noise). We use a microstructu…
Fe-periclase reactivity at Earth's lower mantle conditions: Ab-initio geochemical modelling
2017
Intrinsic and extrinsic stability of the (Mg, Fe) O solid mixture in the Fe-Mg-Si-O system at high P, T conditions relevant to the Earth's mantle is investigated by the combination of quantum mechanical calculations (Hartree-26 Fock/DFT hybrid scheme), cluster expansion techniques and statistical thermodynamics. Iron in the (Mg, Fe) O binary mixture is assumed to be either in the low spin (LS) or in the high spin (HS) state. Un-mixing at solid state is observed only for the LS condition in the 23-42 GPa pressure range, whereas HS does not give rise to un-mixing. LS (Mg, Fe) O un-mixings are shown to be able to incorporate iron by subsolidus reactions with a reservoir of a virtual bridgmanit…
Phase behavior of metals at very high P–T conditions: A review of recent experimental studies
2006
Studies at extreme pressures and temperatures are helpful for understanding the physical properties of the solid state, including such classes of materials as, metals, semiconductors, superconductors, or minerals. In particular, the phase behavior of metals at extreme pressures and temperatures is a challenging problem with many implications for other fields including Earth and planetary sciences. However, despite the efforts performed, the phase behavior of metals at very high pressures (HPs) and temperatures has been proven hard to predict accurately and only a limited number of experimental methods for making measurements in the regime of megabar pressures and thousand degree temperature…
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system.
2015
A superconductor is a material that can conduct electricity without resistance below a superconducting transition temperature, Tc. The highest Tc that has been achieved to date is in the copper oxide system: 133 kelvin at ambient pressure and 164 kelvin at high pressures. As the nature of superconductivity in these materials is still not fully understood (they are not conventional superconductors), the prospects for achieving still higher transition temperatures by this route are not clear. In contrast, the Bardeen-Cooper-Schrieffer theory of conventional superconductivity gives a guide for achieving high Tc with no theoretical upper bound--all that is needed is a favourable combination of …
Supercritical CO2 extraction of essential oil from orange peel; effect of the height of the bed
2000
Abstract The influence of the height of the particle bed on the kinetics of supercritical fluid extraction (SFE) of essential oil from orange peel is analyzed in this article. Peel of dehydrated oranges of the satsuma and naveline cultivars was used. A series of experiments were designed wherein, for the same conditions, particle height varied widely. These experiments were also carried out on different scales with extraction volumes of 0.5 and 5 l. The results of the experiments were interpreted using Sovova's extended flow model as has been done in previous studies. The bibliography indicates that a number of phenomena may distort the process. One of these phenomena is the formation of ma…
Capturing digital data of rock magnetic, gamma-ray and IR spectrometry for in-situ quality control and for the study of the physical–chemical regime …
2014
Abstract Residual kaolin deposits are operated on a worldwide basis. The majority of them is derived from chemical weathering of felsic rocks during the Cenozoic. This is true for the kaolin deposits on the western edge of the Bohemian Massif. Here this type of deposit provides industrial minerals for the ceramic industry in SE Germany. This raw material formed under tropical climatic conditions during the Miocene and Pliocene across a vast peneplain. Only within the Naab-Wondreb Depression, however, were economic accumulations preserved from erosion. Here near Tirschenreuth, kaolin has been mined since its discovery in 1830. The semi-consolidated regolith is composed of quartz and opaline …
Porphyroblast crystallization kinetics: the role of the nutrient production rate
2011
The mechanisms that govern porphyroblast crystallization are investigated by comparing quantitative textural data with predictions from different crystallization models. Such numerical models use kinetic formulations of the main crystallization mechanism to predict textural characteristics, such as grain size distributions. In turn, data on porphyroblast textures for natural samples are used to infer which mechanism dominated during their formation. Whereas previous models assume that the rate-limiting step for a porphyroblast producing reaction is either transport or growth, the model advanced in this study considers the production of nutrients for porphyroblasts as a potentially rate-limi…